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Calcium-Stabilised Transition Metal Bis(Formyl) Complexes: Structure and Bonding

22 June 2023, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Reaction of a molecular calcium hydride with a series of group 9 dicarbonyl complexes [M(C5Me5)(CO)2] (M = Co, Rh, Ir) led to the formation of both mono(formyl) and bis(formyl) complexes. The bis(formyl) complexes are unique. They have been characterised by multinuclear NMR spectroscopy and examples have been crystallographically characterised for the first time.

Keywords

Metal Formyl
Main Group
Metal Carbonyl
Carbonylation
Fischer-Tropsch

Supplementary materials

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Now Published

Calcium-stabilised transition metal bis(formyl) complexes: structure and bonding [opens in a new tab]
Joseph M. Parr, Andrew J. P. White, Mark R. Crimmin journal article
Chemical Communications , Volume 59, Issue 65
Online publication date: 2023

Version History

Jun 22, 2023 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-jg0pd
D O I: 10.26434/chemrxiv-2023-jg0pd [opens in a new tab]

Funding

Engineering and Physical Sciences Research Council
EP/S036628/1

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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