Hostname: page-component-8448b6f56d-t5pn6 Total loading time: 0 Render date: 2024-04-24T03:01:47.917Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of Praseodymium Species on the Structural and Functional Properties of Nanocrystalline BiFeO3 Powders and Thin Films

Published online by Cambridge University Press:  29 May 2012

Gina Montes Albino ,
Marco Gálvez-Saldaña  and
Oscar Perales-Pérez
Gina Montes Albino
Affiliation:
Department of Mechanical Engineering, University of Puerto Rico at Mayagüez P.O. Box 9045, Mayagüez, PR, 00681-9045 USA.
Marco Gálvez-Saldaña
Affiliation:
Department of Physics, University of Puerto Rico at Mayagüez, Mayagüez, PR, 00980, USA.
Oscar Perales-Pérez
Affiliation:
Department of Engineering Science and Materials, University of Puerto Rico at Mayagüez, Mayagüez, PR, 00680- 9044, USA.
Get access

Abstract

The present study addressed the effect of the incorporation of Praseodymium species in the BiFeO3(BFO) structure on the corresponding structural and functional properties of powders and films. The level of the doping species varied from 0 at% to 4 at%. BFO powders and thin films were synthesized by a sol-gel method, where glycol was aggregated to the main solvent to increase the viscosity of the precursor solutions and promote their adhesion onto platinum substrates. The development of the host BFO structure was confirmed by XRD analyses of samples annealed at 700°C for one hour (powders) or 500°C for 2 hours (thin films), in air. The average crystallite size varied from 37 nm to 41 nm and 28nm to 40nm for powders and thin films, respectively, due to the increase of the doping level. The incorporation of specific dopant species played an important role in the ferromagnetic and ferroelectric behavior in the material.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1454: Symposium HH – Nanocomposites, Nanostructures and Heterostructures of Correlated Oxide Systems , 2012 , pp. 39 - 44
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Catalan, Gustau and Scott, James F.. Physics and Applications of Bismuth Ferrite, Advances Materials, 21, 2463, (2009).CrossRefGoogle Scholar
[2] Teague, J. R., Gerson, R., and James, W. J.. Dielectric hysteresis in single crystal BiFeO3 , Solid State Commun. 8, 1073, (1970).CrossRefGoogle Scholar
[3] Simoes, A.Z., et al. ., Rietveld. Analysis and electrical properties of lanthanum doped BiFeO3 ceramics, Materials Chemistry and Physics, 116, 305–309, (2009).Google Scholar
[4] Kumar, Neeraj, et al. . Structural, dielectric and magnetic properties of Pr substituted Bi1−xPrxFeO3 (0≤x≤0.15) multiferroic compounds, Journal of Alloys and Compounds, 501, L29–L32, (2010).Google Scholar
[5] Azough, Feridoon et al. . Microstructure and properties of Co, Ni, Zn, Nb and W modified multiferroic BiFeO3 ceramic, Journal of the European Society 30 (2010),727–736.CrossRefGoogle Scholar
[6] Cullity, B. D. Element of X-ray Diffractions, Addison Wesley, Reading, MA, 1972, 102.Google Scholar
[7] Zhu, W.-M., Guo, H.-Y., and Ye, Z.-G.. Structural and magnetic characterization of multiferroic (BiFeO3)1−x(PbTiO3)x solid solutions, Phys. Rev. B 78, 014401(2008)CrossRefGoogle Scholar
[8] Ederer, Claude and Spaldin, Nicola A.. Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite, Physical Review B 71, 060401R, (2005).CrossRefGoogle Scholar
[9] Wen, Z. et al. . Multiferroic properties of (Bi1-xPrx)(Fe0.95 Mn0.05)O3 thin films, Materials Science and Engineering B 176 (2011) 990– 995 Google Scholar
[10] Seshadri, R. and Hill, Nicola A.. Visualizing the Role of Bi 6s "Lone Pairs" in the Off-Center Distortion in Ferromagnetic BiMnO3 , Chem. Mater. 13, 2892, (2001)CrossRefGoogle Scholar
[11] Wang, et al. . Magnetoelectric coupling and phase transition in BiFeO3 and (BiFeO3)0.95 (BaTiO3)0.05 ceramics, Journal of Applied Physics 109, 044101 (2011).CrossRefGoogle Scholar