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Spectroscopic Elucidation of Lanthanide Cation Dissolution Mechanism in Borosilicate Glass

Published online by Cambridge University Press:  14 March 2011

Hong Li ,
Zheming Wang ,
Liyu Li ,
Denis M. Strachan ,
Yali. Su  and
A.G. Joly
Hong Li
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington 99352, U.S.A.
Zheming Wang
Affiliation:
Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99352, U.S.A.
Liyu Li
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington 99352, U.S.A.
Denis M. Strachan
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington 99352, U.S.A.
Yali. Su
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington 99352, U.S.A.
A.G. Joly
Affiliation:
Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99352, U.S.A.
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Abstract

Oxides of lanthanide dissolution in a Na2O-Al2O3-B2O3-SiO2 glass using Gd as a probe was studied in detail using Raman, fluorescence, and phonon sideband (PSB) spectroscopic techniques. A mechanism of Gd cation dissolution, via partitioning, in the borate-rich and silicate-rich environments was confirmed by examining characteristics of the Raman band evolution, fluorescence emission and lifetime, and PSBs. The study concluded that i) Gd(III) cations in the borate-rich environment resembles Gd-metaborate local structure, i.e., 1BO4:1Gd:2BO3, ii) Gd cations partitioning in the borate-rich environment at low Gd2O3 concentration, [Gd2O3] -1/3[B2O3] < 0, and iii) excess Gd(III) cations, [Gd2O3]–1/3[B2O3], in the silicate-rich environment at high Gd2O3 concentration, [Gd2O3]–1/3[B2O3]>0.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 702: Symposium U – Advanced Fibers, Plastics, Laminates and Composites , 2001 , U8.1.1
Copyright
Copyright © Materials Research Society 2002

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References

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