Hostname: page-component-848d4c4894-nr4z6 Total loading time: 0 Render date: 2024-06-02T11:01:35.525Z Has data issue: false hasContentIssue false
  • English
  • Français

Nitrate adsorption characteristics of synthesized allophanes with various chemical compositions

Published online by Cambridge University Press:  19 December 2022

Fumihiko Ohashi Open the ORCID record for Fumihiko Ohashi [Opens in a new window]
Fumihiko Ohashi*
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Sakurazaka, Moriyama, Nagoya 463-8560, Japan
*
Email: f.ohashi@aist.go.jp
Get access Rights & Permissions [Opens in a new window]

Abstract

Allophane-related aluminium silicates with various chemical compositions were synthesized using a hydrothermal reaction with inorganic reagents as starting solutions. The X-ray diffraction traces of the synthesized allophanes showed broad reflections centred at 0.34 and 0.23 nm, which were attributed to the imogolite-like structure of the allophanes. Energy-dispersive X-ray measurements confirmed that the Al-rich materials were synthesized as targeted. The specific surface area of the synthesized allophanes was 313–500 m2 g–1, which is greater than that of a natural allophane (248 m2 g–1). The amount of nitrate adsorbed on the synthesized allophanes tended to increase as the Al content increased. The maximum amount of nitrate adsorbed was 2.07 mmol g–1 at pH ~2, which was comparable to that of a common anion-exchange material. A possible adsorption mechanism for nitrate at lower pH levels is the weak NO3– interaction of the positively charged surface of Al-OH2+ sites.

Keywords

allophanehydroxyl groupnitrate adsorptionpore volumespecific surface areasynthesis
Type
Short Paper
Information
Clay Minerals , Volume 57 , Issue 3-4 , September 2022 , pp. 223 - 229
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Huaming Yang

