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Waste Glass Weathering

Published online by Cambridge University Press:  25 February 2011

John K. Bates
Affiliation:
Argonne National Laboratory, Chemical Technology Division, 9700 South Cass Avenue, Argonne, IL 60439-4837.
Edgar C. Buck
Affiliation:
Argonne National Laboratory, Chemical Technology Division, 9700 South Cass Avenue, Argonne, IL 60439-4837.
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Abstract

The weathering of glass is reviewed by examining processes that affect the reaction of commercial, historical, natural, and nuclear waste glass under conditions of contact with humid air and slowly dripping water, which may lead to immersion in nearly static solution. Radionuclide release data from weathered glass under conditions that may exist in an unsaturated environment are presented and compared to release under standard leaching conditions. While the comparison between the release under weathering and leaching conditions is not exact, due to variability of reaction in humid air, evidence is presented of radionuclide release under a variety of conditions. These results suggest that both the amount and form of radionuclide release can be affected by the weathering of glass.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1 Lutze, W. and Ewing, R. C., Radioactive Waste Forms for the Future. North-Holland, pp. 1159(1988).Google Scholar
2 Site Characterization Plan, U.S. Department of Energy, Office of Civilian Radioactive Waste Management, DOE Report DOE/RW-0199 (1988).Google Scholar
3 Bates, J. K., Seitz, M. G., and Steindler, M. J., Nucl. Chem. Waste Mgmt. 5, 6373 (1984).CrossRefGoogle Scholar
4 Ryerson, F. J., Lawrence Livermore National Laboratory Report SIP-WF-02 (1992).Google Scholar
5 ASTM Standard C1174-91, American Society for Testing and Materials, Philadelphia, pp. 1–14(1991).Google Scholar
6 Wilder, D. G., Lawrence Livermore National Laboratory Report UCRL-JC--110677 (1993).Google Scholar
7 Dimbleby, V. and Turner, W. E. S., J. Soc. Glass Tech. 23, 242T252T (1939).Google Scholar
8 Stockdale, G. F., and Tooley, F. V., J. Am. Ceram. Soc. 32, 1116 (1950).CrossRefGoogle Scholar
9 Simpson, H. E., J. Am. Ceram. Soc. 42, 337343 (1959).CrossRefGoogle Scholar
10 Walters, H. V. and Adams, P. B., J. Non-Cryst. Sol. 19, 183199 (1975).CrossRefGoogle Scholar
11 Clark, D. E. and Hench, L L., Mat. Res. Soc. Symp. Proc. 15, 113 (1983).CrossRefGoogle Scholar
12 Sanders, D. M. and Hench, L.L., Ceram. Bull. 52, 662669 (1973).Google Scholar
13 Clark, D. E., Pantano, C. D., and Hench, L. L., Corrosion of Glass, Books for Industry, New York (1979).Google Scholar
14 Charles, R. J.,J. Appl. Phys. 29 (11), 15491560 (1959).CrossRefGoogle Scholar
15 Ebert, W. L., Bates, J. K., and Bourcier, W. L., Waste Mgmt. 11, 205221 (1991).CrossRefGoogle Scholar
16 Abrajano, T. A., Bates, J. K., and Mazer, J. J., J. Non-Cryst. Solids 108, 269288 (1989).CrossRefGoogle Scholar
17 Newton, R. G., Glass Technology 26, 2138 (1985).Google Scholar
18 Mazer, J. J., “The Role of Natural Glasses as Analogues in Projecting the Long-Term Alteration of High-Level Nuclear Waste Glasses,” this volume (1994).CrossRefGoogle Scholar
19 Bates, J. K., Bradley, J. P., Teetsov, A., Bradley, C. R., and ten Brink Buchholtz, M., Science 256, 649651 (1992).CrossRefGoogle Scholar
20 Bates, J. K. et al. , Argonne National Laboratory Report ANL-93/13 (1993).Google Scholar
21 Woodland, A. B., Bates, J. K., and Gerding, T. J., Argonne National Laboratory Report ANL-91/36 (1991).Google Scholar
22 Ebert, W. L., Bates, J. K., and Gerding, T. J., Argonne National Laboratory Report AN L-90/13(1990).Google Scholar
23 Bates, J. K., L Ebert, W., and Gerding, T. J., Proc. of the Int. High-Level Radioactive Waste Management Conf., Am. Nucl. Soc, Las Vegas, NV, April 8-12, 1990, p. 1095 (1990).Google Scholar
24 Werme, L., Bjorner, I. K., Bart, G., Zwicky, H. U., Grambow, B., Lutze, W., Ewing, R. C., and Magrabi, C., J. Mater. Res. 5, 11301146 (1990).CrossRefGoogle Scholar
25 Bibler, N. E., Adv. in Ceram. 2Q, 619626 (1986).Google Scholar
26 Bibler, N. E., Savannah River Laboratory Report DP-MS-82-82 (1982).Google Scholar
27 Vernaz, E. Y., Loida, A., Malow, G., Marples, J. A. C., and Matzke, H. J., Third EC Conference on Radioactive Waste Management and Disposal Luxembourg: September 17-21, 1990, EUR-13389, pp. 302-315 (1991).Google Scholar
28 Seitz, M. G., Vandegrift, G. F., Bowers, D. L., and Gerding, T. J., U.S. Nuclear Regulatory Commission Report NUREG/CP-0052 (1984).Google Scholar
29 Kim, J. I., Radiochim. Acta 52/53. 71 -81 (1991).CrossRefGoogle Scholar