This paper generalizes the p* class of models for social network data to predict individual-level attributes from network ties. The p* model for social networks permits the modeling of social relationships in terms of particular local relational or network configurations. In this paper we present methods for modeling attribute measures in terms of network ties, and so construct p* models for the patterns of social influence within a network. Attribute variables are included in a directed dependence graph and the Hammersley-Clifford theorem is employed to derive probability models whose parameters can be estimated using maximum pseudo-likelihood. The models are compared to existing network effects models. They can be interpreted in terms of public or private social influence phenomena within groups. The models are illustrated by an empirical example involving a training course, with trainees' reactions to aspects of the course found to relate to those of their network partners.

Whiterockite, CaMgMn3+3O2(PO4)2CO3F·5H2O, is a new phosphate–carbonate mineral from the White Rock No. 2 quarry, Bimbowrie Conservation Park, South Australia, Australia. The mineral is associated with dufrénite/natrodufrénite, ushkovite, bermanite, leucophosphite and sellaite in a matrix comprising fluorapatite and minor quartz. Whiterockite has formed from hydrothermal alteration and weathering in an oxidising, low-temperature and low-pH environment. Whiterockite forms aggregates of thin platy dark-red crystals up to 0.7 mm across with individual crystals up to 0.2 mm in across. Crystals are transparent with a vitreous lustre. The mineral is brittle, has a perfect cleavage on {001} and has an irregular fracture. The measured density is 2.76(2) g/cm–3. Whiterockite is optically biaxial (–), with α = 1.660(3), β = 1.760(5) and γ = 1.770(5), determined in white light; 2Vmeas = 30(1)°; and orientation: X ≈ c*. The mineral is pleochroic: shades of red brown; X < Y < Z. Electron microprobe analyses provided the empirical formula (Ca0.87Na0.18)Σ1.05Mg1.05(Mn3+2.87Fe3+0.10)Σ2.97O1.93(PO4)2.01CO3F1.04·4.99H2O. Whiterockite is monoclinic, C2/m, a = 11.112(2), b = 6.4551(13), c = 10.667(2) Å, β = 102.61(3)º, V = 746.7(3)Å3 and Z = 2. The crystal structure of whiterockite has been refined using single-crystal synchrotron X-ray diffraction data to R1 = 5.10% on the basis of 957 reflections with F0 > 4σ(F0). The structure can be described as a layered structure formed by the stacking along [001] of three kinds of layers and is related to the structure of jörgkellerite.

Puttapaite, Pb2Mn2+2ZnCr3+4O2(AsO4)4(OH)6·12H2O, is a new mineral from the Beltana deposit, Puttapa, Flinders Ranges, South Australia, Australia. It forms rosette-like aggregates to 50 micrometers across composed of diamond-shaped tablets to 45 micrometers in length and 5 micrometers in thickness. Crystals are flattened on {001} and the observed forms are {001} and {110}. The calculated density is 3.562 g/cm–3. Optically, puttapaite is biaxial (−) with α = 1.700(5), β = 1.720(5), γ = 1.730(5) and 2V (meas.) = 67(1)°. Electron microprobe analyses gave the empirical formula (based on 36 oxygen atoms pfu) Pb1.96(Mn2+1.52Ca0.28Sr0.22)Σ2.02(Zn0.40Mg0.39Cu0.15)Σ0.94(Cr3+2.89Al0.45Fe3+0.40,Mn3+0.26)Σ4.00O2[(AsO4)3.71(Cr6+O4)0.29]Σ4.00(OH)6.13·11.87H2O. Puttapaite is monoclinic, C2/m, with a = 12.405(3), b = 10.565(2), c = 12.311(3) Å, β = 106.06(3)°, V = 1550.4(6) Å3 and Z = 2.

The structure was solved using synchrotron single-crystal X-ray diffraction data and refined to R1 = 0.1189 on the basis of 915 observed reflections with F0 > 4σ(F0). Puttapaite has a unique structure that consists of M4O16 clusters that share corners with TO4 tetrahedra, which in turn share corners with M1 octahedra in the [010] direction. Clusters link in the [001] direction via corner sharing M2 octahedra to form sheets parallel to {100}. Pb anions lie between the sheets.

