Settling and collision of spheroidal particles with an offset mass centre in a quiescent fluid

Abstract Gravitational sedimentation and the collision of particles play key roles in various natural and engineering processes. In practice, particles are often non-spherical in shape with non-uniform mass distribution. In this study we investigate how the mass eccentricity influences the settling and gravitational collision of non-spherical particles in a quiescent fluid. Firstly, we theoretically analyse the effect of mass centre offset on the settling motion of a single spheroid under the low-Reynolds-number assumption. We find that the competition of fluid-inertia torque and gravitational torque determines the terminal settling mode of the spheroid. As the mass centre offset increases from zero to a critical value, the orientation of a settling spheroid undergoes a transition from the broad-side-on to narrow-side-on alignment. With an intermediate mass centre offset, the settling spheroid prefers an oblique orientation with a horizontal drift. Secondly, we investigate the gravitational collision rate of settling spheroids. With the change of particle orientation, the collision kernel exhibits a non-monotonic variation with a maximum when particles settle with an intermediate oblique orientation. Therefore, adjusting the mass centre offset to alter particle orientation can indirectly affect the collision rate of settling spheroidal particles. In summary, our findings reveal the significance of the mass eccentricity on particle dynamics in fluid flows, and suggest a potential approach for manipulating the settling motion and collision rate of non-spherical particles by adjusting their mass centre position.


Particle collisions
The collision-coagulation of particulate matters in fluids is ubiquitous in various natural and industrial scenarios.For instance, the coagulation of sinking marine debris determines the formation of marine snow in oceans (Jackson 1990;McDonnell & Buesseler 2010).This process holds significant biogeochemical importance as it contributes to global carbon fixation (Trudnowska et al. 2021;Arguedas-Leiva et al. 2022).Besides, the collision-coalescence of droplets or ice crystals in the atmosphere plays an important role in the growth of clouds (Grabowski & Wang 2013;Naso et al. 2018), which directly influences the formation of precipitation and, consequently, impacts weather patterns.In addition, in the papermaking industry the aggregation of fibre flocs affects the paper quality (Lundell, Söderberg & Alfredsson 2011).Thus, the understanding and manipulation of particle coagulation are essential for addressing environmental concerns and optimizing industrial operations.
To model the coagulation of particles in fluid flows, Wang, Wexler & Zhou (1998) and Wang et al. (2008) proposed to decompose this problem into three interrelated processes: (1) geometric collision, which refers to the physical encounter among particles without the consideration of particle-particle hydrodynamic interactions.This process is primarily caused by turbulence transport or particle settling motion.(2) Hydrodynamic interaction, which can either enhance the collision rate by far-field many-body hydrodynamic interactions or attenuates it through short-range binary interactions (Wang et al. 2008).
(3) Coagulation, which determines whether two particles coagulate or separate after a collision.Until now, extensive studies have been conducted on the geometric collision of spherical particles in various fluid flows.Smoluchowski (1917) theoretically demonstrated that the collision rate of tracer-like spherical particles is proportional to the shear rate in a linear shear flow.Wang et al. (2008) indicated that the collision of settling spherical particles in a quiescent fluid is caused by the settling velocity difference.In homogeneous isotropic turbulence (HIT), Saffman & Turner (1956) first derived the collision kernel of tracer-like spherical particles, which is a function of turbulence dissipation rate, fluid viscosity and collision diameter.Subsequently, several researchers further explored the collision of inertial particles in HIT (Abrahamson 1975;Sundaram & Collins 1997;Wang, Wexler & Zhou 2000).It has been found that the effect of particle inertia is to enhance the collision rate either by increasing particle relative velocity (Falkovich, Fouxon & Stepanov 2002) or by increasing particle local concentration (Maxey 1987;Eaton & Fessler 1994).
In practice, the dispersed particles are commonly non-spherical, which motivates the investigation of shape effect on particle collision rate.Siewert, Kunnen & Schröder (2014) and Slomka & Stocker (2020) studied the geometric collision of settling non-spherical particles in the quiescent fluid.They demonstrated that, unlike spherical particles, the collision rate of mono-dispersed elongated particles is non-zero, owing to the difference of settling velocity of elongated particles with random orientations.Moreover, Jucha et al. (2018) and Arguedas-Leiva et al. (2022) investigated the collision rate of non-spherical particles in HIT through numerical simulations.They observed a significant enhancement of the collision rate of disk-like or rod-like particles compared with spherical ones, and highlighted the importance of particle orientation in the collision of non-spherical particles.Furthermore, by means of the Monte Carlo simulation, Gruy & Nortier (2017) investigated the collision rate of spheroidal particles in a linear shear flow, and found that the size and shape of particles can influence the collision rate.

Particles with non-uniform mass distribution
Another issue worth concern in practical applications is the non-uniform mass distribution of the particle, which induces a non-coincidence of particle mass centre and geometric centre.Examples are commonly seen, such as some planktons with non-uniformly distributed organelles (Sengupta, Carrara & Stocker 2017), bottom-heavy maple seeds with a heavy embryo on one side of the seed (Lee & Choi 2017) and ice crystals containing entrapped air bubbles or impurities (Maeno 1967;Bogdan 2018).Under the action of gravity, the non-coincidence between particle mass centre and geometric centre induces a gravitational torque that affects particle dynamics.For example, the offset between the mass centre and geometric centre of swimming microorganisms results in a gyrotaxis effect (Kessler 1986;Pedley 1987), which drives the microorganisms to align upwards and promotes their vertical migration in oceans.
Several researchers have noticed this issue and studied on the motion of particles with mass eccentricity in fluids.On the one hand, for spherical particles, the influence of mass eccentricity is primarily on their rotational motion.Jenny, Duek & Bouchet (2004) reported a substantial alteration of the settling motion of a sphere in a still fluid because of an entrapped air bubble inside the particle.The bubble changes the mass centre position of the particle, inducing the instability of particle settling motion in the vortex shedding regime.Will & Krug (2021) fabricated a spherical shell with an adjustable inner heavy core to experimentally study the descending and ascending of a sphere with an offset mass centre.They observed a resonance between particle rotational motion and shed vortices by adjusting the position of the inner core to specific positions.Tanaka et al. (2020) investigated the motion of spherical particles with mass eccentricity in the homogeneous shear turbulence through numerical simulations.The gravitational torque caused by mass eccentricity was found to counteract part of the shear-induced torque, which results in a reduction in particle rotation rate and horizontal displacement.On the other hand, regarding non-spherical particles, orientation plays an important role on particle dynamics.It is well known that a settling cylinder or spheroid with a uniform mass distribution tends to align broad-side-on as the steady settling orientation under the action of a fluid-inertia torque (Jayaweera & Mason 1965;Khayat & Cox 1989;Dabade, Marath & Subramanian 2015).However, when the symmetry of mass distribution within the particle is broken, the gravitational torque can alter the aforementioned steady orientation of a settling non-spherical object.Yasseri (2014) and Angle, Rau & Byron (2019) experimentally studied the effect of mass distribution on the settling of a cylinder.As the density difference on the two sides of the cylinder increases, its alignment was found to transition from broad-side-on to tilted or narrow-side-on.Similarly, Roy et al. (2019) carried out experiments on the settling motion of a rod with asymmetric mass density.The orientation of the rod was found to follow a pitchfork bifurcation with the change of mass distribution.Moreover, in the experiments of falling thin plates with an offset mass centre at Re ∼ O(1000), Huang et al. (2013) andLi et al. (2022) observed a sensitive dependence of the plate falling motion on the change of its mass centre position.

