The IntCal family of radiocarbon (14C) calibration curves is based on research spanning more than three decades. The IntCal group have collated the 14C and calendar age data (mostly derived from primary publications with other types of data and meta-data) and, since 2010, made them available for other sorts of analysis through an open-access database. This has ensured transparency in terms of the data used in the construction of the ratified calibration curves. As the IntCal database expands, work is underway to facilitate best practice for new data submissions, make more of the associated metadata available in a structured form, and help those wishing to process the data with programming languages such as R, Python, and MATLAB. The data and metadata are complex because of the range of different types of archives. A restructured interface, based on the “IntChron” open-access data model, includes tools which allow the data to be plotted and compared without the need for export. The intention is to include complementary information which can be used alongside the main 14C series to provide new insights into the global carbon cycle, as well as facilitating access to the data for other research applications. Overall, this work aims to streamline the generation of new calibration curves.

The direct carbonate procedure for accelerator mass spectrometry radiocarbon (AMS 14C) dating of submilligram samples of biogenic carbonate without graphitization is becoming widely used in a variety of studies. We compare the results of 153 paired direct carbonate and standard graphite 14C determinations on single specimens of an assortment of biogenic carbonates. A reduced major axis regression shows a strong relationship between direct carbonate and graphite percent Modern Carbon (pMC) values (m = 0.996; 95% CI [0.991–1.001]). An analysis of differences and a 95% confidence interval on pMC values reveals that there is no significant difference between direct carbonate and graphite pMC values for 76% of analyzed specimens, although variation in direct carbonate pMC is underestimated. The difference between the two methods is typically within 2 pMC, with 61% of direct carbonate pMC measurements being higher than their paired graphite counterpart. Of the 36 specimens that did yield significant differences, all but three missed the 95% significance threshold by 1.2 pMC or less. These results show that direct carbonate 14C dating of biogenic carbonates is a cost-effective and efficient complement to standard graphite 14C dating.

Fungal hyphae associated with tree roots extending into the surrounding substrate are suspected to have to contaminated buried plant material with recent carbon in two examples and to have resulted in erroneously young radiocarbon ages. This problem might be overcome by choosing sampling sites far from trees or by analyzing the lignin component of samples, although the latter is presently difficult.

Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Early researchers of radiocarbon levels in Southern Hemisphere tree rings identified a variable North-South hemispheric offset, necessitating construction of a separate radiocarbon calibration curve for the South. We present here SHCal20, a revised calibration curve from 0–55,000 cal BP, based upon SHCal13 and fortified by the addition of 14 new tree-ring data sets in the 2140–0, 3520–3453, 3608–3590 and 13,140–11,375 cal BP time intervals. We detail the statistical approaches used for curve construction and present recommendations for the use of the Northern Hemisphere curve (IntCal20), the Southern Hemisphere curve (SHCal20) and suggest where application of an equal mixture of the curves might be more appropriate. Using our Bayesian spline with errors-in-variables methodology, and based upon a comparison of Southern Hemisphere tree-ring data compared with contemporaneous Northern Hemisphere data, we estimate the mean Southern Hemisphere offset to be 36 ± 27 14C yrs older.

As part of the ongoing effort to improve the Northern Hemisphere radiocarbon (14C) calibration curve, this study investigates the period of 856 BC to 626 BC (2805–2575 yr BP) with a total of 403 single-year 14C measurements. In this age range, IntCal13 was constructed largely from German and Irish oak as well as Californian bristlecone pine 14C dates, with most samples measured with a 10-yr resolution. The new data presented here is the first atmospheric 14C single-year record of the older end of the Hallstatt plateau based on an absolutely dated tree-ring chronology. The data helped reveal a major solar proton event (SPE) which caused a spike in the production rate of cosmogenic radionuclides around 2610/2609 BP. This production event is thought to have reached a magnitude similar to the 774/775 AD production event but has remained undetected due to averaging effects in the decadal calibration data. The record leading up to the 2610/2609 BP event reveals a 11-yr solar cycle with varying cyclicity. Features of the new data and the benefits of higher resolution calibration are discussed.

