Hostname: page-component-8448b6f56d-xtgtn Total loading time: 0 Render date: 2024-04-24T03:39:35.057Z Has data issue: false hasContentIssue false
  • English
  • Français

A Phase Field Model of Solid Electrolyte Interface Formation in Lithium-ion Batteries

Published online by Cambridge University Press:  20 July 2012

Jie Deng ,
Gregory J. Wagner  and
Richard P. Muller
Jie Deng
Affiliation:
Sandia National Laboratories, Livermore, CA 94550, USA
Gregory J. Wagner
Affiliation:
Sandia National Laboratories, Livermore, CA 94550, USA
Richard P. Muller
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185, USA
Get access

Abstract

A phase field model is developed to investigate the formation of a solid electrolyte interface layer on the anode surface in lithium-ion batteries. Numerical results show that the growth of solid electrolyte interface exhibits power-law scaling with respect to time, and the growth rate depends on various factors such as temperature, diffusivity of electrons, and rates of electrochemical reactions.

Keywords

energy storagephase transformationsurface chemistry
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1440: Symposium O – Next-Generation Energy Storage Materials and Systems , 2012 , mrss12-1440-o01-09
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Aurbach, D., in Advances in Lithium-ion Batteries, ed. van Schalkwijk, W. and Scrosati, B. (Springer, New York, 2002) pp 7–79.Google Scholar
2. Peled, E., J. Electrochem. Soc. 126, 2047 (1979).Google Scholar
3. Broussely, M., Herreyre, S., Biensan, P., Kasztejna, P., Nechev, K. and Staniewicz, R. J., J. Power Sources 97–98, 13 (2001).Google Scholar
4. Ploehn, H. J., Ramadass, P. and White, R. E., J. Electrochem. Soc. 151, A456 (2004).Google Scholar
5. Christensen, J. and Newman, J., J. Electrochem. Soc. 151, A1977 (2004).Google Scholar
6. Colclasure, A., Smith, K. A. and Kee, R. J., Electrochimica Acta 58, 33(2011).Google Scholar
7. Guyer, J. E., Boettinger, W. J. and Warren, J. A., Phys. Rev. B 69, 021603 (2004).Google Scholar
8. Guyer, J. E., Boettinger, W. J. and Warren, J. A., Phys. Rev. B 69, 021604 (2004).Google Scholar
9. Shibuta, Y., Okajima, Y. and Suzuki, T., Sci. Tech. Adv. Mat. 8, 511 (2007).Google Scholar
10. Gathright, W., Jensen, M. and Lewis, D., Electrochem. Commun. 13, 520 (2011).Google Scholar
11. Gathright, W., Jensen, M. and Lewis, D., J. Mater. Sci. 47, 1677 (2012).Google Scholar
12. Yamada, Y., Iriyama, Y., Abe, T. and Ogumi, Z., Langmuir 25, 12766 (2009).Google Scholar
13. Abe, T., Sagane, F., Ohtsuka, M., Iriyama, Y. and Ogumi, Z., J. Electrochem. Soc. 152, A2151 (2005).Google Scholar