Hostname: page-component-8448b6f56d-tj2md Total loading time: 0 Render date: 2024-04-24T15:06:40.474Z Has data issue: false hasContentIssue false
  • English
  • Français

Organic-Inorganic Hybrid Materials From Surface Initiated Polymerization

Published online by Cambridge University Press:  10 February 2011

Thomas A. P. Seery  and
Fatma Vatansever
Thomas A. P. Seery
Affiliation:
Department of Chemistry and Polymer Program, University of Connecticut, Storrs CT, 06269, seery@mail.ims.uconn.edu
Fatma Vatansever
Affiliation:
Department of Chemistry and Polymer Program, University of Connecticut, Storrs CT, 06269, seery@mail.ims.uconn.edu
Get access

Abstract

A new technique in surface modification is presented where chain growth polymerizations are initiated from tethered ruthenium alkylidene catalysts and organic-inorganic hybrid materials are produced. This approach provides nearly complete control over the polymer layer at the organic-inorganic interface with independent control over the chain length and grafting density. Hybrid particles are characterized using standard methods, i.e. NMR and transmission IR.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 45
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

(1) Alexander, S. J de Phys. 1977, 38, 983–987.10.1051/jphys:01977003808098300Google Scholar
(2) Degennes, P. G. J. de Phys. 1976, 37, 1445–1452.10.1051/jphys:0197600370120144500Google Scholar
(3) Degennes, P. G. Macromolecules 1980, 13, 1069–1075.10.1021/ma60077a009Google Scholar
(4) Milner, S. T. Journal of Polymer Science: Part B; Polymer Physics Edition 1994, 32, 2743–2755.10.1002/polb.1994.090321620Google Scholar
(5) Milner, S. T. Science 1991, 251, 905–914.10.1126/science.251.4996.905Google Scholar
(6) Laub, C. F.; Koberstein, J. T. Macromolecules 1994, 27, 5016–5023.10.1021/ma00096a025Google Scholar
(7) Halperin, A. Journal of Macromolecular Science-Pure and Applied Chemistry 1992, 29, 107–116.10.1080/10101329208054571Google Scholar
(8) Milner, S. T.; Witten, T. A.; Cates, M. E. Macromolecules 1988, 21, 2610–2619.10.1021/ma00186a051Google Scholar
(9) Tovar, G.; Paul, S.; Knoll, W.; Prucker, O.; Ruhe, J. Supramolecular Science 1995, 2, 89–98.10.1016/0968-5677(96)89073-0Google Scholar
(10) Prucker, O.; Ruhe, J. Grafting of Polymers to Solid Surfaces by Using Immobilized Azoinitiators, 1993; Vol. 304, pp 163–172.Google Scholar
(11) Prucker, O.; Ruhe, J. Macromolecules 1998, 31, 592–601.10.1021/ma970660xGoogle Scholar
(12) Prucker, O.; Ruhe, J. Macromolecules 1998, 31, 602–613.10.1021/ma970661pGoogle Scholar
(13) Domack, A.; Prucker, O.; Ruhe, J.; Johannsmann, D. Physical Review E 1997, 56, 680–689.10.1103/PhysRevE.56.680Google Scholar
(14) Petekidis, G.; Vlassopoulos, D.; Galda, P.; Rehahn, M.; Ballauff, M. Macromolecules 1996, 29, 8948–8953.10.1021/ma961128xGoogle Scholar
(15) Mansky, P.; Liu, Y.; Huang, E.; Russell, T. P.; Hawker, C. Science 1997, 275, 1458–1460.10.1126/science.275.5305.1458Google Scholar
(16) Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. Journal of the Chemical Society, Chemical Communications 1994, 801–802.10.1039/C39940000801Google Scholar
(17) Brust, M.; Fink, J.; Bethell, D.; Schiffrin, D. J.; Kiely, C. Journal of the Chemical Society, Chemical Communications 1995, 1655–1656.10.1039/c39950001655Google Scholar
(18) Huber, D. L.; Carlson, G.; Gonsalves, K. E.; Seery, T. A. P. ACS Division of Polymeric Materials: Science and Engineering Preprints 1996, 75, 265–266.Google Scholar
(19) Huber, D. L.; Gonsalves, K. E.; Carlson, G.; Seery, T. A. P. The Formation of Polymer Monolayers: From Adsorption to Surface Initiated Polymerizations; Lohse, D. J., Russell, T. P. and Sperling, L., Ed.; Plenum, 1997, pp 107–122.Google Scholar
(20) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H. Journal of the American Chemical Society 1992, 114, 3974–3975.10.1021/ja00036a053Google Scholar