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This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.
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- Date Published: March 2009
- format: Paperback
- isbn: 9780521105668
- length: 248 pages
- dimensions: 229 x 152 x 14 mm
- weight: 0.37kg
- availability: Available
Table of Contents
1. Symmetry versus splitting parameters
2. The crystal-field formalism
3. Interelectron repulsion parameters
4. Radical parameters for angularly-distorted systems
5. Radical parametres for quadrate symmetry
6. The nature and calculation of 10Dq
7. A crystal-field approach to radical parameters
8. Semi-empirical molecular-orbital approaches
9. The Nephelauxetic effect.
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