Hostname: page-component-8448b6f56d-cfpbc Total loading time: 0 Render date: 2024-04-24T00:14:05.174Z Has data issue: false hasContentIssue false
  • English
  • Français

Pillaring of Layered Double Hydroxides Possessing Variable Layer Charge with Vanadium Polyoxoanions

Published online by Cambridge University Press:  28 February 2011

F. Kooli ,
V. Rives ,
M.A. Ulibarri  and
W. Jones
F. Kooli
Affiliation:
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
V. Rives
Affiliation:
Departamento de Química Inorgánica, Universidad de Salamanca, Facultad de Farmacia, 37007 Salamanca, Spain
M.A. Ulibarri
Affiliation:
Departamento de Química Inorgánica e Ingeniería Qufmíca, Facultad de Ciencias, Universidad de Córdoba, 14004 Córdoba, Spain
W. Jones
Affiliation:
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
Get access

Abstract

A range of layered double hydroxides (LDHs) with Ni/Al and Mg/Al as the M(II)/M(III) cations and containing carbonate as the charge balancing anion have been synthesised. A variation in the M(II)/M(III) ratio between 2 and 6 has been attempted with the influence of the M(II)/M(III) ratio upon the subsequent exchange of carbonate by [V10O28]6- (at pH 4.5) examined. Complete exchange is obtained for all ratios, although the crystallinity of the products varies. For M(II)/M(III) ratios > 4, the product crystallinity is poor. In addition, a second phase is detected for all ratios. In the case of Ni/Al, the amount of vanadium incorporated is found to depend upon the Al content whereas for Mg/Al the amount incorporated is constant. Overall, the replacement of carbonate by decavanadate does not appear to have any significant effect on the textural characteristics (e.g. surface area or porosity) of the pillared products.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 371: Symposium W1 – Advances in Porous Materials , 1994 , 143
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Catalysis Today - Pillared Clays, edited by Burch, R. (Elsevier, Amesterdam, 1988).Google Scholar
2. Cavani, F., Trifiro, F., and Vaccari, A.. Catal. Today 11, 173 (1991)Google Scholar
3. Reichle, W.T., J. Catal. 94, 547 (1985).Google Scholar
4. Jones, W., and Chibwe, M., in Pillared Layered Structures: Current Trends and Applications, edited by Mitchell, I. V. (Elsevier Applied Sciences, London, 1990) pp. 67–77.Google Scholar
5. Yamanaka, S., and Brindley, G.W., Clays Clay Miner. 27, 119 (1979).Google Scholar
6. Drezdzon, M.A., Inorg. Chem. 27, 4682 (1988).Google Scholar
7. Chibwe, K., and Jones, W., Chem. Mater. 1, 489 (1989).Google Scholar
8. Twu, J., and Dutta, K., J. Phys. Chem. 93, 7863 (1989).Google Scholar
9. Kwon, T., Pinnavaia, J.T., Chem. Mater. 1, 381 (1989).Google Scholar
10. Kwon, T., Tsigdinos, G.A., and Pinnavaia, J.T., J. Amer. Chem. Soc. 110, 3653 (1988).Google Scholar
11. Twu, J., and Dutta, P.K., J. Catal. 124, 503 (1990).Google Scholar
12. Dimotakis, E.D., and Pinnavaia, T.J., Inorg. Chem. 29, 2393 (1990).Google Scholar
13. Wang, J., Tiam, Y., Wang, R-C., and Clearfield, A., Chem. Mater. 4, 1276 (1992).Google Scholar
14. Reichle, W.T., Solid State Ionics. 22, 135 (1986).Google Scholar
15. Pausch, L., Lohse, H., Schurmann, K., and Allmann, R., Clays Clay Miner. 34, 507 (1986).Google Scholar
16. Mascolo, G., and Marino, O., Miner. Mag. 43, 619 (1980).Google Scholar
17. Narita, E., Kaviratna, P., and Pinnavaia, T.J., J. Chem. Letters. 1991, 805.Google Scholar
18. Rives, V., Kooli, F., and Jones, W., 1993 (unpublished).Google Scholar
19. Lopez Salinas, E., and Ono, Y., Bull. Chem. Soc. Jpn, 65, 2465 (1992).Google Scholar
20. Kooli, F., Rives, V., and Ulibarri, M.A., Mater.Sci. Forum. 152–153, 375 (1994).Google Scholar
21. Ulibarri, M.A., Labajos, F.M., Rives, V., Trujillano, R., Kagunya, W., and Jones, W.. Inorg. Chem. 33, 2592 (1994).Google Scholar
22. Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R., Rouquerol, J., and Sieminiewska, T., Pure Appl. Chem. 57, 603 (1985).Google Scholar
23. Kooli, F., Rives, V., and Ulibarri, M.A.. (1994) Submitted to Inorg. Chem.Google Scholar
24. Kagunya, W., and Jones, W., in Multifunctional mesoporous Inorganic Solids, edited by Sequiera, Cesar A.C. and Hudson, Michael J. (Kluwer Academic Publishers, Dordrecht 1993) pp 217–224.Google Scholar
25. Mao, G., Tsuji, M., and Tamaura, Y., Clays Clay Minerals. 41, 731 (1993).Google Scholar