Large-scale streaky structures (LSSs) in a temporally developing compressible turbulent mixing layer are investigated using numerical simulations at convective Mach numbers up to
$M_c = 5.0$, corresponding to turbulent Mach numbers approaching 1.0. This significantly extends existing numerical studies of compressible mixing layers, which are typically limited to convective Mach numbers of
$M_c \approx 2.0$, far below the flow conditions encountered in practical applications such as rocket engines and hypersonic vehicles. As compressibility increases, the growth rate of the momentum thickness decreases continuously without showing signs of saturation, accompanied by a significant increase in the length of the LSSs. In instantaneous flow field, the length of LSSs can exceed 100 times the vorticity thickness
$\delta _\omega$ at
$ M_c=4.0$. This behaviour is closely connected to the reduction of the pressure–strain redistribution of turbulent kinetic energy with increasing Mach number. Under strong compressibility, the growth stage is dominated by the streamwise components of production and dissipation, generating long, coherent streaks. As small-scale motions emerge, pressure–strain redistribution intensifies, transferring energy from the streamwise to the vertical and spanwise components and inducing streak meandering and breakdown. In the self-similar regime, production, dissipation and redistribution of kinetic energy reach a dynamic equilibrium. The spanwise scale of the LSSs is weakly affected by compressibility and converges to
$0.4\delta _\omega$ with the increase of Mach number. Increasing compressibility enhances flow anisotropy, leading to the progressive reduction of vertical and spanwise turbulent kinetic energy relative to the streamwise component, with the vertical component experiencing a more pronounced reduction.