References

An, Y., Zhang, W., Liu, H., Zhong, Y., Hu, Z., Shao, Y. et al. (2021) Lignocellulose-based superabsorbent polymer gel crosslinked with magnesium aluminum silicate for highly removal of Zn (II) from aqueous solution. Polymers, 13, 4161.Google ScholarPubMed
Anda, M. & Dahlgren, R.A. (2020) Long-term response of tropical andisol properties to conversion from rainforest to agriculture. Catena, 194, 104679.CrossRefGoogle Scholar
Arai, Y., Sparks, D.L. & Davis, J.A. (2005) Arsenate adsorption mechanisms at the allophane–water interface. Environmental Science & Technology, 39, 2537–2544.CrossRefGoogle ScholarPubMed
Burt, T.P., Howden, N.J.K., Worrall, F., Whelan, M.J. & Bieroza, M. (2011) Nitrate in United Kingdom rivers: policy and its outcomes since 1970. Environmental Science & Technology, 45, 175–181.CrossRefGoogle ScholarPubMed
Cradwick, P.D.G., Farmer, V.C., Russell, J.D., Masson, C.R., Wada, K. & Yoshinaga, N. (1972) Imogolite, a hydrated aluminium silicate of tubular structure. Nature Physical Science, 240, 187–189.CrossRefGoogle Scholar
Deng, L., Du, P., Yu, W., Yuan, P., Annabi-Bergaya, F., Liu, D. & Zhou, J. (2019) Novel hierarchically porous allophane/diatomite nanocomposite for benzene adsorption. Applied Clay Science, 168, 155–163.CrossRefGoogle Scholar
Donia, A.M., Atia, A.A., Al-Amrani, W.A. & El-nahas, A.M. (2009) Effect of structural properties of acid dyes on their adsorption behaviour from aqueous solutions by amine modified silica. Journal of Hazardous Materials, 161, 1544–1550.CrossRefGoogle ScholarPubMed
Du, P., Wang, S., Yuan, P. Liu, J., Liu, D., Guo, H. et al. (2022) Structure of allophanes with varied Si/Al molar ratios and implications to their differentiation on Mars. Icarus, 382, 115057.CrossRefGoogle Scholar
Du, P., Yuan, P., Liu, D., Wang, S., Song, H. & Guo, H. (2018) Calcination-induced changes in structure, morphology, and porosity of allophane. Applied Clay Science, 158, 211–218.CrossRefGoogle Scholar
Ersahin, S. (2001) Assessment of spatial variability in nitrate leaching to reduce nitrogen fertilizers impact on water quality. Agricultural Water Management, 48, 179–189.CrossRefGoogle Scholar
García-Montano, J., Pérez-Estrada, L., Oller, I., Maldonado, M.I., Torrades, F. & Peral, J. (2008) Pilot plant scale reactive dyes degradation by solar photo-Fenton and biological processes. Journal of Photochemistry and Photobiology A: Chemistry, 195, 205–214.Google Scholar
Hansen, B., Thorling, L., Schullehner, J., Termansen, M. & Dalgaard, T. (2017) Groundwater nitrate response to sustainable nitrogen management. Scientific Reports, 7, 8566.CrossRefGoogle ScholarPubMed
Harsh, J.B., Traina, S.J., Boyle, J. & Yang, Y. (1992) Adsorption of cations on imogolite and their effect on surface charge characteristics. Clays and Clay Minerals, 40, 700–706.CrossRefGoogle Scholar
Henmi, T. (1987) The relationship of the properties and structure of allophane to its silica–alumina molar ratio. Nendo-Kagaku, 27, 32–44.Google Scholar
Henmi, T. & Wada, K. (1976) Morphology and composition of allophane. American Mineralogist, 61, 379–390.Google Scholar
Henmi, T., Tange, K., Minagawa, T. & Yoshinaga, N. (1981) Effect of SiO2/Al2O3 ratio on the thermal reactions of allophane. II. Infrared and X-ray powder diffraction data. Clays and Clay Minerals, 29, 124–128.Google Scholar
Horikawa, Y. (1975) Electrokinetic phenomena of aqueous suspensions of allophane and imogolite. Clay Science, 4, 255–263.Google Scholar
JIS K 0102 (2016) Testing methods for industrial wastewater. Pp. 162–169 in: Japanese Industrial Standards. Ministry of Economy, Trade and Industry, Tokyo, Japan.Google Scholar
Johan, E., Matsue, N. & Henmi, T. (1999) New concepts for change in charge characteristics of allophane with phosphate adsorption. Clay Science, 10, 457–468.Google Scholar
Kamimoto, Y., Okamoto, N., Hagio, T., Yong-Jun, J., Deevanhxay, P. & Ichino, R. (2019) Development of magnesium–iron layered double hydroxide and application to nitrate removal. SN Applied Sciences, 1, 1399–1405.CrossRefGoogle Scholar
Karube, J. (1982) Microstructure of allophane in disperse system by light scattering method – studies on the structure formation of volcanic ash soil. I. Transactions of the Japanese Society of Irrigation, Drainage and Reclamation Engineering, 98, 7–14.Google Scholar
Karube, J., Nakaishi, K., Sugimoto, H. & Fujihira, M. (1996) Size and shape of allophane particles in dispersed aqueous systems. Clays and Clay Minerals, 44, 485–491.CrossRefGoogle Scholar
Kloprogge, J.T., Duong, L.V., Wood, B.J. & Frost, R.L. (2006) XPS study of the major minerals in bauxite: gibbsite, bayerite and (pseudo-)boehmite. Journal of Colloid and Interface Science, 296, 572–576.CrossRefGoogle ScholarPubMed
