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The effects of surface modifications of multiwalled carbon nanotubes on their dispersibility in different solvents and poly(ether ether ketone)

Published online by Cambridge University Press:  14 October 2014

Zongshuang Cao ,
Li Qiu ,
Yongzhen Yang ,
Yongkang Chen  and
Xuguang Liu
Zongshuang Cao
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Research Center of Advanced Material Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China
Li Qiu
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Yongzhen Yang*
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Research Center of Advanced Material Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China
Yongkang Chen*
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China; and University of Hertfordshire, School of Engineering and Technology, Hatfield, Hertfordshire AL10 9AB, UK
Xuguang Liu
Affiliation:
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
*
a)Address all correspondence to these authors. e-mail: yyztyut@126.com
b)e-mail: y.k.chen@herts.ac.uk
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Abstract

The effects of surface modifications of multiwalled carbon nanotubes (MWCNTs) on their dispersibility in different solvents and poly(ether ether ketone) (PEEK) have been studied. MWCNTs were treated by mixed acids to obtain acid-functionalized MWCNTs. The acid-functionalized MWCNTs were modified with five different chemical agents separately, 1,6-diaminohexane, hexadecyltrimethyl ammonium bromide, silane coupling agent 3-aminopropyltriethoxysilane, anhydrous sulfanilic acid, and ethanolamine. Multiwalled carbon nanotube and PEEK (MWCNT/PEEK) composite films were fabricated to explore systematically the dispersibility of differently modified MWCNTs in PEEK as well as in different solvents. The morphology and structures of MWCNTs and the compatibility between MWCNTs and PEEK have been investigated. It was observed that the MWCNTs modified with anhydrous sulfanilic acid have an excellent dispersion in the PEEK grafted by sulfonic acid groups and that the MWCNTs modified with ethanolamine are also dispersed well in pure PEEK. The results herein provide useful insights into the development of MWCNT/PEEK composites for a wide variety of applications.

