The hypothesis that chemical remanent magnetization (CRM) in argillaceous rocks may be due to release of Fe during smectite illitization has been tested by study of spatial and temporal relationships of CRM acquisition, smectite illitization, and organic-matter maturation to deformation in the Montana Disturbed Belt. New K-Ar ages and stacking order and percentages of illite layers in illite-smectite (I-S) are consistent with conclusions from previous studies that smectite illitization of bentonites in Subbelts I and II of the Disturbed Belt was produced by thrust-sheet burial resulting from the Laramide Orogeny. Internally concordant, early Paleogene, K-Ar age values (55–57 Ma) were obtained from clay subfractions of thick bentonites which were significantly different in terms of their ages (i.e. Jurassic Ellis Formation and late Cretaceous Marias River Shale), further supporting a model of smectite illitization as a result of the Laramide Orogeny. Internally concordant K-Ar ages were found also for clay sub-fractions from a thick bentonite at Pishkun Canal (54 Ma) and from an undeformed bentonite near Vaughn on the Sweetgrass Arch (48 Ma). In Subbelts I and II, a greater degree of smectite illitization corresponds to increased thermal maturation, increased natural remanent magnetization intensity, and increased deformation (dip of beds). A dissolution-precipitation model over a short duration is proposed for the formation of illite layers in Subbelts I and II. A characteristic remanent magnetization was developed before or just after folding began in the early Paleogene. More smectite-rich I-S, low thermal maturity, and the absence of a CRM were noted in one outcrop of an undeformed rock on the Sweetgrass Arch. Strontium isotope data allow for the possibility that internal or externally derived fluids may have influenced illitization, but the K-Ar age values suggest that illitization was probably in response to conductive heating after the overthrusting had occurred. The differences in K-Ar dates among the bentonites studied herein may be due to differences in the timing of peak temperature related to differences in distance below the overthrust slab, in rates of burial and exhumation, and in initial temperature.

Successions in Oklahoma and Nevada record trilobite extinction and replacement near the Steptoean–Sunwaptan boundary in inner-shelf and outer-shelf settings, respectively. Prior to the extinctions, different trilobite biofacies occupied these environments, but faunas became similar in composition across the environmental gradient in the overlying I. “major” and Taenicephalus zones. Faunal changes in the outer shelf at the I. “major” Zone begin at a drowning unconformity that brought dark, laminated calcisiltite and silty lime mudstone above a subtidal carbonate succession. In contrast, Oklahoma shows facies continuity in a succession of tidally influenced bioclastic carbonates. Loss of genera and a dramatic abundance “spike” of Irvingella are features of the I. “major” Zone in both regions. Turnover of biofacies occurred in the succeeding Taenicephalus Zone, with both the inner and outer shelf dominated by Orygmaspis (Parabolinoides). Blooms of orthid brachiopods in shallow water settings are underappreciated signals of faunal change in the extinction interval. Although absent from the outer shelf in Nevada, orthids became abundant enough in Oklahoma to form shell beds in the lower Taenicephalus Zone, but became rare in overlying strata. Carbon isotope stratigraphy includes a modest positive δ13C excursion that peaks in the extinction interval at 1.4‰ (Oklahoma) and 2.2‰ (Nevada), which is congruent with previous reports from Utah and Wyoming. Although consistent with regional upwelling of dysoxic waters, the absence of sedimentary evidence for significant environmental change over much of the shelf is problematic. This suggests that physical environmental change acted primarily as a catalyst for cascading ecological and biogeographic effects.

In different parts of the world, aphid populations and their natural enemies are influenced by landscapes and climate. In the Neotropical region, few long-term studies have been conducted, maintaining a gap for comprehension of the effect of meteorological variables on aphid population patterns and their parasitoids in field conditions. This study describes the general patterns of oscillation in cereal winged aphids and their parasitoids, selecting meteorological variables and evaluating their effects on these insects. Aphids exhibit two annual peaks, one in summer–fall transition and the other in winter-spring transition. For parasitoids, the highest annual peak takes place during winter and a second peak occurs in winter–spring transition. Temperature was the principal meteorological regulator of population fluctuation in winged aphids and parasitoids during the year. The favorable temperature range is not the same for aphids and parasitoids. For aphids, temperature increase resulted in population growth, with maximum positive effect at 25°C. Temperature also positively influenced parasitoid populations, but the growth was asymptotic around 20°C. Although rainfall showed no regulatory function on aphid seasonality, it influenced the final number of insects over the year. The response of aphids and parasitoids to temperature has implications for trophic compatibility and regulation of their populations. Such functions should be taken into account in predictive models.

While lithium is well known for its neurotoxicity, there are very few publications about lithium-induced acute dystonic reaction. We are presenting a clinical case of lithium-induced acute intermittent dystonic reaction in a patient with schizoaffective disorder (SAD). The patient is a 69-year-old African-American male with a long history of SAD, who was treated for many years with ziprasidone and divalproex and was admitted with SAD exacerbation. Due to increased QTC interval, we switched patient to lurasidone. After 2 weeks, due to increased ammonia level, divalproex was switched to lithium (600 mg loading dose and then 450 mg twice/day). Three days later, patient developed a series of intermittent episodes of acute dystonia, manifested as mutism, dysarthria, upper and lower extremity muscle rigidity, dysphagia, and tremor (Table 1). Dystonic reactions responded to benztropine. Eventually, lithium was discontinued and patient did well on a combination of carbamazepine and olanzapine. In this case, we would like to emphasize not only the intermittent but also the atypical presentation of acute dystonic reactions with involvement of large muscle groups, the resemblance to NMS, and a “spectrum” of dystonic reactions rather than one clear-cut presentation. We can only speculate the role lurasidone played in this presentation but reoccurrence of dysarthria on day 54 after lithium was restarted points to its major role.

