Hostname: page-component-8448b6f56d-c4f8m Total loading time: 0 Render date: 2024-04-16T13:22:30.753Z Has data issue: false hasContentIssue false

Surface Conversion Effects in Plasma-Damaged p-GaN

Published online by Cambridge University Press:  03 September 2012

X.A. Cao
Affiliation:
Dept. Materials Science and EngineeringUniversity of Florida, Gainesville, FL 32611
S.J. Pearton
Affiliation:
Dept. Materials Science and EngineeringUniversity of Florida, Gainesville, FL 32611
G.T. Dang
Affiliation:
Dept. Chemical EngineeringUniversity of Florida, Gainesville, FL 32611
A.P. Zhang
Affiliation:
Dept. Chemical EngineeringUniversity of Florida, Gainesville, FL 32611
F. Ren
Affiliation:
Dept. Chemical EngineeringUniversity of Florida, Gainesville, FL 32611
R.J. Shul
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
L. Zhang
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
R. Hickman
Affiliation:
SVT Associates, Eden Prairie, MN 55344
J.M. Van Hove
Affiliation:
SVT Associates, Eden Prairie, MN 55344
Get access

Abstract

The near-surface (400-500Å) of p-GaN exposed to high density plasmas is found to become more compensated through the introduction of shallow donors. At high ion fluxes or ion energies there can be type-conversion of this surface region. Two different methods for removal of the damaged surface were investigated; wet etching in KOH, which produced self-limiting etch depths or thermal annealing under N2 which largely restored the initial electrical properties.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Shul, R.J., Zhang, L., Baca, A.G., Willison, C.G., Han, J., Pearton, S.J., Ren, F., Zolper, J.C. and Lester, L.F., “High Density Plasma-Induced Etch Damage in GaN”, Mat. Res. Soc. Symp. Proc. Vol. 573, 271 (1999).Google Scholar
2. Eddy, C.R. Jr., and Molnar, B., “The Effect of H2-Based Etching on GaN”, Mat. Res. Soc. Symp. Proc. 395, 745 (1996); “Plasma Etch-Induced Conduction Changes in GaN”, J. Electron. Mater. 28, 314 (1999).Google Scholar
3. Pearton, S.J., Lee, J.W., MacKenzie, J.D., Abernathy, C.R. and Shul, R.J., “Dry Etch Damage in InN, InGaN and InAlN”, Appl. Phys. Lett. 67, 2329 (1995).Google Scholar
4. Ren, F., Lothian, J.R., Pearton, S.J., Abernathy, C.R., Vartuli, C.B., MacKenzie, J.D., Wilson, R.G. and Karlicek, R.F., “Effects of Dry Etching of Surface Properties of III-Nitrides”, J. Electron. Mater. 26, 1287 (1997).Google Scholar
5. Ren, F., Lothian, J.R., Chen, Y.K., MacKenzie, J.D., Donovan, S.M., Vartuli, C.B., Abernathy, C.R., Lee, J.W. and Pearton, S.J., “Effect of BCl3 Dry Etching on AlInN Surface Properties”, J. Electrochem. Soc. 143, 1217 (1996).Google Scholar
6. Ping, A.T., Schmitz, A.C., Adesida, I., Khan, M.A., Chen, A. and Yang, Y.W., “Characterization of RIE Damage to GaN using Schottky Diodes”, J. Electron. Mater. 26, 266 (1997).Google Scholar
7. Ping, A.T., Chen, Q., Yang, J.W., Khan, M.A. and Adesida, I., “The Effects of RIE Damage on Ohmic Contacts to n-GaN”, J. Electron. Mater. 27, 261 (1998).Google Scholar
8. Chen, J.Y., Pan, C.J. and Chi, G.C., “Electrical and Optical Changes in the Near-Surface of GaN”, Solid-State Electron. 43, 649 (1999).Google Scholar
