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Novel synthesis route to graphene using iron nanoparticles

Published online by Cambridge University Press:  22 July 2014

Rajen B. Patel*
Affiliation:
Department of Materials Science and Engineering, New Jersey Institute of Technology, Newark, New Jersey 07102, USA
Chi Yu
Affiliation:
Department of Materials Science and Engineering, New Jersey Institute of Technology, Newark, New Jersey 07102, USA
Tsengming Chou
Affiliation:
Department of Chemical Engineering and Materials Science, Laboratory for Multiscale Imaging, Stevens Institute of Technology, Hoboken, New Jersey 07030, USA
Zafar Iqbal
Affiliation:
Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, New Jersey 07102, USA
*
a)Address all correspondence to this author. e-mail: RajenBP@gmail.com
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Abstract

Graphene is currently one of the most extensively studied materials because it displays a number of unique structural and electronic properties. A variety of methods are currently available for the growth of graphene; however, few are viable for large scale, cost-effective production of high quality graphene. Here, a novel growth process for few layer graphene using chemical vapor deposition (CVD) and a commercial iron nanopowder catalyst is described. This method is readily scalable so it can be used to produce a large volume of graphene sheets. Graphene sheets made from this process were characterized by Raman spectroscopy, and scanning and transmission electron microscopy. Raman spectroscopy shows that the product consists of few layer graphene sheets. This is the first reported method of utilizing nanoparticles to synthesize graphene by a CVD process, which typically produces multiwalled carbon nanotubes. A possible mechanism for the formation of graphene by this modified CVD process is discussed.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieval, I.V., and Firsov, A.A.: Electric field effect in atomically thin carbon films. Science 306, 666 (2004).CrossRefGoogle ScholarPubMed
Nobelprize.Org: The Nobel Prize in Physics 2010. [cited 31, Aug 2012]; Available from: http://www.nobelprize.org/nobel_prizes/physics/laureates/2010/ (2010).Google Scholar
Geim, A.K. and Novoselov, K.S.: The rise of graphene. Nat. Mater. 6, 183 (2007).CrossRefGoogle ScholarPubMed
Chen, Z., Ren, W., Liu, B., Gao, L., Pei, S., Wu, Z-S., Zhao, J., and Cheng, H-M.: Bulk growth of mono- to few-layer graphene on nickel particles by chemical vapor deposition from methane. Carbon 48, 3543 (2010).CrossRefGoogle Scholar
Losurdo, M., Giangregorio, M.M., Capezzuto, P., and Bruno, G.: Graphene CVD growth on copper and nickel: Role of hydrogen in kinetics and structure. Phys. Chem. Chem. Phys. 14, 13 (2011).Google Scholar
Reina, A., Thiele, S., Jia, X., Bhaviripudi, S., Dresselhaus, M.S., Schaefer, J.A., and Kong, J.: Growth of large-area single and Bi-layer graphene by controlled carbon precipitation on polycrystalline Ni surfaces. Nano Res. 2, 509 (2009).CrossRefGoogle Scholar
Mattevi, C., Kim, H., and Chhowalla, M.: A review of chemical vapor deposition of graphene on copper. J. Mater. Chem. 21, 3324 (2010).CrossRefGoogle Scholar
Kim, K.S., Zhao, Y., Jang, H., Lee, S.Y., Kim, J.M., Kim, K.S., Ahn, J-H., Kim, P., Choi, J-Y., and Hong, B.H.: Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457, 706 (2008).CrossRefGoogle Scholar
Vinogradov, N.A., Zakharov, A.A., Kocevskil, V., Ruszl, J., Simonov, K.A., Eriksson, O., Mikkelsen, A., Lundgren, E., Vinogradov, A.S., Mårtensson, N., and Preobrajenski, A.B.: Formation and structure of graphene waves on Fe(110). Phys. Rev. Lett. 109, 026101 (2012).CrossRefGoogle ScholarPubMed
An, H., Lee, W-J., and Jung, J.: Graphene synthesis on Fe foil using thermal CVD. Curr. Appl. Phys. 11, S81 (2011).CrossRefGoogle Scholar
Khan, A.S., Suh, Y.S., Chen, X., Takacs, L., and Zhang, H.: Nanocrystalline aluminum and iron: Mechanical behavior at quasi-static and high strain rates, and constitutive modeling. Int. J. Plast. 22, 195 (2006).CrossRefGoogle Scholar
Goyal, A., Wiegand, D.A., Owens, F.J., and Iqbal, Z.: Enhanced yield strength in iron nanocomposite with in situ grown single-wall carbon nanotubes. J. Mater. Res. 21, 522 (2005).CrossRefGoogle Scholar
Goyal, A., Wiegand, D.A., Owens, F.J., and Iqbal, Z.: Synthesis of carbide-free, high strength iron-carbon nanotube composite by in situ nanotube growth. Chem. Phys. Lett. 442, 365 (2007).CrossRefGoogle Scholar
Goyal, A.: New approaches to scaled-up carbon nanotube synthesis and nanotube-based metal composites and sensors. PhD Dissertation, New Jersey Institute of Technology, 2006.Google Scholar
Patel, R.B., Liu, J., Roy, S., Mitra, S., Dave, R.N., and Iqbal, Z.: Formation of stainless steel–carbon nanotube composites using a scalable chemical vapor infiltration process. J. Mater. Sci. 48, 1387 (2013).CrossRefGoogle Scholar
Patel, R.B., Liu, J., Eng, J., and Iqbal, Z.: One-step CVD synthesis of a boron nitride nanotube-iron composite. J. Mater. Res. 26, 1332 (2011).CrossRefGoogle Scholar
Ferrari, A.C., Meyer, J.C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K.S., Roth, S., and Geim, A.K.: Raman spectrum of graphene and graphene layers. Phys. Rev. Lett. 97, 187401 (2006).CrossRefGoogle ScholarPubMed
Ferrari, A.C. and Basko, D.M.: Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat. Nanotechnol. 8, 235 (2013).CrossRefGoogle ScholarPubMed
Graf, D., Molitor, F., Ensslin, K., Stampfer, C., Jungen, A., Hierold, C., and Wirtz, L.: Spatially resolved Raman spectroscopy of single- and few-layer graphene. Nano Lett. 7, 238242 (2007).CrossRefGoogle ScholarPubMed
Casiraghi, C., Pisana, S., Novoselov, K.S., Geim, A.K., and Ferrari, A.C.: Raman fingerprint of charged impurities in graphene. Appl. Phys. Lett. 91, 233108 (2007).CrossRefGoogle Scholar
Basko, D.M.: Theory of resonant multiphonon Raman scattering in graphene. Phys. Rev. B 78, 125418 (2008).CrossRefGoogle Scholar
Malard, L.M., Pimenta, M.A., Dresselhaus, G., and Dresselhaus, M.S.: Raman spectroscopy in graphene. Phys. Rep. 473, 51 (2009).CrossRefGoogle Scholar
Matthews, M.J., Pimenta, M.A., Dresselhaus, G., Dresselhaus, M.S., and Endo, M.: Origin of dispersive effects of the Raman D band in carbon materials. Phys. Rev. B 59, R6585 (1999).CrossRefGoogle Scholar
Patel, R.B.: Synthesis and characterization of novel boron-based nanostructures and composites. PhD Dissertation, New Jersey Institute of Technology, 2013.Google Scholar
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