Liu, G.D., Wu, W.L. & Zhang, J. (2005) Regional differentiation of non-point source pollution of agriculture-derived nitrate nitrogen in groundwater in northern China. Agriculture, Ecosystems and Environment, 107, 211–220.CrossRefGoogle Scholar
Mahi, O., Khaldi, K., Belardja, M.S., Belmokhtar, A. & Benyoucef, A. (2021) Development of a new hybrid adsorbent from Opuntia Ficus Indica NaOH-activated with PANI-reinforced and its potential use in Orange-G dye removal. Journal of Inorganic and Organometallic Polymers and Materials, 31, 2095–2104.CrossRefGoogle Scholar
Monson, P.A. (2012) Understanding adsorption/desorption hysteresis for fluids in mesoporous materials using simple molecular models and classical density functional theory. Microporous and Mesoporous Materials, 160, 47–66.CrossRefGoogle Scholar
Mukhamed'yarova, A.N., Gareev, B.I., Nurgaliev, D.K., Aliev, F.A. & Vakhin, A.V. (2021) A review on the role of amorphous aluminum compounds in catalysis: avenues of investigation and potential application in petrochemistry and oil refining. Processes, 9, 1811.CrossRefGoogle Scholar
Nezamzadeh-Ejhieh, A. & Shahriari, E. (2011) Heterogeneous photodecolorization of methyl green catalyzed by Fe(II)-o-phenanthroline/zeolite Y nanocluster. International Journal of Photoenergy, 2011, 518153.Google Scholar
Nishikiori, H., Kanada, N., Setiawan, R.A., Morita, K., Teshima, K. & Fujii, T. (2015) Photoelectrochemical properties of dye-dispersing allophane–titania composite electrodes. Applied Clay Science, 107, 138–144.CrossRefGoogle Scholar
Ohashi, F., Wada, S.I., Suzuki, M., Maeda, M. & Tomura, S. (2002) Synthetic allophane from high-concentration solutions: nanoengineering of the porous solid. Clay Minerals, 37, 451–456.CrossRefGoogle Scholar
Padilla, G.N., Matsue, N. & Henmi, T. (2002) Adsorption of sulfate and nitrate on nano-ball allophane. Clay Science, 11, 575–584.Google Scholar
Rasmussen, C.J., Vishnyakov, A., Thommes, M., Smarsly, B.M, Kleitz, F. & Neimark, A.V. (2010) Cavitation in metastable liquid nitrogen confined to nanoscale pores. Langmuir, 26, 10147–10157.CrossRefGoogle ScholarPubMed
Sase, H., Takahashi, M., Matsuda, K., Yamashita, N., Tsunogai, U., Nakagawa, F. et al. (2022) Nitrogen saturation of forested catchments in central Japan – progress or recovery? Soil Science and Plant Nutrition, 68, 5–14.CrossRefGoogle Scholar
Sing, K.S.W. & Williams, R.T. (2004) Physisorption hysteresis loops and the characterization of nanoporous materials. Adsorption Science & Technology, 22, 773–782.CrossRefGoogle Scholar
Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J. & Siemieniewska, T. (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure and Applied Chemistry, 57, 603–619.CrossRefGoogle Scholar
Tabayashi, Y. & Yamamuro, M. (2012) Mechanism of reactive nitrogen deposition on the nitrogen leaching. Journal of Geography, 121, 411–420.CrossRefGoogle Scholar
Tani, M., Okuten, T., Koike, M., Kuramochi, K. & Kondo, R. (2002) Nitrate adsorption in some andisols developed under different moisture conditions. Soil Science and Plant Nutrition, 50, 439–446.CrossRefGoogle Scholar
Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J. & Sing, K.S.W. (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 87, 1051–1069.CrossRefGoogle Scholar
Tietema, A., De Boer, W., Riemer, L. & Verstraten, J.M. (1992) Nitrate production in nitrogen-saturated acid forest soils: vertical distribution and characteristics. Soil Biology and Biochemistry, 24, 235–240.CrossRefGoogle Scholar
Wada, K. (1967) A structural scheme of soil allophane. American Mineralogist, 52, 690–708.Google Scholar
Wada, K. (1989) Allophane and imogolite. Pp. 1051–1087 in: Minerals in Soil Environments, Vol. 1, 2nd Edition (Dixon, J.B. & Weed, S.B., editors). Soil Science Society of America, Madison, USA.Google Scholar
Wada, K. & Yoshinaga, N. (1969) The structure of ‘imogolite’. American Mineralogist. 54, 50–71.Google Scholar
Wada, S.I., Eto, A. & Wada, K. (1979) Synthetic allophane and imogolite. European Journal of Soil Science, 30, 347–355.CrossRefGoogle Scholar
Wang, S., Du, P., Yuan, P., Liu, Y., Song, H., Zhou, J., Deng, L. & Liu, D. (2020) Structural alterations of synthetic allophane under acidic conditions: implications for understanding the acidification of allophanic Andosols. Geoderma, 376, 114561.CrossRefGoogle Scholar
Yokobe, T., Hyodo, F. & Tokuchi, N. (2020) Volcanic deposits affect soil nitrogen dynamics and fungal–bacterial dominance in temperate forests. Soil Biology and Biochemistry, 150, 108011.CrossRefGoogle Scholar