Plumboperloffite, PbMn2+2Fe3+2(PO4)3(OH)3, is a new mineral and member of the bjarebyite group from Wiperaminga Hill West Quarry, Boolcoomatta Reserve, Olary Province, South Australia, Australia. The mineral was found in a single cavity in triplite–barbosalite matrix associated with fluorapatite, phosphosiderite, natrodufrénite and fluorite. The mineral forms intergrowths of subparallel, thin tabular to bladed crystals. Individual crystals are up to 40 μm in length. Plumboperloffite is brownish orange in colour with a vitreous lustre. The mineral has brittle tenacity, an excellent cleavage on {100} and uneven fracture. The calculated density is 4.416 g/cm3. Plumboperloffite is biaxial (+), α = 1.87(1), β = 1.88(1) and γ = 1.89(1) as measured in white light. The measured 2V is 88(1)°. Dispersion is apparently strong, based on extinction colours and the orientation is Y = b. The pleochroism in shades of yellow brown is X < Z < Y. Electron microprobe analysis gave the empirical formula (based on 15 O apfu) (Pb0.92Ca0.04Ba0.01K0.01)Σ0.98(Mn2+1.84Fe2+0.13)Σ1.97(Fe3+1.97Al0.03)Σ2.00(P3.01O11.94)(OH)Σ3.06. Plumboperloffite is monoclinic, space group P21/m with a = 9.1765(18), b = 12.340(3), c = 5.0092(10) Å, β = 101.01(3)°, V = 556.8(2) Å3 and Z = 2. The crystal structure has been refined using X-ray single-crystal data to a final R1 = 0.0207 on the basis of 1417 reflections with Fo > 4σ(Fo). The mineral is isostructural with members of the bjarebyite-group minerals.

Bimbowrieite, NaMgFe3+5(PO4)4(OH)6⋅2H2O, is a new mineral found in a mineralogically zoned rare-element bearing pegmatite at the White Rock No.2 quarry, Bimbowrie Conservation Park, South Australia, Australia. Crystals are dark olive green to greenish brown and are bladed with dimensions of up to 150 μm. Crystals occur as aggregates up to 0.4 mm across associated with ushkovite, bermanite, leucophosphite and sellaite. Bimbowrieite is pleochroic, biaxial (+), with α = 1.785(5), β = 1.795(5), γ = 1.805(5) and 2V(meas.) = 89.4(5)°. The average of 28 chemical analyses gave the empirical formula: (Na0.81Ca0.19)Σ1.00(Mg0.75Mn2+0.19Fe2+0.05)Σ0.99(Fe3+4.99Al0.01)Σ5.00(PO4)3.97(OH)5.88⋅2.05 H2O based on 24 oxygen atoms. Bimbowrieite is monoclinic, space group C2/c with a = 25.944(5), b = 5.1426(10), c = 13.870(3 Å, β = 111.60(3)°, V = 1720.4(7) Å3 and Z = 4. The crystal structure was refined to R1 = 1.97% for 1060 observed reflections with F0 > 4σ(F0). Bimbowrieite is isostructural with dufrénite. The structure is based on a trimer of face-sharing octahedra in which an M2 octahedra shares two trans faces with two M4 octahedra. Trimers link in the c-direction by sharing corners with two M3 octahedra and with T1 and T2 tetrahedra. Linkage in the a-direction is via corner-sharing M1 octahedra and linkage in the b-direction is via corner-sharing T1 and T2 tetrahedra.

The ideal period for implementing environmental education or education for sustainability is during the early childhood years. The educational context of playgroups can be a platform for both children and their parents to learn together and together engage in early childhood education for sustainability (ECEfS), however there is a paucity of literature examining ECEfS within Australian playgroup contexts. The Little Explorers Playgroup (LEP) is a facilitated playgroup located in a sustainable living centre in Sydney, Australia, and provides opportunities for children and their parents to engage in ECEfS. The study purpose was to evaluate the effect of the LEP on the participating children and parents’ environmental attitudes and behaviours. This qualitative study was designed as a single critical case study employing semi-structured telephone interviews conducted with twenty-three participants, including three LEP playgroup facilitators and 20 parents. The data generated by the interviews was analysed thematically and the findings indicated that the LEP empowered and positively transformed both the children and parents’ environmental attitudes and behaviours. This was evident through the children and parents’ adoption of more environmentally responsible attitudes and behaviours. The findings demonstrate that playgroups may be an untapped opportunity for facilitating community change towards sustainable living.

