Hostname: page-component-8448b6f56d-mp689 Total loading time: 0 Render date: 2024-04-18T01:27:47.468Z Has data issue: false hasContentIssue false
  • English
  • Français

Effects of Alpha and Gamma Radiation on Glass Reaction in an Unsaturated Environment

Published online by Cambridge University Press:  28 February 2011

David J. Wronkiewicz ,
John E. Young  and
John K. Bates
David J. Wronkiewicz
Affiliation:
Chemical Technology Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837
John E. Young
Affiliation:
Chemical Technology Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837
John K. Bates
Affiliation:
Chemical Technology Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837
Get access

Abstract

Radiation may effect the long-term performance of glass in an unsaturated repository site by interacting with air, water vapor, or liquid water. The present study examines (1) the effects of alpha or gamma irradiation in a water vapor environment, and (2) the influence of radiolytic products on glass reaction. Results Indicate that nitric and organic acids form in an irradiated water vapor environment and are dissolved in thin films of condensed water. Glass samples exposed to these conditions react faster and have a different assemblage of secondary phases than glasses exposed to nonirradiated water vapor environments.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 212: Symposium P – Scientific Basis for Nuclear Waste Management XIV , 1990 , 99
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Pederson, L. R. and McVay, G. L., J. Am. Ceram. Soc. 66, 863–867 (1983).CrossRefGoogle Scholar
2. McVay, G. L., Weber, W. J., and Pederson, L. R., Nucl. and Chem. Waste Mgmt. 2, 103–108 (1981).CrossRefGoogle Scholar
3. Weber, W. J., Nucl. Inst, and Methods in Phys. Res. B32, 471–479 (1988).Google Scholar
4. Burns, W. G., Hughes, A. E., Marples, J. A. C., Nelson, R. S., and Stoneham, A. M., J. Nucl. Mater. 107, 245 (1982).CrossRefGoogle Scholar
5. Barkatt, A., Barkatt, A., and Sousanpour, W., Nucl. Tech. 60, 218–227 (1983).Google Scholar
6. McVay, G. L. and Pederson, L. R., J. Am. Ceram. Soc. 64, 154–158 (1984).Google Scholar
7. Bates, J. K., Fischer, D. F., and Gerding, T. J., Argonne National Laboratory report ANL-86-62 (1986).Google Scholar
8. Bates, J. K., Gerding, T. J., Fischer, D. F., and Ebert, W. L., Lawrence Livermore National Laboratory report UCRL-15991 (1987).Google Scholar
9. Abrajano, T. A. Jr., Bates, J. K., Gerding, T. J., and Ebert, W. L., Argonne National Laboratory report ANL-88-14 (1988).Google Scholar
10. Ebert, W. L., Bates, J. K., and Gerding, T. J., Argonne National Laboratory report ANL-90/13 (1990).Google Scholar
11. Ebert, W. L., Bates, J. K., Abrajano, T. A. Jr., and Gerding, T. J., Ceram. Trans. 9, 155–164 (1990).Google Scholar
12. Aubar, M. et al., NSRDS-NBS-43 (1973).Google Scholar
13. Walters, W. S. and Wisberg, S. J., AERE Report R-11984 (1986).Google Scholar
14. Site Characterization Plan, U.S. Department of Energy, Office of Civilian Radioactive Waste Management, DOE Report DOE-RW-0199 (1988).Google Scholar
15. Baxter, R. G., Savannah River Laboratory report DP-1606 (1988).Google Scholar
16. Aines, R. D., Am. Ceram. Soc., 3rd Inter. Symp. on Nuclear Waste Disposal, Chicago, IL, 1986.Google Scholar
17. Linacre, J. K. and Marsh, W. R., AERE Report R-10027 (1981).Google Scholar
18. Lind, S. C., Radiation Chemistry of Gases, Am. Chem. Soc. Monograph Ser., Relnhold Publishing Corp., NY (1961).Google Scholar
19. Bates, J. K., Abrajano, T. A. Jr., Ebert, W. L., Mazer, J. J., and Gerding, T. J., Mat. Res. Soc. Symp. Proc. Vol. 123, 237–244 (1989).CrossRefGoogle Scholar
20. Ebert, W. L. and Bates, J. K., Mat. Res. Soc. Symp. Proc. Vol. 176, 339–346 (1990).Google Scholar
21. Yokayama, H., Hermansson, H. P., Christenson, H., Bjorner, I. K., and Werme, L., Mat. Res. Soc. Symp. Proc. Vol. 44, 601–608 (1985).Google Scholar
22. Abrajano, T. A. Jr., Bates, J. K., and Mazer, J. J., J. Non-Cryst. Sol. 108, 269–288 (1989).CrossRefGoogle Scholar
23. Reed, D. T. and Van Konynenburg, R. A., Am. Nucl. Soc. Symp., Las Vegas, Nevada, 1991 (in press).Google Scholar