Objects of the present study
However, to the best of the authors' knowledge, there are still unresolved questions regarding the settling motion of a non-spherical particle with an offset mass centre: What are the influential parameters in this problem, and how do these parameters affect particle settling motion?Moreover, there is also a lack of study on the collision rate of settling non-spherical particles with mass eccentricity.How the mass eccentricity affects particle collision behaviour, even in a quiescent fluid, is not known.These scientific problems, however, play important roles in practical applications.Hence, in the present study, we aim to investigate the effect of mass centre offset on the settling motion and collision rate of non-spherical particles.To simplify our problems, the present study is conducted under the following main assumptions.First, non-spherical particles are modelled as spheroids following the majority of earlier studies (Voth & Soldati 2017).Second, we only consider the settling motion of particles in a quiescent fluid under the low-Reynolds-number assumption.Third, complex particle-particle hydrodynamic interactions are disregarded when studying particle collisions.In principle, the present work is composed of two parts.In the first part, we investigate the stability of different settling modes of a single spheroid, and illustrate the bifurcation characteristics of the spheroid settling motion with the variation of relevant parameters.We observe a transition of the stable orientation of the settling spheroid, as well as a non-monotonic variation of the horizontal drift angle as the mass centre offset increases.Subsequently, in the second part of this work, we move on to studying the gravitational collision rate of settling spheroidal particles.The collision kernel exhibits a non-monotonic variation with the change of particle pitch angle.These findings altogether reveal the possibility for manipulating the settling motion and collision rate of non-spherical particles by adjusting their mass centre position.
The remainder of this paper is organized as follows.First, we describe the problem of settling and gravitational collision of spheroidal particles in a quiescent fluid in § 2. Subsequently, in § 3 we present the theory and numerical method involved in the current study.Then, we analyse the effect of mass centre offset on the settling motion of a single spheroidal particle in § 4, and focus on the gravitational collision rate of settling spheroidal particles with different orientations in § 5. Finally, we provide a discussion on the settling spheroidal particles with mass eccentricity in turbulent flows, and summarize key findings and prospects of this study in § 6.

Settling of a spheroidal particle with an offset mass centre
In figure 1 we depict the schematic of the spheroidal particle with an offset mass centre.The major and minor axes of the spheroid have a length of 2a and 2b, respectively.The aspect ratio of a spheroid is defined as λ = r p /r e , where r p is the polar radius and r e is the equator radius.Based on the shape, we can categorize spheroidal particles into two groups: prolate particles with r p = a, r e = b and λ > 1 (figure 1a); and oblate particles with r p = b, r e = a and λ < 1 (figure 1b).The equivalent diameter of the spheroid (the diameter of a sphere with the same volume as the spheroid) is denoted by D eq = 2(r 2 e r p ) 1/3 .In the present study we consider the gravity-driven settling motion of spheroidal particles with an offset mass centre.Gravity acts in the negative y direction (e g = −e y ) with the gravity acceleration g = ge g .The mass centre G of the spheroid deviates from its geometric centre C along the major axis, as illustrated in figure 1.The distance between point G and point C is defined as the mass centre offset in which R CG = x G − x C represents the vector from the geometric centre to the mass centre.(b) (a) . Schematic of the geometric collision between two settling spheroidal particles.The dotted lines depict particle settling trajectories.Note that the orientations and trajectories of different particles vary in the three-dimensional space, although the schematic here is two dimensional.

Geometric collision of settling spheroidal particles
The collision of settling spheroidal particles in a quiescent fluid is also investigated in the present study.Specifically, we only account for the geometric collision in a mono-dispersed system by neglecting particle-particle hydrodynamic interactions.Under this assumption, a collision event is equivalent to the physical encounter of two particles with different settling velocities.For example, as illustrated in figure 2(a), a collision event occurs when two settling particles encounter each other at time t = t 2 .However, in figure 2(b) a geometric collision cannot happen since the two particles settle with the same orientation and identical velocity.

Governing equations
In a viscous fluid the motion of a spheroidal particle with an offset mass centre is governed by Newton-Euler equations as follows: Note that (3.1) and (3.2) should be established with respect to the mass centre G of the particle rather than the geometric centre C. In (3.1), F H = ∂V p τ • n s dS is the resultant hydrodynamic force acting on the particle (where τ denotes the hydrodynamic stress and n s denotes the outer normal unit vector on the particle surface ∂V p ), F G = −ρ p V p ge y is the gravitational force and F B = ρ f V p ge y is the buoyancy force, v G represents the velocity of the mass centre and ρ p , ρ f and V p denote the particle density, fluid density and particle volume, respectively.In (3.2),I G denotes the moment of inertia of the particle with respect to the mass centre, ω is the angular velocity, T H,G represents the hydrodynamic torque about the mass centre and T B denotes the moment of buoyancy force with respect to the mass centre, which is calculated by As for a particle with an offset mass centre, I G is determined by the mass distribution inside the particle (see more details in Appendix A).In general, T H,G is calculated by where r G = x − x G represents the vector from the mass centre G to a point on the particle surface.In addition, we can also define a hydrodynamic torque with respect to the geometric centre C as The relationship between T H,G and T H,C can be derived as Note that the moment of gravitational force vanishes in (3.2) since its application point coincides with the mass centre G.

Low-Reynolds-number limit
We define the particle Reynolds number as Re p ≡ ρ f v C − u f @p D eq /μ.Here, u f @p denotes the fluid velocity at the position of the particle, v C is the velocity of the particle centroid and μ is the dynamic viscosity of the fluid.In the cases of a small particle Reynolds number, the hydrodynamic force acting on a spheroidal particle is the Stokesian drag formulated as (Happel & Brenner 1983) Here, the resistance tensor M st is given as in which X A and Y A are two dimensionless coefficients determined by the aspect ratio (see Appendix B).Moreover, in the low-Reynolds-number limit, the hydrodynamic torque acting on a spheroidal particle can be regarded as the superposition of shear-induced torque T J and fluid-inertia-induced torque T I (Sheikh et al. 2020), whose expressions are (Jeffery 1922;Dabade et al. 2015) and Here, the symbol '•' denotes the variable in the body-fixed frame (as depicted in figure 1); Ŝ and Ω represent the strain rate tensor and vorticity of the fluid at the position of the particle, respectively.Parameters α 0 , β 0 and h λ are dimensionless coefficients that are solely determined by the aspect ratio of the spheroid (see Appendix B).Furthermore, we emphasize that the Jeffery torque and fluid-inertia torque, as formulated in (3.6) and (3.7), refer to the hydrodynamic torques with respect to the geometric centre of the spheroid, i.e.T H,C = T J + T B .Therefore, by applying (3.3) to Newton-Euler equations (3.1) and (3.2), we can derive the following equations to govern the translational and rotational motions of a settling spheroid with an offset mass centre: (3.9) Hereinafter, we name the term T g = −R CG × (F st − ρ f V p g) as the gravitational torque, similar to Roy et al. (2019) and Tanaka et al. (2020).In addition, (3.4) and (3.7) involve the velocity of the geometric centre (v C ), which is related to the velocity of the mass centre (3.10)