9. Ren, F., Lothian, J.R., Chen, Y.K., Karlicek, R., Tran, L., Schurmann, M., Stall, R., Lee, J.W. and Pearton, S.J., “Recessed Gate GaN FET”, Solid-State Electron. 41, 1819 (1997).Google Scholar
10. Shul, R.J., Zolper, J.C., Crawford, M.H., Hickman, R.J., Briggs, R.D., Pearton, S.J., Lee, J.W., Karlicek, R., Tran, C., Schurmann, M., Constantine, C. and Barratt, C., “Plasma-Induced Damage in GaN”, Proc. Electrochem. Soc. 96–15, 232 (1996).Google Scholar
11. Usikov, A.S., Lundin, W.L., Ushakov, U.I., Pushnyi, B.V., Schmidt, N.N., Zadiranov, Y.Y. and Shubtra, T.V., “Electrical and Optical Properties of GaN After Dry Etching”, Proc. Electrochem. Soc. 97–14, 57 (1998).Google Scholar
12. Satore, K., Matsutani, A., Shirasawa, T., Mori, M., Honda, T., Sakaguchi, T., Kagana, F. and Iga, K., “RIBE of GaN”, Mat. Res. Soc. Symp. Proc. 449, 1029 (1997).Google Scholar
13. McCarthy, L.S., Kozodoy, P., DenBaars, S.D., Rodwell, M. and Mishra, U.K., 25th Int. Symp. Compound Semicond., Oct. 1998, Nara, Japan.Google Scholar
14. Ren, F., Abernathy, C.R., Hove, J.M. Van, Chow, P.P., Hickman, R., Klaassen, J.J., Kopf, R.F., Cho, H., Jung, K.B., Wilson, R.G., Han, J., Shul, R.J., Baca, A.G. and Pearton, S.J., “300°C GaN HBT”, MRS Internet J. Nitride Semicond. Res. 3, 41 (1998).Google Scholar
15. Han, J., Baca, A.G., Shul, R.J., Willison, C.G., Zhang, L., Ren, F., Zhang, A.P., Dang, G.T., Donovan, S.M., Cao, X.A., Cho, H., Jung, K.B., Abernathy, C.R., Pearton, S.J. and Wilson, R.G., “Growth and Fabrication of GaN HBT”, Appl. Phys. Lett. 74, 2702 (1999).Google Scholar
16. Yoshida, S. and Suzuki, J., “High Temperature Reliability of GaN MESFET and BJT”, J. Appl. Phys. 85, 7931 (1999).Google Scholar
17. Pearton, S.J., “RIE of Compound Semiconductors”, Int. J. Mod. Phys. B 8, 1781 (1994).Google Scholar
18. Hove, J.M. Van, Hickman, R., Klaassen, J.J., Chow, P.P. and Ruden, P.P., “High Quality GaN Grown by rf-MBE”, Appl. Phys. Lett. 70, 282 (1997).Google Scholar
19. Kim, B.J., Lee, J.W., Park, H.S. and Kim, T.I., “Wet Etching of GaN Grown by OMVPE”, J. Electron. Mater. 27, L32 (1998).Google Scholar
20. Stocker, S.A., Schubert, E.F. and Redwing, J.M., “Crystallographic Wet Etching of GaN”, Appl. Phys. Lett. 73, 2345 (1998).Google Scholar
21. Lee, J.-L., Kim, J.K, Lee, J.W., Park, Y.J. and Kim, T., “Effect of Surface Treatment by KOH on p-Ohmic Contacts to GaN”, Solid-State Electron. 43, 435 (1999).Google Scholar
22. Sze, S.M., Physics of Semiconductor Devices (Wiley-Interscience, NY, 1981).Google Scholar
23. Zolper, J.C., Rieger, D.J., Baca, A.G., Pearton, S.J., Lee, J.W. and Stall, R.A., “Sputtered AlN for Annealing GaN”, Appl. Phys. Lett. 69, 538 (1996).Google Scholar
24. Brown, J., Ramer, J., Zhang, K., Lester, L.F., Hersee, S.D. and Zolper, J.C., “ECR Etching of GaN With and Without H2 ”, Mat. Res. Soc. Symp. Proc. Vol. 395, 702 (1996).Google Scholar
25. Cao, X.A., Cho, H., Pearton, S.J., Dang, G.T., Zhang, A., Ren, F., Shul, R.J., Zhang, L., Ren, F., Shul, R.J., Zhang, L., Baca, A.G., Hickman, R. and Hove, J.M. Van, “Depth and Thermal Stability of Dry Etch Damage in GaN Schottky Diodes”, Appl. Phys. Lett. 75, 232 (1999).Google Scholar