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Dissolution Testing of a Metallic Waste Form in Chloride Brine

Published online by Cambridge University Press:  19 October 2011

Dawn E. Janney*
Affiliation:
dawn.janney@inl.gov, Idaho National Laboratory, Nuclear Fuels and Materials, P.O. Box 1625, Idaho Falls, ID, 83415-6188, United States, 208-533-7478, 208-533-7996
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Abstract

Argonne National Laboratory has developed an electrometallurgical process for conditioning spent sodium-bonded metallic reactor fuel from the Experimental Breeder Reactor II (EBR-II). One waste stream from this process consists of a metal waste form (MWF) whose baseline composition is stainless steel alloyed with 15 wt% Zr (SS-15Zr) and whose microstructure is a eutectic intergrowth of iron solid solutions and Fe-Zr-Cr-Ni intermetallics. This paper reports scanning electron microscope (SEM) observations of corrosion products formed during static immersion tests in which coupons of surrogate MWF containing 10 wt% U (SS-15Zr-10U) were immersed in solutions with nominal pH values of 3 and 4 and 1000 ppm added chloride for 70 days at 50 °C. Although the majority of the surface areas of the coupons appear unchanged, linear areas with localized corrosion products apparently consisting of porous materials overlying corrosion-product-filled channels formed on both coupons, cross-cutting phase boundaries in the original eutectic microstructures. Many of the linear areas intersected the sample edge at notches present before the tests or followed linear flaws visible in pre-test images. Compositions of corrosion products differed significantly from the bulk composition, and the maximum observed concentration of U exceeded that reported in actinide-bearing phases in uncorroded surrogate MWF samples with comparable concentrations of U.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

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References

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