Terminal velocity of a settling spheroid in a quiescent fluid
In a quiescent fluid the terminal velocity (denoted by v t ) of a settling spheroid with a pitch angle θ and azimuth angle φ (see figure 1) can be determined by the equilibrium of gravitational force, buoyancy force and Stokesian drag force.The expression of the terminal velocity is (3.11)where τ p is a time scale defined by According to (3.11), when the spheroid settles with its symmetry axis perpendicular to gravity (θ = 90 • ) or parallel to gravity (θ = 0 • ), the terminal velocity aligns with the gravitational direction.This allows us to define two characteristic settling velocities: v 1 corresponding to θ = 90 • and v 3 corresponding to θ = 0 • , with the following expressions: As for a prolate particle, v 1 is the broad-side-on (maximum-drag alignment) settling velocity, while v 3 corresponds to the narrow-side-on (minimum-drag alignment) settling velocity, with v 1 < v 3 .Conversely, for an oblate particle, the opposite is true so that v 1 > v 3 .With the above expressions of v 1 and v 3 , the terminal velocity v t in (3.11) can be equivalently expressed as (3.14)

Two-dimensional settling motion of a single spheroid in a quiescent fluid
In general, the oblate spheroid as shown in figure 1(b) would undergo a three-dimensional rotation if the mass centre initially deviates from the plane spanned by the symmetry axis of the spheroid and the gravitational direction (named as the symmetry-vertical plane hereinafter).However, with the focus on the terminal settling state of the spheroid, we only explore the problem with the mass centre onto the symmetry-vertical plane.This choice is justified by studying the time evolution of the three-dimensional rotation of an oblate spheroid in Appendix C).Moreover, the azimuth angle φ could be an arbitrary value in a three-dimensional space.Without the loss of generality, we consider the settling motion of the spheroid in the x-y plane by setting φ = 0.Under these conditions, the orientation of the spheroid is solely described by the pitch angle θ.By applying zero fluid velocity u f ≡ 0 into (3.4)-(3.9), the governing equations of particle settling motion can be simplified as Here, F st,x and F st,y are the components of the Stokesian drag, e 0x and e 0y are the components of the unit vector e 0 = R CG / R CG , ω denotes the angular velocity of the spheroid around z-axis, and r I = I Gz /ρ p V p is the radius of revolution, where I Gz is the moment of inertia around the z axis.Additionally, the time evolution of the pitch angle θ is subject to Moreover, (3.10) can be rewritten as In summary, (3.15)-(3.20)altogether govern the two-dimensional settling motion of a spheroid with an offset mass centre in a quiescent viscous fluid.

Normalization
To normalize (3.15)-(3.20),we choose D eq as the characteristic length scale, U = (α − 1)gD eq as the characteristic velocity scale and T = D eq /U = D eq /[(α − 1)g] as the characteristic time scale.Here, α = ρ p /ρ f represents the density ratio between the spheroid and fluid.However, since the mass centre deviates from the geometric centre along the major axis of the spheroid, we use the semi-major axis length a, instead of D eq , to normalize the mass centre offset, yielding d = d/a.Hereinafter, we utilize the value of d to measure the extent of deviation between the mass centre and geometric centre of the spheroidal particle.
Finally, we can derive the normalized form of the governing equations (3.15)-(3.20)as follows: This parameter, which is called the Galileo number, measures the ratio of buoyancy to viscous force acting on the particle.With this definition, the normalized characteristic settling velocities v 1 and v 3 defined by (3.13) are formulated as At the end of this section, we emphasize that the Galileo number should be constrained to satisfy the low-Reynolds-number limit.Further details regarding this assumption are given in Appendix D.

Dynamic collision kernel and the Monte Carlo simulation
In a multi-particle system the collision rate of dispersed particles is quantified by the collision kernel defined by Wang et al. (1998 Here, ṄC represents the number of collisions that occur per unit time and per unit volume, and n denotes the particle number concentration (the number of particles per unit volume).
The collision kernel defined in (3.29) is referred to as the dynamic collision kernel (denoted by the superscript 'D').One needs to detect and count collision events in the multi-particle system to obtain Γ D (Wang et al. 2005).
In the present work we employ the Monte Carlo simulation to calculate the dynamic collision kernel of dispersed particles.Specifically, we randomly seed N p particles within a triple-periodic computational domain Ω.The position of each particle is tracked by numerically solving the following equation with a time step Δt: Here, x i denotes the centroid position of the ith particle, and v i represents the velocity of the ith particle (which is equal to the terminal velocity v t as provided in (3.11) for settling spheroidal particles).At each time step, we detect the contact status for all particle pairs in the system (by employing the contact detection method proposed by Choi et al. (2009) for spheroidal particles).One 'collision event' is identified if a pair of particles are not in contact at the previous time step but get in touch at the current time step.Finally, when the simulation ends at time t = T, the dynamic collision kernel can be directly computed according to (3.29) as follows: Here, N C (T) represents the total number of collision events counted in the simulation from t = 0 to t = T, and V Ω is the total volume of the computational domain.
In Appendix E we validate the present Monte Carlo simulation method to determine the dynamic collision kernel.

Kinematic collision kernel
Alternatively, the collision kernel can also be described in a kinematic manner as the average inward flux of particles across a collision sphere per unit time (Saffman & Turner 1956;Wang et al. 2000).As for the particles with a uniform spatial distribution, the kinematic collision kernel is expressed by Wang et al. (2000) Here, the superscript 'K' denotes the kinematic collision kernel, R is the radius of the collision sphere and |W r (R)| is the mean relative radial velocity (RRV) of particles with a centre-to-centre distance R. The angle bracket • denotes the ensemble average over all samples.For spherical particles, the collision radius R is equal to the particle diameter, and the kinematic collision kernel Γ K is theoretically equivalent to the dynamic collision kernel Γ D (Wang et al. 2005).However, regarding spheroidal particles, deriving the accurate expression of the kinematic collision kernel is theoretically challenging because of the complexity of the particle geometry.As an alternative, Siewert et al. (2014) suggested to use the equivalent diameter D eq as the collision radius R, by which Γ K defined in (3.32) is regarded as an 'approximate kinematic collision kernel' for spheroidal particles.Hence, according to (3.32), the key point for determining the kinematic collision kernel is reduced to the calculation of RRV.Moreover, we emphasize that a correction of the kinematic collision kernel should be taken into account by multiplying (3.32) with a radial distribution function if the particles are not uniformly distributed, for example, in the case of the spatial accumulation of inertial particles in turbulent flows (Sundaram & Collins 1997;Wang et al. 2000).