This research investigates two factors influencing the ability of tree-ring data to provide accurate 14C calibration information: the fitness and rigor of the statistical model used to combine the data into a curve; and the accuracy, precision and reproducibility of the component 14C data sets. It presents a new Bayesian spline method for calibration curve construction and tests it on extant and new Southern Hemisphere (SH) data sets (also examining their dendrochronology and pretreatment) for the post-Little Ice Age (LIA) interval AD 1500–1950. The new method of construction allows calculation of component data offsets, permitting identification of laboratory and geographic biases. Application of the new method to the 10 suitable SH 14C data sets suggests that individual offset ranges for component data sets appear to be in the region of ± 10 yr. Data sets with individual offsets larger than this need to be carefully assessed before selection for calibration purposes. We identify a potential geographical offset associated with the Southern Ocean (high latitude) Campbell Island data. We test the new methodology for wiggle-matching short tree-ring sequences and use an OxCal simulation to assess the likely precision obtainable by wiggle-matching in the post-LIA interval.

We present 37 new radiocarbon (14C) measurements from mollusk shells fragments sampled along the Chilean continental margin and stored in museum collections with known calendar age. These measurements were used to estimate the modern pre-bomb regional marine 14C age deviations from the global ocean reservoir (∆R). Together with previously published data, we calculated regional mean ∆R values for five oceanographic macro regions along the coast plus one for a mid-latitude open ocean setting. In general, upwelling regions north of 42ºS show consistent although sometimes highly variable ∆R values with regional averages ranging from 141 to 196 14C yr, whereas the mid-latitude open ocean location of the Juan Fernández archipelago and the southern Patagonian region show minor, ∆R of 40±38 14C yr, and 52±47 14C yr respectively. We attribute the alongshore decreasing pattern toward higher latitudes to the main oceanographic features along the Chilean coast such as perennial coastal upwelling in northern zone, seasonally variable upwelling at the central part and the large freshwater influence upon the southern Patagonian channels.

Archaeological sites in the Canadian Arctic often contain substantial quantities of marine mammal bones and in some cases completely lack terrestrial mammal bones. A distrust of radiocarbon (14C) dates on marine mammal bones among Arctic archaeologists has caused many sites to be insufficiently dated. The goal of this study was to investigate the marine reservoir effect on Atlantic walrus in the Foxe Basin region of the Canadian Arctic through a two-pronged approach: dating of live-harvested specimens of known age collected prior to AD 1955 and dating of pairs of animal remains (walrus and caribou) from stratigraphically contemporaneous levels within archaeological features. 14C dates on pre-bomb, live-harvested walrus indicate that a ΔR value of 160±50 yr be used in calibrating dates on walrus from this region. These results differed significantly from a similar set of pre-bomb mollusks, which argues against applying mollusk-based corrections to marine mammals. The results of comparative dating of caribou and walrus from archaeological features provided maximum estimates of reservoir ages that were more varied than the directly measured ages. Although about half of inferred ΔR values overlap the museum specimen results, the others indicate that the assumption of contemporaneity does not hold true.

We consider one misconception of those who currently reject the general validity of radiocarbon (14C) age determinations older than, at most, 10,000 BP. There is an allegation that the presence of 14C reported by accelerator mass spectrometry (AMS) laboratories in their measurements of 14C infinite age (>100,000 years) organics used to define background levels, support their point of view. This article has been written for a general audience, primarily for those who have questions about the validity of these arguments. However, they may not be familiar with the literature relevant to providing a clear response to the claims of these individuals. We conclude that, in our view, of all of the possible explanations for the reports of the presence of 14C in these background samples, the least probable explanation has been advanced by those rejecting the validity of the 14C time scale in excess of, at most, 10,000 BP.

