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Experimental Study of the Relative Energy of Symmetrical <110> Tilt Boundaries in a Semi-Conducting F.C.C. Oxide (NiO).

Published online by Cambridge University Press:  15 February 2011

Guy Dhalenne
Affiliation:
Laboratoire de Chimie Appliquée, Université Paris Xl, Batiment 414, 91405 Orsay Cedex, FRANCE.
Michel Dechamps
Affiliation:
Laboratoire de Chimie Appliquée, Université Paris Xl, Batiment 414, 91405 Orsay Cedex, FRANCE.
Alexandre Revcolevschi
Affiliation:
Laboratoire de Chimie Appliquée, Université Paris Xl, Batiment 414, 91405 Orsay Cedex, FRANCE.
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Abstract

Large size bicrystalline samples of NiO corresponding to tilt configurations around a < 110 > axis have been grown by the flame fusion technique, the misorientation angles varying from 0 to 180°. The variation of the relative energy of the grain boundary with misorientation has been studied and has indicated a very different behaviour from that previously observed by the authors on <100> tilt boundaries. High relative energy values and deep cusps on the energy curve at high coincidence angles are observed. The results are discussed in terms of interface energy.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

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