Results: settling of a spheroid with an offset mass centre
In this section we investigate the two-dimensional settling motion of a spheroid with an offset mass centre.Specifically, we first derive and analyse the stability of possible terminal settling modes of the spheroid in § 4.1.Then, we study the bifurcation characteristics of the settling mode with the change of involved parameters in § 4.2.Finally, we further discuss the horizontal drift in § 4.3.

Terminal settling modes
Let the time derivatives on the right-hand sides of (3.21)-(3.24)be zero, we can obtain the settling motion of a spheroid in the terminal state, in which the hydrodynamic force, gravitational force and buoyant force are in balance.As a result, there are four equilibrium pitch angles for a settling prolate particle (λ > 1), i.e. and, for a settling oblate particle (λ < 1), As depicted in figure 3, the terminal settling motion with θ = θ 1 or θ 2 corresponds to a narrow-side-on alignment that the major axis of the spheroid aligns with the direction of gravity.In these two cases, both the fluid-inertia torque and the gravitational torque vanish.Specifically, when θ = θ 1 , the mass centre G is positioned above the geometric centre C, resulting in a 'top-heavy settling mode'.While, when θ = θ 2 , the mass centre G lies below the geometric centre C, leading to a 'bottom-heavy settling mode'.However, the other two equilibrium pitch angles, i.e. θ 3 and θ 4 , correspond to an 'oblique settling mode'.In this scenario, the balance between the gravitational torque and the fluid-inertia torque results in a finite pitch angle of the settling spheroid.Note that, due to the symmetry of the problem, the settling motions with θ = θ 3 or θ 4 are physically equivalent.The preference for θ 3 or θ 4 as the terminal orientation for a settling spheroid is determined by the initial condition.Hence, for the sake of simplicity, unless stated otherwise, we only focus on the oblique settling mode with θ 3 in the following discussions.
With the pitch angle of the spheroid obtained, we can easily derive the terminal velocity of the settling spheroid according to (3.14) as Here, the subscript i = 1, 2, 3 corresponds to the aforementioned 'top-heavy', 'bottom-heavy' and 'oblique' settling modes, respectively.Since the spheroid does not rotate in the equilibrium state (ω = 0), the velocities of the geometric centre and mass centre are identical, and are both equal to the terminal velocity (i.e. Then, we define the settling velocity (v sett ) of the spheroid as the component of the terminal velocity along the gravitational direction, and the horizontal drift velocity (v drift ) as the velocity component perpendicular to the gravitational direction.i.e.
We can infer from (4.4) and (4.5) that with the change of the pitch angle θ, v sett varies between v 1 and v 3 , while v drift ranges from 0 to |v 1 − v 3 |/2.Furthermore, we define a drift angle ψ to quantify the capability of a settling spheroid to drift horizontally: Obviously, when the spheroid aligns with narrow-side-on or broad-side-on, it settles vertically with a zero horizontal drift (i.e.v drift = 0 and ψ = 0).

Critical mass centre offset
According to (4.1) and (4.2), the oblique settling mode is conditionally present with the following condition: By defining the three factors f λ = X A Y A /h λ , f α = α/(α − 1) and f Ga = 1/Ga 2 , (4.7) can be equivalently expressed as: Therefore, the oblique settling mode exists only when the particle mass centre offset d is not greater than a critical threshold value dcr , which is a function of the aspect ratio, density ratio and Galileo number of the spheroid.Figure 4 plots the value of f λ with the variation of λ.It is observed that | f λ | decreases as the particle asphericity increases, regardless of whether the particle is prolate or oblate in shape.Meanwhile, according to the expressions of f α and f Ga , these two factors decrease monotonically with the increase of α or Ga.Hence, we can infer from (4.8) that the critical mass centre offset dcr is greater for a spheroid with a higher density ratio α, a higher Galileo number Ga or deviating further from a sphere in shape.

The stability of terminal settling modes
In this section we examine the stability of the 'top-heavy', 'bottom-heavy' and 'oblique' settling modes by performing linear stability analysis.To do so, we first calculate the Jacobian matrix (denoted by J) of the dynamic system subject to the governing equations (3.21)-(3.26): (4.9) Here x = [v Gx , v Gy , ω, θ] T represents the vector of variables and F = F (x) is the vector composed of the left-hand terms of (3.21)-(3.24).Next, we calculate the eigenvalues of the Jacobian matrix evaluated at x = xi .Here, xi (i = 1, 2, 3) denotes the variable vector corresponding to the ith terminal settling mode mentioned above.Finally, the stability of the ith settling mode is determined by the maximum eigenvalue of J( xi ), denoted by eig i max .The ith settling mode is stable if eig i max is negative.There are four involved parameters ( d, λ, α, Ga) in the governing equations (3.21)-(3.26).Thus, these parameters determine the dynamics of the settling spheroid.To begin with, we keep the density ratio and Galileo number fixed at α = 3 and Ga = 4, and analyse the stability of different settling modes by varying the aspect ratio and mass centre offset.The results of linear stability analysis are presented in figure 5. First, the maximum eigenvalue of the top-heavy settling mode is always positive, regardless of the aspect ratio or mass centre offset.This indicates that the top-heavy settling mode is unconditionally unstable.Second, the bottom-heavy settling mode is conditionally stable only if d is greater than dcr .Third, the oblique settling mode is always stable as long as it exists when d < dcr .
Furthermore, we illustrate the pitch angle and drift angle of the spheroid in the steady settling mode (denoted by the subscript 's') in figure 6.First, when the mass centre coincides with the geometric centre (i.e.d = 0), the steady pitch angle is θ s = 90 • for a prolate particle or θ s = 0 • for an oblate particle, which is actually the value of θ 3 with d = 0.In fact, this is a special case of the oblique settling mode, i.e. a broad-side-on alignment of the settling spheroid with a zero horizontal drift (ψ s = 0).This stable alignment is the result of the fluid-inertia torque acting on the settling spheroid with a symmetric mass distribution (Dabade et al. 2015).Second, when d is greater than dcr , the bottom-heavy settling mode becomes stable and the spheroid settles with a narrow-side-on alignment, which also results in a zero horizontal drift.Third, when the mass centre offset is set between 0 and d cr , the spheroid settles in an oblique alignment.As indicated by the arrow in figure 6(a,c), the steady pitch angle (θ s ) progressively increases from 90 • to 180 • for a prolate particle (or from 0 • to 90 • for an oblate particle) as d increases from 0 to dcr , corresponding to a transition of particle orientation from the broad-side-on to the narrow-side-on alignment.Throughout this transition, the settling velocity increases monotonously according to (4.4).However, the drift angle ψ s exhibits a non-monotonous variation with a local maximum for an intermediate oblique orientation.As depicted in figure 6(b,d), the maximum value of the drift angle increases as the particle asphericity grows.More detailed discussions regarding the maximum drift angle are provided in § 4.3.
Next, we move on to examining the effect of density ratio and Galileo number on the stability of different settling modes.To do so, we vary the values of α and Ga and fix the aspect ratio λ and the mass centre offset d.As shown in figure 7, the top-heavy settling mode remains unconditionally unstable; the oblique settling mode is stable as long as it exists when d < dcr ; and the bottom-heavy settling mode becomes stable when d is greater than dcr .We note that the stability of each settling mode exhibited here is qualitatively the same as what is shown in figure 5 with varying λ and d and fixed α and Ga.
Moreover, similar to figure 6, we illustrate the steady pitch angle and drift angle of the settling spheroid with varying α and Ga but fixed d and λ in figure 8. Here, the transition from the oblique settling mode to the bottom-heavy settling mode as α or Ga decreases is ascribed to the decrease of dcr (as indicated by the arrow in figure 8a,c).Throughout this transition, the drift angle ψ s also exhibits a non-monotonous variation (figure 8b,d), similar to the results shown in figure 6(b,e).