To determine the effectiveness of glacial erosion and the magnitude of cosmogenic nuclide inheritance from prior periods of cosmic-ray exposure, we measured the abundance of 10Be and 26Al in nine samples collected from bedrock, boulders and cobbles exposed by the retreat of Tumbling Glacier, Baffin Island, Canada. Most samples had nuclide concentrations so low that we were only able to set upper limits for nuclide abundance. Three boulders, two on a Neoglacial moraine of Tumbling Glacier that impounds Crater Lake and one on a roche moutonnée within the Neoglacial moraine loop, had nuclide abundances indicating no more than 900 yr of exposure at the surface. Three bedrock samples, striated by Tumbling Glacier and exposed by ice retreat within the last 20 yr, have similarly low nuclide abundances. One bedrock sample, covered by Tumbling Glacier ice for some part of the Holocene but not eroded, allows us to estimate crudely the duration of Neoglaciation at our sample site (about 5450 yr) and to provide a lower limit on the erosion rate of Tumbling Glacier (0.10 ± 0.03 mm a–1). We analyzed two cobbles collected from the tops of roches moutonnées at Crater Lake; one cobble had the equivalent of 3000 yr of exposure, the other < 900 yr.

Since the AD 775 and AD 994 Δ14C peak (henceforth M12) was first measured by Miyake et al. (2012, 2013), several possible production mechanisms for these spike have been suggested, but the work of Mekhaldi et al. (2015) shows that a very soft energy spectrum was involved, implying that a strong solar energetic particle (SEP) event (or series of events) was responsible. Here we present Δ14C values from AD 721–820 Sequoiadendron giganteum annual tree-ring samples from Sequoia National Park in California, USA, together with Δ14C in German oak from 650–670 BC. The AD 721–820 measurements confirm that a sharp Δ14C peak exists at AD 775, with a peak height of approximately 15‰ and show that this spike was preceded by several decades of rapidly decreasing Δ14C. A sharp peak is also present at 660 BC, with a peak height of about 10‰, and published data (Reimer et al. 2013) indicate that it too was preceded by a multi-decadal Δ14C decrease, suggesting that solar activity was very strong just prior to both Δ14C peaks and may be causally related. During periods of strong solar activity there is increased probability for coronal mass ejection (CME) events that can subject the Earth’s atmosphere to high fluencies of solar energetic particles (SEPs). Periods of high solar activity (such as one in October–November 2003) can also often include many large, fast CMEs increasing the probability of geomagnetic storms. In this paper we suggest that the combination of large SEP events and elevated geomagnetic activity can lead to enhanced production of 14C and other cosmogenic isotopes by increasing the area of the atmosphere that is irradiated by high solar energetic particles.

While the North American archaeological record signals the presence of early humans along the northeastern Pacific coast by the Late Pleistocene, we know little about the technological systems employed by these coastally oriented colonizing groups. We here report the discovery of the earliest unequivocal evidence for the use and manufacture of shell fishhooks in the western hemisphere. Four single-piece shell fishhooks dating to the terminal Pleistocene/early Holocene transition (between ~11,300 and 10,700 cal B.P.) have been excavated on Isla Cedros, Baja California, Mexico. One hook is directly dated at 9495 ± 25 B.P. with a marine reservoir–corrected age of 11,165–9185 cal B.P. Radiocarbon ages associated with three other shell fishhooks range between 8900 ± 25 B.P. and 10,415 ± 25 B.P, while median ages for the earliest contexts confirm occupation of the island by at least 12,600–12,000 cal B.P. The stratigraphic levels from which the fishhooks were recovered contained a diverse assemblage of fish remains, including deepwater species, indicative of boat use. Thus, some of the earliest known inhabitants of the Pacific coast of the Americas employed shell hook and line technology for offshore marine fishing at least by the Pleistocene-Holocene transition, if not earlier.

δ18O records from the GISP2 and GRIP ice cores are widely used as benchmark paleoclimate chronologies, but there are significant differences between the two time scales. The present study shows that offsets between the two chronologies over the past 14,500 yr do not accumulate gradually, but appear over two short intervals of 100–200 yr. An initial offset of 80 yr occurs close to 3300–3400 yr B.P., and another 100 yr of slip appears at the start of the Younger Dryas. Since these discrepancies are localized, resolving them may be far easier than if large sections of both cores required reexamination.