Wortupaite (IMA2022–107) is a new hydrated magnesium nickel tellurite mineral with a zemannite-like structure, described from the Wortupa gold mine, South Australia, Australia. Wortupaite forms needles up to 25 μm in length, generally clustered and sometimes in blocky masses of shorter (10‒15 μm) crystals. Wortupaite is found growing on melonite, from which the component nickel and tellurium are derived, and is associated with calcite. The strongest powder diffraction lines are [dobsÅ(Iobs)(hkl)]: 8.059 (93) (100), 4.034 (92) (200), 2.832 (43) (211 and 121), 2.769 (100) (202) and 1.920 (45) (213 and 123). The empirical formula of wortupaite as determined by electron probe microanalysis is (Mg0.57Ni0.39Mn0.04)Σ1(Ni2+1.87Fe3+0.13)Σ2(Te4+O3)3⋅3H2O, simplified to the ideal formula of MgNi2+2(Te4+O3)3⋅3H2O with H2O content calculated from the crystal structure. The average crystal structure of wortupaite was determined by single-crystal X-ray diffraction with synchrotron radiation (R1 = 0.0558 for 100 independent reflections). Wortupaite is hexagonal, crystallising in the space group P63/m, with a = 9.2215(13) Å, c = 7.5150(15) Å, V = 553.43(19) Å3 and Z = 2. Wortupaite has a microporous structure, with the negatively charged zemannite-like framework formed by Te4+O3 trigonal pyramids and Ni2+O6 octahedra. For charge balance, Mg2+ and Ni2+ dominant sites are assumed to be located on central sites in the channels, coordinated by 6 H2O groups. An OW site was refined around the Mg2+ dominant site, but OW position(s) were not locatable around the Ni2+ dominant site. A discussion of the different models for crystallographic arrangement of channel species is provided, taking into account possible Fourier truncation effects. Unlike the other four minerals with zemannite-like structures which have a near 50% split of divalent and trivalent framework cations, wortupaite is the first natural phase to have only divalent cations in the framework sites.

In the wake of World War I and the Spanish flu epidemic, the Anglican layman James Moore Hickson embarked on a five- year international healing ministry. What circumstances contributed to his positive reception by the public and the press, and how did he gain episcopal support and private audiences with the archbishop of Canterbury? Hickson's ministry in Western Australia near the end of his global tour sheds light on some of the reasons why his ministry was so widely accepted.

This article is a clinical guide which discusses the “state-of-the-art” usage of the classic monoamine oxidase inhibitor (MAOI) antidepressants (phenelzine, tranylcypromine, and isocarboxazid) in modern psychiatric practice. The guide is for all clinicians, including those who may not be experienced MAOI prescribers. It discusses indications, drug-drug interactions, side-effect management, and the safety of various augmentation strategies. There is a clear and broad consensus (more than 70 international expert endorsers), based on 6 decades of experience, for the recommendations herein exposited. They are based on empirical evidence and expert opinion—this guide is presented as a new specialist-consensus standard. The guide provides practical clinical advice, and is the basis for the rational use of these drugs, particularly because it improves and updates knowledge, and corrects the various misconceptions that have hitherto been prominent in the literature, partly due to insufficient knowledge of pharmacology. The guide suggests that MAOIs should always be considered in cases of treatment-resistant depression (including those melancholic in nature), and prior to electroconvulsive therapy—while taking into account of patient preference. In selected cases, they may be considered earlier in the treatment algorithm than has previously been customary, and should not be regarded as drugs of last resort; they may prove decisively effective when many other treatments have failed. The guide clarifies key points on the concomitant use of incorrectly proscribed drugs such as methylphenidate and some tricyclic antidepressants. It also illustrates the straightforward “bridging” methods that may be used to transition simply and safely from other antidepressants to MAOIs.