Pitchfork bifurcation of particle settling motion
In the previous section we demonstrated the terminal settling motion of a spheroid shifts from the oblique mode to the bottom-heavy mode as d increases from less than dcr to greater than dcr .Here, we discuss the bifurcation characteristic through this transition.In figure 9 we present bifurcation diagrams of the steady settling mode of the spheroid with the variation of relevant parameters (i.e.Ga, α, λ and d).There are two different sections of the steady pitch angle in each panel.On the one hand, the dual-branch structure of θ s corresponds to the bi-steady oblique settling mode with θ = θ 3 or θ 4 .In this scenario, the preference of θ 3 or θ 4 as the terminal pitch angle for the settling spheroid is determined by the initial releasing condition.On the other hand, the single-branch structure of θ s corresponds to the bottom-heavy settling mode.According to figure 9, the transition from the bottom-heavy settling mode to the oblique settling mode exhibits a pitchfork bifurcation pattern, which is the same as the bifurcation behaviour of a settling rod with mass eccentricity in the experiments of Roy et al. (2019).In principle, this pitchfork bifurcation can be induced in two ways: by changing d with a certain dcr (figure 9d,h), or by varying dcr through tuning the involved parameters (Ga, α or λ) with a fixed d (figures 9a-c and 9e-g).
Last but not least, we can infer from figure 9(d,h) that the spheroid is able to favour an oblique pitch angle between the broad-side-on to narrow-side-on alignment by the adjustment of d.This finding enlightens us on the possibility of manipulating the settling motion of spheroidal particles by adjusting their mass centre position.

Horizontal drift
In this section we further explore the horizontal drift of the settling spheroid.According to the formulation of the drift angle ψ (4.6), we can derive the maximum drift angle ψ max over all pitch angle as  Here, κ = X A /Y A is a shape-dependent parameter.Recalling the characteristic settling velocities v 1 and v 3 as defined in (3.13), we find that κ can be physically interpreted as the ratio between v 1 and v 3 : Accordingly, κ is referred to as the velocity ratio that measures the range of variation of the settling velocity (v sett ) of a spheroid.As shown in figure 10(a), with the increase of λ, the velocity ratio decreases monotonously from a value greater than one (λ < 1) to less than unity (λ > 1).This finding indicates that the range of variation in settling velocity increases as the particle shape deviates further from a sphere.For an infinitely thin disk (λ → 0) or an infinitely elongated rod (λ → ∞), the values of the velocity ratio κ are lim λ→0 κ = 1.5, (4.12) lim λ→∞ κ = 0.5.(4.13) Regarding the maximum drift angle ψ max , it is a function of κ according to (4.10).Thus, ψ max is also solely determined by the aspect ratio.As shown in figure 10(b), ψ max increases as the degree of particle asphericity increases.In other words, more elongated prolate particles or thinner oblate particles are capable of experiencing greater horizontal drift by adjusting their mass centre offset.Furthermore, by substituting (4.12) and (4.13) into (4.10),we can obtain the maximum drift angle for an infinitely elongated rod and an

Results: gravitational collision of settling spheroidal particles
In § 4 we have demonstrated that adjusting the mass centre position can change the terminal settling orientation of a spheroidal particle.Based on this finding, we investigate the collision kernel of settling spheroidal particles with different orientations in this section, to study how mass eccentricity influences the gravitational collision rate.In the following, we consider two different orientation distributions of dispersed particles: a completely random orientation and a partially random orientation with a fixed pitch angle.To examine the gravitational collision rate, we will first derive the approximate kinematic collision kernel, and then conduct Monte Carlo simulations to compute the dynamic collision kernel in these two scenarios.

Approximate kinematic collision kernel
According to the theory introduced in § 3.2.2, the primary focus should be fixed on the calculation of RRV to obtain the kinematic collision kernel of dispersed particles.

Random orientation
The problem of geometric collision of settling spheroidal particles with random orientations was proposed by Siewert et al. (2014).Without the consideration of mass eccentricity and fluid-inertia torque, settling spheroidal particles do not experience any change in their orientation after being released.Consequently, the orientation distribution of dispersed particles is assumed to be completely random.Under this assumption, the mean RRV ( |W r | ) can be derived as follows (Siewert et al. 2014): (5.1) Here, x 1 and x 2 represent the positions of two particles with a centre-to-centre distance of the collision radius R 12 .The six-fold integral in (5.1) represents the average over all possible orientations of particles and all relative directions of pairwise particles.Moreover, c(λ) is a dimensionless shape-dependent function defined by which is plotted in figure 11.Substituting the expression of |W r | into (3.32), and regarding D eq as the collision radius, we can obtain the approximate kinematic collision kernel as eq τ p gc(λ). (5.3) Here, the subscript 'rand' denotes the completely random distribution of particle orientations.Indicated by (5.3), the collision kernel is proportional to the shape-dependent function c(λ), which implies a vanishing Γ K rand for spherical particles since c(λ) is equal to zero at λ = 1.This makes sense as spherical particles with an equal size settle with the same velocity and have no chance to collide.In the following parts, we regard Γ K rand as a characteristic collision kernel to normalize the collision kernel in other cases.

