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Artificial colouration of smectite through adsorbing dyes from wastewater to make a hybrid pigment

Published online by Cambridge University Press:  29 November 2022

Itamar A. Rodrigues  and
Fauze J. Anaissi Open the ORCID record for Fauze J. Anaissi [Opens in a new window]
Itamar A. Rodrigues
Affiliation:
Universidade Estadual do Centro-Oeste, Departamento de Química, Laboratório de Materiais e Compostos Inorgânicos, Alameda Elio Antônio Dalla Vecchia 838, 85040-167, Guarapuava, PR, Brazil
Fauze J. Anaissi*
Affiliation:
Universidade Estadual do Centro-Oeste, Departamento de Química, Laboratório de Materiais e Compostos Inorgânicos, Alameda Elio Antônio Dalla Vecchia 838, 85040-167, Guarapuava, PR, Brazil
*
*Email: anaissi@unicentro.br
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Abstract

Artificially coloured smectites (smectite pigments) were prepared via the sorption of anionic dyes on smectite saturated with ferric ions (Fe-smectite). Fe-smectite has a surface charge and is capable of decolourizing aqueous solutions containing single-component anionic dyes (Amaranth, Brilliant blue FCF and Tartrazine) or multi-component dyes (dye mixtures). Kinetic and equilibrium models were used to describe the sorption of individual dyes, whereas the decolourization of the multi-component system was studied by monitoring the reduction in the intensity of the absorption bands in the visible light region. The Langmuir–Freundlich dual-site model presented the best fit to the experimental data, and the sorption kinetics followed the pseudo-second order model. The smectite pigments were dispersed in colourless paint (10%, w/w), acting as organic–inorganic hybrid pigments. Colorimetric measurements of the powdered smectite pigments dispersed in colourless real-estate paint showed chemical compatibility without the need for solvents as dispersants. These properties allow the application of coloured smectites as pigments in a sustainable circular economy.

Keywords

anionic dyecolourless painthybrid pigmentsorptionwastewater treatment
Type
Article
Information
Clay Minerals , Volume 57 , Issue 3-4 , September 2022 , pp. 160 - 171
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Zhou Chun-Hui

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