Keywords

surface chemistrypolymercomposite
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 22 , 28 November 2014 , pp. 2625 - 2633
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Moniruzzaman, M. and Winey, K.I.: Polymer nanocomposites containing carbon nanotubes. Macromolecules 39, 5194 (2006).Google Scholar
Coleman, J.N., Khan, U., Blau, W.J., and Gun’ko, Y.K.: Small but strong: A review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44, 1624 (2006).CrossRefGoogle Scholar
Yao, N., Lordi, V., and Ma, S.X.C.: Structure and oxidation patterns of carbon nanotubes. J. Mater. Res. 13, 2432 (1998).Google Scholar
Diez-Pascual, A.M., Naffakh, M., Gonzalez-Dominguez, J.M., Anson, A., Martinez-Rubi, Y., Martinez, M.T., Simard, B., and Gomez, M.A.: High performance PEEK/carbon nanotube composites compatibilized with polysulfones-I structure and thermal properties. Carbon 48, 3485 (2010).CrossRefGoogle Scholar
Pham, J.Q., Mitchell, C.A., Bahr, J.L., Tour, J.M., Krishanamoorti, R., and Green, P.F.: Glass transition of polymer/single-walled carbon nanotube composite films. J. Polym. Sci., Part B: Polym. Phys. 41, 3339 (2003).Google Scholar
Kim, J.Y., Park, H.S., and Kim, S.H.: Unique nucleation of multi-walled carbon nanotubes and poly(ethylene 2,6-naphthalate) nanocomposites during non-isothermal crystallization. Polymer 47, 1379 (2006).CrossRefGoogle Scholar
Barraza, H.J., Pompeo, F., O’Rear, E.A., and Resasco, D.E.: SWNT-filled thermoplastic and elastomeric composites prepared by miniemulsion polymerization. Nano Lett. 2, 797 (2002).CrossRefGoogle Scholar
Spitalsky, Z., Tasis, D., Papagelis, K., and Galiotis, C.: Carbon nanotube-polymer composites: Chemistry, processing, mechanical and electrical properties. Prog. Polym. Sci. 35, 357 (2010).CrossRefGoogle Scholar
Diez-Pascual, A.M. and Naffakh, M.: Grafting of an aminated poly(phenylene sulphide) derivative to functionalized single-walled carbon nanotubes. Carbon 50, 857 (2012).Google Scholar
Diez-Pascual, A.M., Naffakh, M., Gomez, M.A., Marco, C., Ellis, G., Gonzalez-Dominguez, J.M., Anson, A., Martinez, M.T., Martinez-Rubi, Y., Simard, B., and Ashrafi, B.: The influence of a compatibilizer on the thermal and dynamic mechanical properties of PEEK/carbon nanotube composites. Nanotechnol. 20, 315707 (2009).CrossRefGoogle ScholarPubMed
Monthioux, M., Smith, B.W., Burteaux, B., Claye, A., Fischer, J.E., and Luzzi, D.E.: Sensitivity of single-wall carbon nanotubes to chemical processing: An electron microscopy investigation. Carbon 39, 1251 (2001).CrossRefGoogle Scholar
Cebe, P., Chung, S.Y., and Hong, S.D.: Effect of thermal history on mechanical properties of poly(ether ether ketone) below the glass transition temperature. J. Appl. Polym. Sci. 33, 487 (1987).Google Scholar
Searle, O.B. and Pfeiffer, R.H.: Victrex® poly (ethersulfone) (PES) and Victrex® poly (ether ether ketone) (PEEK). Polym. Eng. Sci. 25, 474 (1985).Google Scholar
Deng, F., Ogasawara, T., and Takada, N.: Experimental characterization of poly(ether ether ketone)/multi-wall carbon nanotube composites. Key Eng. Mater. 334–335, 721 (2007).Google Scholar
Song, L., Zhang, H., Zhang, Z., and Xie, S.S.: Processing and performance improvements of SWNT paper reinforced PEEK nanocomposites. Composites, Part A 38, 388 (2007).Google Scholar
Diez-Pascual, A.M., Naffakh, M., Gonzalez-Dominguez, J.M., Anson, A., Martinez-Rubi, Y., Teresa Martinez, M., Simard, B., and Gomez, M.A.: High performance PEEK/carbon nanotube composites compatibilized with polysulfones-II. Mechanical and electrical properties. Carbon 48, 3500 (2010).Google Scholar
Xie, W.L., Mai, Y.W., and Zhou, X.P.: Dispersion and alignment of carbon nanotubes in polymer matrix: A review. Mater. Sci. Eng. 49, 89 (2005).CrossRefGoogle Scholar
Sydlik, S.A., Lee, J.H., Walish, J.J., Thomas, E.L., and Swager, T.M.: Epoxy functionalized multi-walled carbon nanotubes for improved adhesives. Carbon 59, 109 (2013).Google Scholar
Ming, J., Wu, Y.Q., Yu, Y.C., and Zhao, F.Y.: Steaming multiwalled carbon nanotubes via acid vapour for controllable nanoengineering and the fabrication of carbon nanoflutes. Chem. Commun. 47, 5223 (2011).CrossRefGoogle ScholarPubMed
Sun, Y., Wilson, S.R., and Schuster, D.I.: High dissolution and strong light emission of carbon nanotubes in aromatic amine solvents. J. Am. Chem. Soc. 123, 5348 (2001).CrossRefGoogle ScholarPubMed
Zhang, X.T., Zhang, J., Wang, R.M., and Liu, Z.F.: Cationic surfactant directed polyaniline/CNT nanocables: Synthesis, characterization, and enhanced electrical properties. Carbon 42, 1455 (2004).Google Scholar
Kathi, J., Rhee, K.Y., and Lee, J.H.: Effect of chemical functionalization of multi-walled carbon nanotubes with 3-aminopropyltriethoxysilane on mechanical and morphological properties of epoxy nanocomposites. Composites, Part A 40, 800 (2009).CrossRefGoogle Scholar
Szabo, T., Berkesi, O., and Dekany, I.: Drift study of deuterium-exchanged graphite oxide. Carbon 43, 3186 (2005).Google Scholar
Matarredona, O., Rhoads, H., Li, Z.R., Harwell, J., Balzano, L., and Resasco, D.E.: Dispersion of single-walled carbon nanotubes in aqueous solutions of the anionic surfactant NaDDBS. J. Phys. Chem. B. 107, 13357 (2003).Google Scholar
Datsyuk, V., Kalyva, M., Papagelis, K., Parthenios, J., Tasis, D., Siokou, A., Kallitsis, I., and Galiotis, C.: Chemical oxidation of the multiwalled carbon nanotubes. Carbon 46, 833 (2008).CrossRefGoogle Scholar
Zhang, J., Zou, H.L., Qing, Q., Yang, Y.L., Li, Q.W., Liu, Z.F., Guo, X.Y., and Du, Z.L.: Effect of chemical oxidation on the structure of single-walled carbon nanotubes. J. Phys. Chem. B 107, 3712 (2003).CrossRefGoogle Scholar
Nakamura, K., Fujitsuka, M., and Kitajima, M.: Finite size effect on Raman scattering of graphite microcrystals. Chem. Phys. Lett. 172, 205 (1990).Google Scholar
Bacsa, W.S., Heer, W.A., Ugarte, D., and Chatelain, A.: Raman spectroscopy of closed-shell carbon particles. Chem. Phys. Lett. 211, 346 (1993).CrossRefGoogle Scholar
Kastner, J., Pichler, T., Kuzmany, H., Curran, S., Blau, W., Delamesiere, D.N., Draper, S., and Zandbergen, H.: Resonance Raman and infrared spectroscopy of carbon nanotubes. Chem. Phys. Lett. 221, 53–58 (1994).Google Scholar
Nie, Z.H., Fava, D., Kumacheva, E., Zou, S., Walker, G.C., and Rubinstein, M.: Self-assembly of metal-polymer analogues of amphiphilic triblock copolymers. Nat. Mater. 6, 609 (2007).Google Scholar
Fouconnier, B., Guerrero, A.R., and Carter, E.J.V.: Effect of [CTAB]-[SiO2] ratio on the formation and stability of hexadecane/water emulsions in the presence of NaCl. Colloids Surf., A 400, 10 (2012).CrossRefGoogle Scholar