Fixed pitch angle
As discussed in § 4, the terminal settling state of a spheroidal particle depends on its mass centre offset when the fluid-inertia torque is involved.By adjusting d, the spheroid can settle with an arbitrary pitch angle between the broad-side-on and narrow-side-on alignment.Therefore, we consider a partially random distribution of particle orientations: a random distribution of the azimuth angle φ but a fixed pitch angle with θ = θ 0 .By varying θ 0 , we can investigate how the change of mass centre offset affects the gravitational collision rate.In view of the symmetry, we restrict our discussion on the fixed pitch angle ranging from θ 0 = 0 • to θ 0 = 90 • , which encompasses all possible orientations from the broad-side-on to narrow-side-on alignment for settling spheroidal particles.In this scenario, the calculation of ( |W r | is achieved by averaging over all possible azimuth angles φ and relative directions of particle pairs as follows: (5.4) Since the pitch angle of the particle is fixed at θ 1 = θ 2 = θ 0 , the average is reduced to a four-fold integral instead of the six-fold integral in (5.1).Accordingly, the approximate kinematic collision kernel can be written as (5.5) The subscript 'fix' indicates the fixed pitch angle of dispersed particles.Same as Γ K rand , Γ K fix is also proportional to the shape-dependent function c(λ).Thus, the ratio Γ K fix /Γ K rand is independent of particle shape, but is correlated with the pitch angle by the function of | sin(2θ 0 )|, as illustrated in figure 12.The maximum value of Interestingly, as discussed in § 4.1, the horizontal drift velocity of a settling spheroidal particle is also correlated with the pitch angle by | sin(2θ)| (see (4.5)), just as Γ K fix does.The relationship between the collision kernel and the drift velocity can be interpreted as follows.According to (4.4), dispersed particles with a fixed pitch angle settle with the same vertical velocity.Thus, the geometric collision can only be caused by the difference of their horizontal drift velocities.Therefore, it is rational that the correlation of particle drift velocity with the pitch angle is the same as that of the gravitational collision kernel.Especially, as for the narrow-side-on or broad-side-on settling (θ 0 = 0 • or 90 • ), the collision kernel Γ K fix vanishes since the particles experience zero horizontal drift with these two orientations.
Table 1.Dimensionless parameters for the Monte Carlo simulation of settling spheroidal particles.For the normalization, we choose the particle equivalent diameter D eq as the characteristic length scale, τ p gc(λ) as the characteristic velocity and D eq /(τ p gc(λ)) as the characteristic time scale.Here φ represents the particle volume fraction.

Dynamic collision kernel
In the derivation of the approximate kinematic collision kernel for spheroidal particles, we introduce an assumption that the collision radius is equal to the particle equivalent diameter (Siewert et al. 2014).However, this assumption needs to be further examined.Hence, we conduct Monte Carlo simulations of settling spheroidal particles to determine the dynamic collision kernel Γ D .The configuration of the Monte Carlo simulation is provided in table 1.

Random orientation
We first consider settling spheroidal particles with random orientations.We choose eight particle shapes: oblate particles with aspect ratio λ = 0.2, 0.33, 0.5, 0.8 and prolate particles with aspect ratio λ = 1.2, 2, 3, 5. Figure 13(a) illustrates the dynamic collision kernels obtained by the Monte Carlo simulation.It can be inferred that the approximate kinematic collision kernel underestimates the dynamic collision kernel for most particle shapes (except for a slight overestimation for the case of λ = 1.2).The difference between Γ D rand and Γ K rand becomes more pronounced as the particle shape deviates further from a sphere, especially for oblate particles.This difference actually reflects the geometric complexity for the collision of spheroidal particles, which is ignored in deriving the approximate kinematic collision kernel.Nevertheless, in spite of the deviation, Γ K rand still provides a reasonable estimation of the dynamic collision kernel, as long as the particle shape does not deviate significantly from a sphere.Even in the case of the greatest discrepancy here (the case of λ = 0.2), Γ K rand is still within the same order of magnitude as Γ D rand .984 A40-22

Fixed pitch angle
Then we move on to the case of settling spheroidal particles with a fixed pitch angle.Figure 13(b) shows the comparison of the dynamic collision kernel obtained by the Monte Carlo simulation and the approximate kinematic collision kernel for spheroidal particles with different aspect ratios and different pitch angles.The difference between Γ D fix and Γ K fix is manifested in two aspects.Firstly, Γ D fix exhibits a skewed dependence on θ 0 towards the narrow-side-on alignment side (θ 0 = 0 • side for oblate particles and θ 0 = 90 • side for prolate particles), which is different from the symmetry function of Γ K fix (θ 0 ) about θ 0 = 45 • .Secondly, the normalized dynamic collision kernel (Γ D fix /Γ K rand ) is not only a function of the pitch angle but also dependent on particle aspect ratio.The discrepancy between Γ K fix and Γ D fix , which is generally manifested by an underestimation of the exact collision rate by Γ K fix , becomes more pronounced with the increase of particle asphericity.Nevertheless, in spite of these differences, we demonstrate that Γ K fix qualitatively captures the non-monotonic variation trend of the dynamic collision kernel with the change of θ 0 .
In summary, by conducting Monte Carlo simulations, we verified the results obtained in § 5.1 that the collision rate of settling spheroidal particles reaches its maximum when particles settle with an intermediate pitch angle.This finding enlightens us to manipulate the gravitational collision rate of settling spheroidal particles by adjusting the mass centre position.

Discussion: extend to turbulent flows
Although the present study is conducted by only considering the simplest quiescent fluid as the background flow, the results are relevant in the case of turbulent flows.Here, we provide a discussion on the collision of particles with mass centre offset in turbulent flows.In the previous studies on the settling particles in turbulence, Siewert et al. (2014) and Jucha et al. (2018) have demonstrated that the collision rate of non-spherical particles is enhanced compared with spherical ones, since the settling spheroidal particles with random orientations increases the RRV.This conclusion was drawn without considering the fluid-inertia torque and gravitational torque induced by mass centre offset.To analyse the collision rate of settling spheroidal particles in turbulent flows with the inclusion of these two torques, the orientation of particles has to be re-examined.
In general, there are three torques determining the orientation of particles in turbulent flows.The first is the shear-induced torque, i.e.Jeffery torque, which can be estimated by T J ∼ μa 3 |ω − Ω|.While the vorticity fluctuations in the turbulent flow randomize the orientation of dispersed particles.The second one is the fluid-inertia torque, which can be estimated by T I ∼ ρ f a 3 |u − v| 2 .Under the action of this torque, spheroidal particles tend to settle with broad-side-on.The third is the gravitational torque related to the mass centre offset, which can be estimated by T g ∼ ρ p V p gd.As discussed in the present work, this torque aligns the major axis of the settling spheroids in the gravitational direction.
In the earlier study, Anand, Ray & Subramanian (2020) explored the effect of fluid inertia on the orientation of settling spheroids in turbulence and found that the fluid-inertia torque leads to the broad-side-on alignment.Furthermore, Sheikh et al. (2020) discussed the competition between the fluid-inertia torque and Jeffery torque by defining a dimensionless parameter R = |u − v| 2 /(ν|ω − Ω|).They demonstrated that spheroidal particles tend to settle with the broad-side-on alignment when the fluid-inertia effect is dominant with R 1. While, in a strong turbulent flow where R 1, the turbulent shear effect prevails, leading to a random orientation distribution of dispersed particles.If we further introduce the effect of mass centre offset into this problem, the relative strength of T I , T J and T g should be examined.It can be predicted that if the mass centre offset is large enough to make the gravitational torque overwhelm the other two torques, the narrow-side-on alignment would be present.Moreover, if the gravitational torque is comparable to the fluid-inertia torque, and both of them are much stronger than the Jeffery torque, settling spheroidal particles would preferentially favour an oblique orientation, which is determined by the specific ratio between T I and T g as discussed in the present work.
The enhanced collision rate of spheroidal particles with random orientations reported in Siewert et al. (2014) and Jucha et al. (2018) occurs when T J plays a predominant role.However, if the fluid-inertia torque or the gravitational torque dominates, the RRV induced by settling velocity would be considerably attenuated since particles prefer the broad-side-on or narrow-side-on alignment (corresponding to the case of a fixed pitch angle θ 0 = 0 or θ 0 = π/2).While, in the scenario where T I is comparable with T g but much greater than T J , the RRV of colliding particles could be primarily predicted by the situation of a fixed pitch angle, which has been discussed in § § 5.1.2and 5.2.2.
Nevertheless, the above qualitative discussion only considers the contribution of settling-velocity-induced RRV to the collision rate of spheroidal particles in turbulent flows.However, as for settling inertial particles in turbulent flows, the collision rate would also be affected by other effects, such as the sling effect (Falkovich & Pumir 2007;Jucha et al. 2018), preferential concentration at low-vorticity regions (Sundaram & Collins 1997;Zhou, Wexler & Wang 1998;Pumir & Wilkinson 2016;Anand et al. 2020) and preferential sweeping effect to enhance settling velocity (Ghosh et al. 2005;Good et al. 2014;Anand et al. 2020).A quantitative study on the effects of fluid-inertia torque and mass centre offset on particle behaviour in turbulence is left for future work.