Two century-scale time series in northern Bolivia constrain the ages of abrupt changes in the physical, geochemical, and biological characteristics of sediments obtained from lakes that formed during deglaciation from the late Pleistocene glacial maximum. The watersheds of Laguna Viscachani (16°12′S, 68°07′W, 3780 m) and Lago Taypi Chaka Kkota (16°13′S, 68°21′W, 4300 m), located on the eastern and western slopes of the Cordillera Real, respectively, contain small cirque glaciers. A high-resolution chronology of the lake sediments is provided by 23 AMS14C dates of discrete macrofossils. Late Pleistocene glaciers retreated rapidly, exposing the lake basins between 10,700 and 970014C yr B.P. The sedimentary facies suggest that after 890014C yr B.P. glaciers were absent from the watersheds and remained so during the middle Holocene. An increase in the precipitation–evaporation balance is indicated above unconformities dated to ∼230014C yr B.P. in both Lago Taypi Chaka Kkota and Laguna Viscachani. An abrupt increase in sediment accumulation rates after 140014C yr B.P. signals the onset of Neoglaciation. A possible link exists between the observed millennial-scale shifts in the regional precipitation–evaporation balance and seasonal shifts in tropical insolation.

Radiocarbon dating of bulk sediments has been the standard method for establishing chronologies in the studies of lake sediment cores which have contributed significantly to our knowledge of late Quaternary paleo-environments. These bulk sediment dates are presumed to be direct ageindicators for the speciments (e.g., pollen or macrofossils) which are actually being studied. However, several recent studies have reinforced long-standing apprehensions concerning this presumption. In this study, we demonstrate for the first time the radiocarbon dating of pollen concentrate samples by accelerator mass spectrometry. The dates obtained by this method should provide more reliable radiocarbon chronologies for paleo-environmental studies than have been obtainable by bulk sediment dating.

The Last Glacial–Interglacial Transition (LGIT; 15,000–11,000 cal BP) was characterized by complex spatiotemporal patterns of climate change, with numerous studies requiring accurate chronological control to decipher leads from lags in global paleoclimatic, paleoenvironmental, and archaeological records. However, close scrutiny of the few available tree-ring chronologies and radiocarbon-dated sequences composing the IntCal13 14C calibration curve indicates significant weakness in 14C calibration across key periods of the LGIT. Here, we present a decadally resolved atmospheric 14C record derived from New Zealand kauri spanning the Lateglacial from ~13,100–11,365 cal BP. Two floating kauri 14C time series, curve-matched to IntCal13, serve as a 14C backbone through the Younger Dryas. The floating Northern Hemisphere (NH) 14C data sets derived from the YD-B and Central European Lateglacial Master tree-ring series are matched against the new kauri data, forming a robust NH 14C time series to ~14,200 cal BP. Our results show that IntCal13 is questionable from ~12,200–11,900 cal BP and the ~10,400 BP 14C plateau is approximately 5 decades too short. The new kauri record and repositioned NH pine 14C series offer a refinement of the international 14C calibration curves IntCal13 and SHCal13, providing increased confidence in the correlation of global paleorecords.

Combining atmospheric Δ14CO2 data sets from different networks or laboratories requires secure knowledge on their compatibility. In the present study, we compare Δ14CO2 results from the Heidelberg low-level counting (LLC) laboratory to 12 international accelerator mass spectrometry (AMS) laboratories using distributed aliquots of five pure CO2 samples. The averaged result of the LLC laboratory has a measurement bias of –0.3±0.5‰ with respect to the consensus value of the AMS laboratories for the investigated atmospheric Δ14C range of 9.6 to 40.4‰. Thus, the LLC measurements on average are not significantly different from the AMS laboratories, and the most likely measurement bias is smaller than the World Meteorological Organization (WMO) interlaboratory compatibility goal for Δ14CO2 of 0.5‰. The number of intercomparison samples was, however, too small to determine whether the measurement biases of the individual AMS laboratories fulfilled the WMO goal.