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Phosphorus-Vacancy-Related Deep Levels in Gainp Layers Grown by Molecular Beam Epitaxy

Published online by Cambridge University Press:  22 February 2011

Z.C. Huang
Affiliation:
Department of Electrical and Computer Engineering and Center for Electronic and Electro-optic Materials, State University of New York at Buffalo, Bonner Hall, Buffalo, NY 14260
C.R. Wie
Affiliation:
Department of Electrical and Computer Engineering and Center for Electronic and Electro-optic Materials, State University of New York at Buffalo, Bonner Hall, Buffalo, NY 14260
J.A. Varriano
Affiliation:
The Institute of Optics, University of Rochester, Rochester, NY 14627
M.W. Koch
Affiliation:
The Institute of Optics, University of Rochester, Rochester, NY 14627
G.W. Wicks
Affiliation:
The Institute of Optics, University of Rochester, Rochester, NY 14627
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Abstract

Deep levels in lattice matched Ga0.51In0.49P/GaAs heterostructure have been investigated by thermal-electric effect spectroscopy(TEES) and temperature dependent conductivity measurements. Four samples were grown by molecular beam epitaxy with various phosphorus (P2) beam equivalent pressure(BEP) of 0.125, 0.5, 2, and 4×10−4 Torr. We report for the first time, to our knowledge, an electrical observation of phosphorus vacancy point defects in the GaInP/GaAs material system. The phosphorus vacancies, Vp. behave as an electron trap which is located at EC−0.28±0.02 eV. We have found that this trap dominates the conduction band conduction when T> 220K, and is responsible for the variable-range hopping conduction when T < 220K. Its concentration decreases with the increasing phosphrous BEP. Successive rapid thermal annealing showed that its concentration increases with the increasing annealing temperature. Another electron trap at EC−0.51eV was also observed only in samples with P2 BEP less than 2×10−4 Torr. Its capture cross section is 4.5×10−15 cm 2 as obtained from the illumination time dependent TEES spectra.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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