Conclusions and prospect for future work
In this study we have investigated the effect of mass centre offset on the settling motion and gravitational collision rate of spheroidal particles in a quiescent fluid under the low-Reynolds-number assumption.
We firstly analysed the settling motion of a single spheroid with an offset mass centre.Based on the Newton-Euler equations, we derived a critical mass centre offset that determines the terminal settling mode of the spheroid.When the mass centre coincides with the geometric centre, a spheroid settles with the broad-side-on alignment under the action of the fluid-inertia torque.With a non-zero mass centre offset below the critical threshold, a spheroid prefers an oblique settling mode, in which the fluid-inertia torque balances with the gravitational torque.The spheroid drifts horizontally in this mode, due to the misalignment of its velocity and the direction of gravity.However, when the mass centre offset exceeds the critical value, the gravitational torque is dominant, and the spheroid settles in a bottom-heavy mode with a narrow-side-on alignment and vanishing horizontal drift.Therefore, we conclude that the orientation of a settling spheroid undergoes a transition from the broad-side-on to narrow-side-on alignment as the mass centre offset increases from zero to the critical value.This transition, which is found to follow a pitchfork bifurcation pattern, can be induced either by the change of mass centre offset, or by varying the critical mass centre offset through tuning the density ratio, Galileo number or aspect ratio.Moreover, we further analysed the horizontal drift of the spheroid.The maximum drift angle is found to be a function of velocity ratio between narrow-side-on and broad-side-on settling.As the shape of the spheroid deviates further from a sphere, both the velocity ratio and the maximum drift angle increase accordingly.
In the second part of this work, we shifted to study the gravitational collision rate of settling spheroidal particles with different orientations.First, we originally derived the approximate kinematic collision kernel of settling spheroidal particles with a fixed pitch angle, following the theoretical model proposed by Siewert et al. (2014).It is found that the approximate kinematic collision correlates with the pitch angle in the same manner as the drift velocity does.Then, Monte Carlo simulations are conducted to determine the dynamic collision kernel of settling particles.It is demonstrated that the collision kernel of settling spheroidal particles varies from zero (for the broad-side-on or narrow-side-on alignment) to a maximum value (for an intermediate oblique orientation) with the change of pitch angle.Furthermore, the comparison between the kinematic and dynamic collision kernel reveal that the approximate kinematic collision kernel of spheroidal particles underestimates the collision rate in most scenarios.This discrepancy is related to the geometric complexity for colliding spheroids and becomes more significant with the increase of particle asphericity.However, despite the discrepancy, the approximate kinematic collision kernel is qualitatively correct and provides a reasonable estimation of the dynamic collision kernel for spheroidal particles, as long as the particle does not deviate significantly from a spherical shape.This finding justifies the rationality of the theory of approximate kinematic collision kernel for spheroidal particles as provided in § 3.2.2.By expressing the collision kernel in a kinematic manner, the collision rate of particles can be estimated based on the collective statistics of dispersed particles, rather than relying on complicated procedures of collision detection and counting.This is particularly helpful in establishing theoretical models for collision rates of non-spherical particles in other complex scenarios, such as turbulent particle-laden flows.
According to our analysis, the settling motion of a spheroidal particle is highly sensitive to the mass centre offset.For example, according to (4.8), as for a prolate particle with an aspect ratio λ = 3, density ratio α = 2 and Galileo number Ga = 4, the value of dcr is only 0.0734.This indicates that even a small degree of the offset between particle mass centre and its geometric centre can result in a substantial change of particle alignment from broad-side-on to narrow-side-on.Regarding the collision in a multi-particle system, it also reveals a sensitive dependency of collision rate on the mass centre offset.
These findings highlight the importance of considering mass eccentricity in practical applications involving settling non-spherical particles, even in the cases where the extent of deviation between particle mass centre and geometric centre is small.Furthermore, the present results also imply the possibility for the manipulation of the settling motion and collision rate of spheroidal particles by adjusting their mass centre position.
Finally, we discuss the potential valuable work awaiting future explorations as follows.First, with the focus on the terminal settling state of the spheroid, we restrict the mass centre on the symmetry-vertical plane in the present study.However, when the mass centre is not located on the symmetry axis of the spheroid and deviates from the symmetry-vertical plane, our preliminary exploration in Appendix C demonstrates that the spinning (rotation around the symmetry axis) and tumbling (rotation around the axis perpendicular to the symmetry axis) motions of the spheroid are coupled in the developing stage.The three-dimensional angular dynamics in this scenario may introduce more intricate bifurcation behaviour of the rotation of the spheroid.What and how the relevant factors influence the developing process for the three-dimensional rotation are unknown and remain for further investigation.Second, we propose a way to manipulate the orientation of non-spherical particles in the present work.Although we only consider the quiescent flow, this mechanism should also play a significant role in turbulent flows.As discussed in § 6.1, the coupled effect of turbulent shear, fluid-inertia torque and mass centre offset may result in an intricate behaviour of the orientations and collisions of non-spherical particles in turbulent flows, which can be explored in the future.Third, it is important to note that all the results presented in this study are obtained within the low-Reynolds-number limit with a disregard of particle-particle hydrodynamic interactions.In future work these limits can be broken by performing particle-resolved direct numerical simulations of settling spheroidal particles with an offset mass centre.Therefore, according to the parallel-axis theorem of a rigid body, the moment of inertia of the spheroid about its mass centre G can be derived as for a prolate particle and for an oblate particle.Consequently, the dimensional form of the radius of gyration r I in (3.17) is Note that in a limiting case where the hole is as large as half of the spheroid, all of the mass accumulates on half of the volume ( ŷ > 0 half for a prolate particle or x > 0 half for an oblate particle).In this limiting case, the mass centre position of the spheroid is where V p represents the whole volume of the spheroid and 1 2 V p represents the dense half-part.Therefore, the dimensionless mass centre offset d = d/a is constrained within the range of d ∈ [0, 0.375].Appendix C. Three-dimensional rotation of the oblate spheroid In this appendix we consider the three-dimensional rotation of an oblate spheroid with mass eccentricity settling in a quiescent fluid.As shown in figure 15, we define an azimuth angle χ (which is different from the azimuth angle φ defined in figure 1) as the angle between the unit vector p and the symmetry-vertical plane.
To examine the three-dimensional rotation, we need to compute the six-degree-offreedom motion of the spheroid by numerically solving the Newton-Euler equations (3.8)-(3.10).In figure 16 we provide a few examples of the solution of this problem.We consider an oblate spheroid with Ga = 3, α = 3, λ = 1/3, while the mass centre offset and the initial condition are varied in different simulations.According to the results shown in figure 16(a-d), we observe that the mass centre always drifts to the symmetry-vertical plane (corresponding to χ = 0) in the terminal state, and the spheroid orientation converges to the steady pitch angle as provided in the main text, regardless of the value of d and the initial condition.Specifically, in the cases shown in figure 16(a,b,e, f ), the narrow-side-on settling is finally reached (θ s = 90 • ), since the mass centre offset is larger than the critical threshold (i.e.d > dcr ).In contrast, the oblique mode with a finite pitch angle (θ s ≈ 47 • ) is preferred by the spheroid with d < dcr in the cases shown in figure 16(c,d,g,h).Therefore, the above results justify the two-dimensional simplification  the geometric collision kernel is analytically available (Smoluchowski 1917): Here R is the diameter of the sphere and γ is the shear rate.It is important to note that (E1) is valid for a randomly spatial distribution of particles in an infinitely large domain.However, when the linear shear flow is confined between two parallel plates with a distance l, the collision kernel should be corrected as follows (Wang et al. 1998): To conduct a Monte Carlo simulation, we randomly seed N p particles in a linear shear flow between two parallel plates, as shown in figure 18.The velocities of the top and bottom plate are u top = [ 1 2 γ L y , 0, 0] T and u bottom = [− 1 2 γ L y , 0, 0] T to generate a linear shear flow.Dispersed spherical particles motion as tracers so that the velocity of the ith particle is v i = u f @x i = [γ y i , 0, 0] T .A periodic boundary condition for the particle motion is imposed in the streamwise (x) direction.The configuration of the Monte Carlo simulation is provided in table 2. According to (E2), the theoretical collision kernel should be Γ th = 0.0647γ L y D 2 in this case.We repeat the Monte Carlo simulation six times, and compare the dynamic collision kernel obtained by the Monte Carlo simulation with the theoretical value in table 3. Here, the error of the Monte Carlo simulation is defined by As shown in table 3, the dynamic collision kernel obtained by the Monte Carlo simulation agrees well with the theoretical value, which validates the present numerical method of the Monte Carlo simulation.The deviation between Γ D and Γ th is ascribed to the statistical error in the Monte Carlo simulation, which may be due to the limited size of the computational domain and the limited simulation time for obtaining statistics.

