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Fluorinated Heteroaromatic Polyethers for Low Dielectric Constant/High Temperature Applications

Published online by Cambridge University Press:  15 February 2011

G. Maier
Affiliation:
Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, Lichtenbergstrabe 4, D-85747 Garching, Germany
J. M. Schneider
Affiliation:
Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, Lichtenbergstrabe 4, D-85747 Garching, Germany
R. Hecht
Affiliation:
Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, Lichtenbergstrabe 4, D-85747 Garching, Germany
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Abstract

Synthesis and characterization of three classes of poly(arylene ether oxazole)s and poly(arylene ether thiazole)s with trifluoromethyl substituents in various positions is described. Based on these examples, the influence of the chemical structure of the polymers on properties such as glass transition temperature, solubility, and thermal stability will be discussed. Structural parameters studied are the number and nature of the heteroaromatic rings, the number and position of the trifluoromethyl groups, and the structure (flexibility, polarity) of various linking groups.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

1. Hendricks, N. H., Solid State Technology 7/1995, 117 (1995); and references cited thereinGoogle Scholar
2. Murarka, S. P., Solid State Technology 3/1996, 83 (1996); and references cited thereinGoogle Scholar
3. Singer, P., Semiconductor International 5/1996, 88 (1996); and references cited thereinGoogle Scholar
4. Krevelen, D. W. Van, Properties of Polymers. 3rd ed., (Elsevier, Amsterdam 1990), p. 321 ffGoogle Scholar
5. Rossbach, V., Oberlein, G., in Handbook of Polymer Synthesis, edited by Kricheldorf, H. R. (Marcel Dekker, New York 1992), part B, p. 1197 ffGoogle Scholar
6. Encyclopedia of Polymer Science and Engineering, edited by Mark, H. F., Bikales, N. M., Overberger, C. G., and Menges, G. (John Wiley & Sons, New York 1988); Chapters on: Polybenzimidazoles; Polyhydrazides and Polyoxadiazoles; Polybenzothiazoles and Polybenzoxazoles, Polyquinolines, Polyquinoxalines:Google Scholar
7. Maier, G., in The Polymeric Materials Encyclopedia, edited by Salamone, J. C. (CRC Press, Boca Raton 1996), vol.5: H-L, p. H59 Google Scholar
8. Cassidy, P. E., Thermally Stable Polymers (Marcel Dekker, New York 1980)Google Scholar
9. Hergenrother, P. M. (editor), Advances in Polymer Science, Vol.177: High Performance Polymers (Springer-Verlag, Berlin 1994)Google Scholar
10. Lakhan, R., Ternai, B., in Advances in Heterocyclic Chemistry, edited by Katritzky, A. R. and Boulton, A. J. (Academic Press, New York 1974) vol.17, p. 152 Google Scholar
11. Metzger, J. V., in Comprehensive Heterocyclic Chemistry, edited by Katritzky, A. R. and Rees, C. W. (Pergamon Press, Oxford 1984) vol.6, p. 235 Google Scholar
12. Maier, Gerhard, Hecht, Reinhold, Nuyken, Oskar, Burger, Klaus, Helmreich, Brigitte, Macromolecules 26, 25832591 (1993)Google Scholar
13. Maier, Gerhard, Hecht, Reinhold, Macromolecules 28, 75587565 (1995)Google Scholar
14. Ibata, T., Sato, R., Chem. Lett. 1978, 1129 Google Scholar
15. Johnson, R. N., Farnham, A. G., Clendinning, R. A., Hale, W. F., Merriam, C. N., J Polym. Sci. A-I 5, 2375 (1967)Google Scholar
16. Harris, J. E., Johnson, R. N., in Encyclopedia of Polymer Science and Engineering, 2nd ed., edited by Mark, H. F., Bikales, N. M., Overberger, C. G., and Menges, G. (John Wiley & Sons, New York 1988) vol.13, p. 196 Google Scholar
17. Staniland, P. A., in Comprehensive Polymer Science, edited by Allen, G. and Bevington, J. C. (Pergamon Press, Oxford 1989) vol.5, p. 483 Google Scholar
18. Gerbi, D. J., Dimotsis, G., Morgan, J. L., Williams, R. F., and Kellman, R., J Polym. Sci., Polym. Lett. Ed. 23, 551 (1985)Google Scholar
19. Kricheldorf, H. R., Bier, G., J Polym. Sci., Polym. Chem. Ed. 21, 2283 (1983); H. R. Kricheldorf, J. Engelhardt, Makromol. Chem. 191, 2017 (1990)Google Scholar
20. Nygaard, L., Hansen, R. L., Nielsen, J. T., Rastrup-Andersen, J., Sorensen, G. O., Steiner, P. A., J Mol. Structure 12, 59 (1972)Google Scholar
21. Nygaard, L., Hansen, B. L., Sorensen, G. O., J Mol. Structure 9, 163 (1971)Google Scholar
22. Katritzky, A., Rees, C., Potts, K. (Eds.), Comprehensive Heterocyclic Chemistry (Pergamon Press, Oxford 1984) Vol.6, p. 178ffGoogle Scholar