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Biorenewable Multiphase Polymers

Published online by Cambridge University Press:  31 January 2011

Megan L. Robertson ,
Marc A. Hillmyer ,
Anne-Cécile Mortamet  and
Anthony J. Ryan
Megan L. Robertson
Affiliation:
Department of Chemistry, University of Minnesota, Minneapolis, 55455-0431, USA; e-mail: rueg0011@umn.edu.
Marc A. Hillmyer
Affiliation:
Department of Chemistry, University of Minnesota, Minneapolis, 55455-0431, USA; tel. 612-625-7834; and e-mail: hillmyer@umn.edu.
Anne-Cécile Mortamet
Affiliation:
chp07amm@shef.ac.uk.
Anthony J. Ryan
Affiliation:
University of Sheffield, UK; tel. +44-114-222-9761; and e-mail: tony.ryan@sheffield.ac.uk.
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Abstract

Hybrid macromolecules composed of two or more covalently connected segments have the ability to self-assemble into nanostructured materials. These fascinating materials are used in applications ranging from footwear to bitumen modification to microelectronics. The number of technologies that utilize or could benefit from multiphase polymers is expanding at a rapid rate. This growth is due to the development of simple scalable synthetic technologies, a deeper understanding of their structure-property relationships, and their effectiveness as low-level additives. As industrial uses of self-assembled polymers become more prevalent, there will be a heightened focus on alternative preparative approaches that do not rely on petroleum feedstocks. Therefore the development of biorenewable multiphase polymers is an important research endeavor. In this article, we will explore the synthesis, self-assembly, and properties of renewable block and graft copolymers that contain aliphatic polyesters, as well as bio-sourced segmented polyurethanes. These two classes of multiphase polymers are the most promising and practical candidates for implementation in the next generation of sustainable materials.

Type
Research Article
Information
MRS Bulletin , Volume 35 , Issue 3: Materials from Renewable Resources , March 2010 , pp. 194 - 200
Copyright
Copyright © Materials Research Society 2010

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