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Preparation of Amazingly Hard polyHIPE material from a Direct Emulsion

Published online by Cambridge University Press:  01 February 2011

Carlos Youssef ,
Rénal Backov ,
Mona Treguer ,
Marc Birot  and
Hervé Deleuze
Carlos Youssef
Affiliation:
carlos.joseph@hotmail.fr, Institut des Sciences Moléculaires, UMR-CNRS 5255, 351 cours de la Libération, Université de Bordeaux, 33405 Talence, France
Rénal Backov
Affiliation:
backov@crpp-bordeaux.cnrs.fr, Centre de Recherche Paul Pascal, UPR 8641-CNRS, 115 Avenue Albert Schweitzer, Université de Bordeaux, 33600 Pessac, France
Mona Treguer
Affiliation:
treguer@icmcb-bordeaux.cnrs.fr, Institut de Chimie de la Matière Condensée, UPR 9048-CNRS, 87 Avenue Albert Schweitzer, Université de Bordeaux, 33608 Pessac, France
Marc Birot
Affiliation:
m.birot@ism.u-bordeaux1.fr, Institut des Sciences Moléculaires, UMR-CNRS 5255, 351 cours de la Libération, Université de Bordeaux, 33405 Talence, France
Hervé Deleuze
Affiliation:
herve.deleuze@u-bordeaux1.fr, Institut des Sciences Moléculaires, UMR-CNRS 5255, 351 cours de la Libération, Université de Bordeaux, 33405 Talence, France
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Abstract

Interconnected microcellular polymeric monoliths having unexpected high mechanical strength have been prepared using the High Internal Phase Emulsion methodology. Direct concentrated emulsions of aqueous 5-amino-1-vinyl-[1,2,3,4]tetrazole mixed with low molar (5 %) fractions of N,N'-methylenebisacrylamide (MBA) as cross-linking agent were prepared using dodecane as dispersed phase and a mixture of hydrophilic surfactants. “Reverse” polyHIPE materials were obtained after radical copolymerization, solvent extraction and drying. Their morphology, chemical composition and physico-chemical behaviour are discussed.

Keywords

polymerizationporosityscanning electron microscopy (SEM)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1269: Symposium FF – Polymer Materials and Membranes for Energy Devices , 2010 , 1269-FF03-07
Copyright
Copyright © Materials Research Society 2010

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