Kingsgateite, ZrMo6+2O7(OH)2⋅2H2O, is a new supergene mineral from the Old 25 Pipe, Kingsgate, Gough Co., New South Wales, Australia. The mineral occurs in cavities in a quartz, muscovite matrix associated with molybdenite, gelosaite and mambertiite. It forms yellowish green to bluish grey, square tabular crystals to 0.12 mm across. Kingsgateite has a white streak and a vitreous lustre. Cleavage was not observed and the fracture is uneven. The calculated density is 3.74 g/cm–3 based on the empirical formula. Kingsgateite is optically biaxial (+), the calculated indices of refraction are α = 1.88, β = 1.89, γ = 1.96 and 2Vcalc = 42.6°. The pleochroism is X = light orange, Y = light yellow and Z = red brown; Y < X < Z. The mineral is tetragonal, space group I41cd, a = 11.4626(16), c = 12.584(3) Å, V = 1653.4(6) Å3 and Z = 8. Electron microprobe analysis yielded ZrO2 23.09, UO2 1.14, ThO2 0.76, FeO 0.62, MoO3 59.27, P2O5 0.29, SO3 1.25, Cl 0.16, H2O 11.62, O=Cl –0.04, total 98.16 wt.%. The empirical formula on the basis of 11 anions per formula unit is Zr0.88U6+0.02Th0.01Fe2+0.04Mo6+1.94S0.07P0.02O6.90Cl0.02OH2.08⋅2.00H2O. The crystal structure of kingsgateite, refined using synchrotron single-crystal data [R1 = 4.53% for 1159 reflections with Fo > 4σ(Fo)], is a framework of edge- and corner-sharing ZrO5(OH)2 pentagonal bipyramids and MoO4(OH)(H2O) octahedra. Kingsgateite is isostructural with the synthetic compound ZrMo6+2O7(OH)2⋅2H2O.

Reaphookhillite, ideally MgZn2(PO4)2⋅4H2O, is a new phosphate mineral from Reaphook Hill, Flinders Ranges, South Australia, Australia. Reaphookhillite occurs as colourless, bladed to thin tabular crystals to 0.6 mm across. Cleavage is perfect parallel to {010}. The mineral occur as overgrowths on parahopeite crystals and is associated with scholzite, leucophosphite and chalcophanite. The calculated density is 3.09 g/cm3 from the empirical formula. Reaphookhillite is optically biaxial (+), α = 1.583(3), β = 1.596(3), γ = 1.611(3) and 2Vcalc = 88.7°. Electron microprobe analyses gave ZnO 41.57, MgO 7.96, MnO 0.40, P2O5 33.72, H2O(calc) 16.92, total 100.57 wt.%. The empirical formula, based on 12 O apfu, is Mg0.83Zn2.16Mn2+0.02(PO4)2.01⋅3.97H2O. Reaphookhillite is triclinic, P${\bar 1}$, with the unit-cell parameters of a = 5.7588(12), b = 7.5341(15) c = 5.2786(11) Å, α = 93.44(3), β = 91.27(3), γ = 91.30(3)°, V = 228.49(8) Å3 and Z = 1. The strongest eight lines in the powder X-ray diffraction pattern are [dobs in Å (I) (hkl)] 7.577 (100) (010); 4.461 (24) (01${\bar 1}$); 4.461 (24) (01${\bar 1}$); 3.771 (14) (020); 3.158 (13) (02${\bar 1}$); 2.982 (32) (021); 2.880 (27) (200); 2.775 (14) (1${\bar 2}$1, 12${\bar 1}$); and 2.668 (13) (1${\bar 2}{\bar 1}$, 210). Reaphookhillite is isostructural with parahopeite, with Mg replacing Zn in the 6-coordinated site in the structure. The structure contains ZnO4 and PO4 tetrahedra which share corners to form a sheet in the (001) plane. Sheets are linked in the c direction by corner sharing MgO2(H2O)4 octahedra.

Magnesiobermanite, MgMn3+2(PO4)2(OH)2⋅4H2O, is a new secondary phosphate mineral and the Mg analogue of bermanite found in a granitic pegmatite at the White Rock No.2 quarry situated in the Bimbowrie Conservation Park, South Australia, Australia. Magnesiobermanite occurs as aggregates of twinned, bladed to tabular crystals, up to 1.2 mm across. Individual crystals are up to 0.3 mm in length. The crystals are orange–red to brownish red, with a vitreous lustre and a salmon-pink streak. The mineral is brittle with a conchoidal fracture and a good cleavage on {100}. The mineral is biaxial (–), with α = 1.690(2), β = 1.719(2) and γ = 1.734(2) (white light). The calculated 2V is 70.4°. Electron microprobe analyses provided: MgO 9.59, Mn2O3 27.41, Fe2O3 8.84, Al2O3 0.18, P2O5 33.27, H2O 20.94, total 100.23 wt.%. The empirical formula (based on 14 O atoms) is: Mg1.02(Mn3+1.49Fe3+0.47Al0.02)1.98(PO4)2.01(OH)1.95⋅4.01H2O. Magnesiobermanite is monoclinic, space group P21, with the unit-cell parameters: a = 5.4215(11), b = 19.072(4), c = 5.3889(11) Å, β = 110.21(3)°, V = 522.89(18) Å3 and Z = 2. The crystal structure was refined to an R1 index of 2.43% based on for 3222 observed reflections with Fo > 4σ(Fo). Magnesiobermanite is isostructural with bermanite, Mn2+Mn3+2(PO4)2(OH)2⋅4H2O, from which it derives its name. The structure is based upon a sheet of the form [(M(OH)2(PO4)2] in the (010) plane. Sheets are linked in the b direction by [M3(H2O)4O2] octahedra and by hydrogen bonds.

