Criddleite, ideally TlAg2Au3Sb10S10, is a rare constituent within the Hemlo gold deposit, Hemlo, Ontario, Canada. The mineral occurs as 20 to 50 µm-sized lath-like, tabular or anhedral grains usually surrounding or penetrating aurostibite, or associated with native antimony, native gold and stibnite. Criddleite is opaque with a metallic lustre and a black streak. It has been synthesized by reacting TlSbS2 and high purity Ag, Au, Sb and S in an evacuated silica glass tube at 400 °C. The measured density of the synthetic material is 6.86; the calculated density is 6.57 g/cm3. The difference is due to minor admixed aurostibite, native antimony and a dyscrasite-like phase within the charge. VHN25 is 94–129. Mohs hardness (calc.) = 3–3 ½. In reflected plane-polarized light in air, natural criddleite is weakly bireflectant with a discernible reflectance pleochroism from grey-blue to slightly greenish grey-blue. The mineral has a distinct to moderate anisotropy with rotation tints in shades of buff to slate grey. Reflectance spectra and colour values for both natural and synthetic criddleite are given. X-ray study showed that synthetic criddleite is monoclinic (pseudotetragonal) with refined unit-cell parameters a = 20.015(2), b = 8.075(2), c = 7.831(2) Å, β = 92.01(2)°, V = 1264.9 ± 1.0 Å3 and a:b:c = 2.4786: 1:0.9698. The space group choices are A2/m(12), A2(5) or Am(8), diffraction aspect A*/*. The seven strongest lines in the X-ray powder diffraction pattern [d in Å (I) (hkl)] are: 5.63(90) (011), 3.91(50) (002), 3.456(50) (320), 2.860(70) (700), 2.813(100) (022), 2.018(60) (040) and 1.959(70) (004). Electron microprobe analyses are reported of natural criddleite in five polished sections of drill core from four holes. The averaged empirical formulae, based on 26 atoms, are Tl0.92Ag1.99Au2.93Sb9.87S10.28 (natural) and Tl0.94Ag2.03Au2.89Sb9.76S10.38 (synthetic).

A brief cold–warm–cold climate change during the middle Wisconsinan is described for the first time in North America, based on fossil beetle assemblages at Titusville, Pennsylvania. AMS dating of insect chitin and wood suggests the change occurred between 39,000 and 43,500 yr B.P. Basal peats in river terrace deposits contain arctic–subarctic beetle species representing a climate similar to that found at treeline in Canada, where mean July temperatures range from 10° to 13°C. These cold-adapted beetles were replaced by species representing a climate similar to the mixed coniferous–deciduous forests of southern Canada, where mean July temperatures range from 18° to 20°C. In turn, these warmer-adapted beetles were replaced by arctic–subarctic species in the upper part of the section, representing a climate with mean July temperatures in the range 10°–13°C. The brief warm interval is informally designated the Titusville interstade. The difference in temperature between the colder and warmer intervals is about 5°–7°C. The Titusville interstade is correlated with the Upton Warren Interstade of the British Isles which is of similar age and intensity. It is also correlated with the high sea-surface temperature interval between Heinrich events 4 and 5 represented in North Atlantic sediment cores.