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Increased vegetable production for the fresh market often has been suggested as an agricultural alternative that will improve the income situation of small-scale farmers. Because vegetable production is an intensive activity and high incomes per acre are possible, it has political appeal as a quick solution to the low income levels generally associated with small farm operations. This study was developed from the small farm program of the University of Florida, which has concentrated on the northern and panhandle areas of Florida. Trials conducted by the Vegetable Crops Department of the University of Florida in 1974 and 1975 indicate that by variation of the planting season and control of insects and diseases, vegetables can be produced during periods of the year when the north Florida area has not historically competed in the fresh vegetable market.
Plutonium metallurgy lies at the heart of science-based stockpile stewardship. One aspect is concerned with developing predictive capabilities to describe the properties of stockpile materials, including an assessment of microstructural changes with age. Yet, the complex behavior of plutonium, which results from the competition of its 5f electrons between a localized (atomic-like or bound) state and an itinerant (delocalized bonding) state, has been challenging materials scientists and physicists for the better part of five decades. Although far from quantitatively absolute, electronic-structure theory provides a description of plutonium that helps explain the unusual properties of plutonium, as recently reviewed by Hecker. (See also the article by Hecker in this issue.) The electronic structure of plutonium includes five 5f electrons with a very narrow energy width of the 5f conduction band, which results in a delicate balance between itinerant electrons (in the conduction band) or localized electrons and multiple lowenergy electronic configurations with nearly equivalent energies. These complex electronic characteristics give rise to unique macroscopic properties of plutonium that include six allotropes (at ambient pressure) with very close free energies but large (∼25%) density differences, a lowsymmetry monoclinic ground state rather than a high-symmetry close-packed cubic phase, compression upon melting (like water), low melting temperature, anomalous temperature-dependence of electrical resistance, and radioactive decay. Additionally, plutonium readily oxidizes and is toxic; therefore, the handling and fundamental research of this element is very challenging due to environmental, safety, and health concerns.
The effects of contour live barriers of vetiver and pennisetum on soil erosion were studied on four small farms in south central Honduras. Paired plots were installed and soil erosion measured by changes in the soil surface level of transects 0.3 and 6.0 m up the slope from the barrier. After three years, transects 0.3 m above the barriers significantly retained eroded soil compared with control transects. Soil accumulation by barriers ranged from 2.6 to 11.2 cm, and natural terrace formation (the difference between the barrier and corresponding control transect) ranged from 5.2 to 13.8 cm. No difference was detected between barrier and control for the transects 6.0 m above the barrier. Deposition in front of the barriers and reduction in surface rilling were apparent to farmers. Erosion from up slope on the barrier plots and from both transects in the control sections was not obvious. Direct measurement and farmer observation of sediment deposition by live barriers will help evaluate farmer-identified species for future use. The deposition helps farmers become aware of sheet erosion before the effects of soil degradation on crop yields become grossly apparent and soil fertility restoration becomes too costly for small-scale farmers.
α-Dodecatungstosilicate (α-SiW12O40 4−) anions form ordered monolayers on Ag(111) and Au(111) surfaces. In-situ STM images reveal that the silicotungstate ion forms a square adlattice with an intermolecule spacing of 10.2 ± 0.5 Å on both Ag and Au surfaces. Additional structures exhibiting either row or rhombic motifs are observed on Au electrodes. The structure of the adlattices can be modeled using a simple model which maximizes the coordination of the silicotungstate ion to the electrode while maintaining van der Waals contacts between terminal oxygens of adjacent silicotungstates.
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