Aldermanite from Tom's quarry in the Kapunda–Angaston area of the Mount Lofty Ranges, South Australia has been characterised by electron microprobe analyses and single-crystal structure analysis. The empirical formula is Na0.72K0.13Ca0.06Mg1.15Al2.92(PO4)2.05[(OH)2.92F2.96]Σ5.88⋅8.91H2O, based on 23 anions. Analysis of a specimen from the type locality, the nearby Klemm's quarry, Moculta, gave a similar formula, Na0.59K0.06Ca0.36Mg0.92Al3.16(PO4)1.97[(OH)4.08F2.70]Σ6.78⋅8.36H2O. Na and F were not analysed in the original description of the mineral. The ideal end-member formula is [Mg(H2O)6][Na(H2O)2Al3(PO4)2(OH)6]⋅H2O, compared to the original formula of Mg5Al12(PO4)8(OH)22⋅nH2O with n ≈ 32. Aldermanite is monoclinic, P21/c with a = 13.524(3), b = 9.958(2), c = 7.013(1) Å and β = 97.40(3)°. The crystal structure of aldermanite is built from sawtooth layers of cis- and trans-corner-connected, Al-centred octahedra, decorated with corner-connected PO4 tetrahedra to give (100) layers of composition Al3(PO4)2(OH,F)6. Interlayer Mg(H2O)6 octahedra and H2O molecules hold the layers together through H bonding. The corner-connected octahedra form 6-membered rings that are centred by 8-coordinated Na and have a topology identical to a 3-octahedra-wide {110} slice of the pyrochlore structure. This pyrochlore element contains intersecting kagomé nets of Al atoms, parallel to (111) and (11$\bar{1}$) of cubic pyrochlore. Minerals of the walentaite group, as well as zirconolite-3O polytypes have the same type of intersecting kagomé nets of small cations.

Baumoite, Ba0.5[(UO2)3O8Mo2(OH)3](H2O)~3, is a new mineral found near Radium Hill, South Australia, where it occurs in a granite matrix associated with baryte, metatorbernite, phurcalite and kaolinite. Baumoite forms thin crusts of yellow to orange–yellow tabular to prismatic crystals. The mineral is translucent with a vitreous lustre and pale yellow streak. Crystals are brittle, the fracture is uneven and show one excellent cleavage. The Mohs hardness is ~2½. The calculated density is 4.61 g/cm3. Optically, baumoite crystals are biaxial (–), with α = 1.716(4), β = 1.761(4), γ = 1.767(4) (white light); and 2Vcalc = 42.2°. Electron microprobe analyses gave the empirical formula Ba0.87Ca0.03Al0.04U2.97Mo2.02P0.03O22H11.99, based on 22 O atoms per formula unit. The eight strongest lines in the powder X-ray diffraction pattern are [dobs Å (I) (hkl)]: 9.175(39)(12${\bar 1}$), 7.450(100)(020), 3.554(20)(221), 3.365(31)(004, 202), 3.255(31)(123, 30${\bar 2}$), 3.209(28)(12${\bar 4}$), 3.067(33)(30${\bar 3}$, 222, 32${\bar 2}$) and 2.977(20)(142). Single-crystal X-ray studies (R1 = 5.85% for 1892 main reflections) indicate that baumoite is monoclinic, superspace group X2/m(a0g)0s with X = (0,½,0,½), with unit-cell parameters: a = 9.8337(3), b = 15.0436(5), c = 14.2055(6) Å, β = 108.978(3)°, V = 1987.25(13) Å3 and Z = 4. The crystal structure is twinned and incommensurately modulated and is based upon sheets of U6+ and Mo6+ polyhedra of unique topology. Four independent cationic sites partially occupied by Ba atoms are located between the sheets, together with H2O molecules.