Table not available.

We present ALMA band 7 data of the extreme OH/IR star, OH 26.5+0.6. In addition to lines of CO and its isotopologues, the circumstellar envelope also exhibits a number of emission lines due to metal-containing molecules, e.g., NaCl and KCl. A lack of C18O is expected, but a non-detection of C17O is puzzling given the strengths of H217O in Herschel spectra of the star. However, a line associated with Si17O is detected. We also report a tentative detection of a gas-phase emission line of MgS. The ALMA spectrum of this object reveals intriguing features which may be used to investigate chemical processes and dust formation during a high mass-loss phase.

Sedimentary basins developed along the European margin during the earliest, Permian, stage of proto-Atlantic rifting, during a phase of high heat flow. The proximity of some basins to Caledonian thrusts has implied that rifts locally utilized the basement fabric. New mineralogical and palaeomagnetic data show that thrust planes in the Moine Thrust Zone channelled a pulse of hot fluid in Permian time. The fluids precipitated kaolin in fractures in the thrust zone, and with decreasing intensity away from the zone. The high-temperature polytype dickite is largely confined to major thrust planes. Stable H and O isotope analyses indicate that the parent fluid included meteoric water involved in a hydrothermal system. Coeval hydrothermal hematite has a chemical remanence that dates the fluid pulse as Permian. This is direct evidence for post-orogenic activity in the thrust zone, in which the thrusts vented excess heat during regional crustal extension. The example from the European margin exemplifies the importance of deep-seated structures in the release of heat, and the value of kaolinite polytype mapping as a tool to record anomalous palaeo-heat flow.

Snow sublimation is a fundamental process that affects the snow crystal structure and is important for ice-core interpretation, remote sensing, snow hydrology and chemical processes in snow. Prior studies have shown that sublimation can change the isotopic content of the remaining snow; these studies have inferred sublimation rates using field data, and were unable to control many of the environmental parameters that determine sublimation rate (e.g. temperature, relative humidity, snow microstructure). We present sublimation rate measurements on snow samples in the laboratory, where we have controlled many of these parameters simultaneously. We use the same experimental apparatus to determine sublimation rate, investigate the isotopic effects of sublimation, and study the isotopic exchange between vapor and solid. Our results suggest that pore spaces in snow are almost always at saturation vapor pressure; undersaturation may be possible in large pore spaces or in regions of rapid interstitial airflow. We present a revised formulation for determining the mass-transfer coefficient for snow as a linear function of Reynolds number (hm = 0.566Re + 0.075), estimate the fractionation coefficient for sublimating snow, and provide evidence for isotopic exchange between vapor and solid.

Among weevils of the subfamily Baridinae (548 extant genera and ca. 9,000 species), unique prosternal horns and associated sheaths have evolved independently multiple times. These structures are utilized in a unique form of male-male aggression in which males push, rather than overturn as in most other horned beetles, their competitor. Herein we report the first fossils of male Baridinae exhibiting such prosternal horns. Two males recovered from the middle Eocene Green River Formation in northwestern Colorado serve to provide a minimum age (at ca. 47 million years old) for both the origin of horns and its associated form of male-male combat in Baridinae.

Deflection missions to near-Earth asteroids will encounter non-negligible uncertainties in the physical and orbital parameters of the target object. In order to reliably assess future impact threat mitigation operations such uncertainties have to be quantified and incorporated into the mission design. The implementation of deflection demonstration missions offers the great opportunity to test our current understanding of deflection relevant uncertainties and their consequences, e.g., regarding kinetic impacts on asteroid surfaces. In this contribution, we discuss the role of uncertainties in the NEOTωIST asteroid deflection demonstration concept, a low-cost kinetic impactor design elaborated in the framework of the NEOShield project. The aim of NEOTωIST is to change the spin state of a known and well characterized near-Earth object, in this case the asteroid (25143) Itokawa. Fast events such as the production of the impact crater and ejecta are studied via cube-sat chasers and a flyby vehicle. Long term changes, for instance, in the asteroid's spin and orbit, can be assessed using ground based observations. We find that such a mission can indeed provide valuable constraints on mitigation relevant parameters. Furthermore, the here proposed kinetic impact scenarios can be implemented within the next two decades without threatening Earth's safety.

Extended abstract of a paper presented at Microscopy and Microanalysis 2013 in Indianapolis, Indiana, USA, August 4 – August 8, 2013.

We discuss the first applications of our newly developed Monte Carlo event generator SOPHIA to multiparticle photoproduction of relativistic protons with thermal and power-law radiation fields. The measured total cross section is reproduced in terms of excitation and decay of baryon resonances, direct pion production, diffractive scattering, and non-diffractive multiparticle production. Non-diffractive multiparticle production is described using a string fragmentation model. We demonstrate that the widely used ‘Δ-approximation’ for the photoproduction cross section is reasonable only for a restricted set of astrophysical applications. The relevance of this result for cosmic ray propagation through the microwave background and hadronic models of active galactic nuclei and gamma-ray bursts is briefly discussed.