Figure 1 .
Figure 1.Schematic of (a) a prolate particle and (b) an oblate particle with an offset mass centre.The mass centre of the spheroid is denoted by G and the geometric centre of the spheroid is dented by C. The orientation of the spheroid is described by the unit vector n along the symmetric axis, which determines the pitch angle θ and the azimuth angle φ.Here Cxŷẑ represents the body-fixed frame of the spheroid.
.26) Here, the superscript '*' represents the dimensionless variables normalized by the characteristic scales mentioned above (except for the dimensionless mass centre offset d), and the dot symbol in (3.23) denotes the derivative with respect to the dimensionless time t * .Moreover, the dimensionless parameter Ga presented in (3.21)-(3

Figure 3 .
Figure 3. Schematic of three typical terminal settling modes.(a,d) Top-heavy mode, (b,e) bottom-heavy mode, (c, f ) oblique mode for (a-c) a prolate particle and (d-f ) an oblate particle.

Figure 4 .
Figure 4. Variation of the shape factor f λ with the aspect ratio λ.

Figure 5 .
Figure 5. Maximum eigenvalue of the Jacobian matrix of different terminal settling modes for (a-c) a prolate particle and (d-f ) an oblate particle.The aspect ratio and mass centre offset vary, while the density ratio and Galileo number are fixed at α = 3 and Ga = 4. (a,d) Top-heavy settling mode, (b,e) bottom-heavy settling mode, (c, f ) oblique settling mode.The black solid line represents the critical mass centre offset dcr .The grey zone in panel (c, f ) represents the parameter space where d > dcr and the oblique settling mode does not exist.The spheroid in each panel depicts the schematic of each settling mode.

Figure 6 .
Figure 6.Variation of (a,d) the steady pitch angle and (b,e) the steady drift angle of the settling spheroid with the change of aspect ratio and mass centre offset.The density ratio and Galileo number are fixed at α = 3 and Ga = 4. (c, f ) The schematic diagrams of the steady pitch angle θ s and the steady drift angle ψ s .(a-c) Prolate particles, (c,d) oblate particles.The black solid line in (a,b,d,e) represents the critical mass centre offset dcr .

Figure 7 .
Figure 7. Same as figure 5 but for varying α and Ga with the mass centre offset fixed at d = 0.005 and the aspect ratio fixed at (a-c) λ = 2 (prolate particle) or (d-f ) λ = 0.5 (oblate particle).

Figure 8 .
Figure 8. Variation of (a,c) the steady pitch angle and (b,d) the steady drift angle of the settling spheroid with the change of Galileo number and density ratio.The mass centre offset is fixed at d = 0.005.(a,b) A prolate particle with λ = 2, (c,d) an oblate particle with λ = 0.5.The black line corresponds to dcr = d = 0.005.

Figure 9 .
Figure 9. Bifurcation diagrams of the steady pitch angle θ s with the variation of (a,e) Ga, (b, f ) α, (c,g) λ or (d,h) d.The other three influencing parameters are fixed as indicated in each panel.(a-d) Prolate particles, (e-h) oblate particles.

Figure 10 .
Figure 10.Dependence of (a) the velocity ratio κ and (b) the maximum drift angle ψ max on the aspect ratio of the spheroid.

Figure 11 .
Figure 11.Plot of the shape-dependent function c(λ) versus the aspect ratio λ.

Figure 12 .
Figure 12.Plot of Γ K fix normalized by Γ K rand with the variation of θ 0 .

Figure 13 .
Figure 13.Normalized dynamic collision kernel of settling spheroidal particles obtained by the Monte Carlo simulation.(a) Random orientation.(b) Fixed pitch angle.The approximate kinematic collision kernel Γ K fix Figure

Figure 15 .
Figure 15.Sketch of the three-dimensional rotation of an oblate spheroid with mass eccentricity.The unit vector along the direction from the centroid C to the mass centre G is denoted by p.The green plane represents the symmetry-vertical plane (the plane spanned by the direction along the symmetry axis (n) and the gravitational direction (e g )).

Figure 18 .
Figure 18.Schematic of the Monte Carlo simulation of spherical particles in a linear shear flow between two parallel planes.The size of the computational domain is L x , L y and L z in the streamwise, wall-normal and spanwise directions, respectively.

Table 3 .
−0.56 % −2.57% −0.34 % Results of the Monte Carlo simulation for the dynamic collision kernel of spherical particles in a linear shear flow.