The new mineral species barlowite, ideally Cu4FBr(OH)6, has been found at the Great Australia mine, Cloncurry, Queensland, Australia. It is the Br and F analogue of claringbullite. Barlowite forms thin blue, platy, hexagonal crystals up to 0.5 mm wide in a cuprite-quartz-goethite matrix associated with gerhardtite and brochantite. Crystals are transparent to translucent with a vitreous lustre. The streak is sky blue. The Mohs hardness is 2–2.5. The tenacity is brittle, the fracture is irregular and there is one perfect cleavage on {001}. Density could not be measured; the mineral sinks in the heaviest liquid available, diluted Clerici solution (D &3.8 g/cm3). The density calculated from the empirical formula is 4.21 g/cm3. Crystals are readily soluble in cold dilute HCl. The mineral is optically non-pleochroic and uniaxial (–). The following optical constants measured in white light vary slightly suggesting a small variation in the proportions of F, Cl and Br: ω 1.840(4)–1.845(4) and ε 1.833(4)–1.840(4). The empirical formula, calculated on the basis of 18 oxygen atoms and H2O calculated to achieve 8 anions and charge balance, is Cu4.00F1.11Br0.95Cl0.09(OH)5.85. Barlowite is hexagonal, space group P63/mmc, a = 6.6786(2), c = 9.2744(3) Å , V = 358.251(19) Å3, Z = 2. The five strongest lines in the powder X-ray diffraction pattern are [d(Å )(I)(hkl)]: 5.790(100)(010); 2.889(40)(020); 2.707(55)(112); 2.452(40)(022); 1.668(30)(220).

Middlebackite is a new supergene mineral formed in the upper levels of the Iron Monarch quarry, South Australia. It occurs as aggregates of blue, prismatic crystals up to 0.3 mm across comprising individual crystals up to 0.05 mm in length associated with atacamite and mottramite. Crystals are translucent with a vitreous lustre and have a pale blue streak. Middlebackite is brittle with one perfect cleavage and uneven fracture. Mohs hardness is ~2. The calculated density is 3.64 g cm–3. Crystals are biaxial (+) with α = 1.663(4), β = 1.748(4) and γ = 1.861(4) (measured in white light). The calculated 2V is 86.7°. Pleochroism is X = colourless, Y = very pale blue and Z = dark sky blue; Z > Y > X. The empirical formula unit, based on six oxygen atoms per formula unit is Cu2.00(C2O4)Cl0.02(OH)1.98. Middlebackite is monoclinic, space group P21/c with a = 7.2597(15), b = 5.7145(11), c = 5.6624(11) Å, β = 104.20(3)°, V = 227.73(8) Å3 and Z = 2. The five strongest lines in the powder X-ray diffraction pattern are [d(Å), (I), (hkl)]: 7.070 (16) (100), 3.739 (100) (11$\bar{1}$), 2.860 (18) (020), 2.481 (12) (12$\bar{1}$) and 2.350 (9) (300). The crystal structure was refined from synchrotron single-crystal X-ray diffraction data to R1 = 0.0341 for 596 observed reflections with F0 > 4σ(F0). The structure is based on sheets of edge- and corner-sharing octahedra parallel to the bc plane. Sheets link in the a direction via oxalate anions.

The crystal structure of the copper aluminium phosphate mineral sieleckiite, Cu3Al4(PO4)2 (OH)12·2H2O, from the Mt Oxide copper mine, Queensland, Australia was solved from single-crystal X-ray diffraction data utilizing synchrotron radiation. Sieleckiite has monoclinic rather than triclinic symmetry as previously reported and is space group C2/m with unit-cell parameters a = 11.711(2), b = 6.9233(14), c = 9.828(2) Å, β = 92.88(3)°, V = 795.8(3) Å3and Z = 2. The crystal structure, which has been refined to R1 = 0.0456 on the basis of 1186 unique reflections with Fo > 4σF, is a framework of corner-, edge- and face- sharing Cu and Al octahedra and PO4 tetrahedra.