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Competitive Removal of Malachite Green and Rhodamine B Using Clinoptilolite in a Two-dye System

Published online by Cambridge University Press:  01 January 2024

Evrim Baran  and
Bilal Acemioğlu
Evrim Baran
Affiliation:
Department of Chemistry, Faculty of Science and Arts, University of Kilis 7 Aralik, Kilis 79000, Turkey
Bilal Acemioğlu*
Affiliation:
Department of Chemistry, Faculty of Science and Arts, University of Kilis 7 Aralik, Kilis 79000, Turkey
*
*E-mail address of corresponding author: acemioglu@kilis.edu.tr
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Abstract

Surface and groundwaters become contaminated with dyes due to discharge into the environment, which increases the risk of a number of human diseases. Many methods of dye removal from discharge waters at the source have been developed, but few are effective and the most effective method (activated carbon) is very expensive. The purpose of the present study was to test a natural zeolite (clinoptilolite type) as a potentially effective and inexpensive method to remediate dye discharge into the environment. In the removal experiments, malachite green (MG) and rhodamine B (RB) cationic dyes were used. The effects of various experimental conditions such as initial dye concentration, pH, and temperature on dye removal were investigated in a single-dye system. The degree of removal of MG and RB increased with increasing initial concentration and temperature of the dye in a single-dye system. An increase in pH decreased RB removal, but increased MG removal. In a two-dye system, MG and RB adsorption decreased by ~41.74 and 21.51%, respectively, due to competitive adsorption of the two dyes. Adsorption reflected a pseudo-second order kinetics model with high correlation coefficients (r2 = 0.996–1.000) in single-dye and two-dye systems. Adsorption was most consistent with the Langmuir-1 and the Redlich-Peterson isotherm models with high correlation coefficients (r2 = 0.987–0.999) in both systems. The Langmuir-1 adsorption capacities were determined as 43.86 and 44.25 mg/g for the removal of MG and RB in single-dye systems, respectively. In a two-dye system, the Langmuir-1 capacities were 20.62 and 31.54 mg/g for the removal of MG and RB, respectively.

Keywords

Adsorption SelectivityClinoptiloliteMalachite GreenRhodamine BSingle-Two-dye Systems
Type
Article
Information
Clays and Clay Minerals , Volume 64 , Issue 3 , June 2016 , pp. 299 - 313
Copyright
Copyright © Clay Minerals Society 2016

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References

Acemioğlu, B., 2004 Adsorption of Congo red from aqueous solution onto calcium-rich fly ash Journal of Colloid and Interface Science 274 371–379.CrossRefGoogle ScholarPubMed
Acemioğlu, B. Kertmen, M. Digrak, M. and Alma, M.H., 2010 Use of Aspergillus wentii for biosorption of methylene blue from aqueous solution African Journal of Biotechnology 9 874–881.Google Scholar
Al-Degs, Y. Khraisheh, M.A.M. Allen, S.J. Ahmad, M.N. and Walker, G.M., 2007 Competitive adsorption of reactive dyes from solution: Equilibrium isotherm studies in single and multisolute systems Chemical Engineering Journal 128 163–167.CrossRefGoogle Scholar
Alpat, S.K. Ozbayrak, O. Alpat, S. and Akcay, H., 2008 The adsorption kinetics and removal of cationic dye Toluidine blue O from aqueous solution with Turkish zeolite. Journal of Hazardous Materials 151 213–220.Google ScholarPubMed
Alvarez-Ayuso, E. Garcia-Sanchez, A. and Querol, X., 2003 Purification of metal electroplating waste waters using zeolites Water Research 37 4855–4862.CrossRefGoogle ScholarPubMed
Alves, M.E. and Lavorenti, A., 2004 Sulfate adsorption and its relationships with properties of representative soil of the São Paulo State, Brazil Geoderma 118 89–99.CrossRefGoogle Scholar
Anandkumar, J. and Mandal, B., 2011 Adsorption of chromium(VI) and Rhodamine B by surface modified tannery waste: Kinetic, mechanistic and thermodynamic studies Journal of Hazardous Materials 186 1088–1096.CrossRefGoogle ScholarPubMed
Armagan, B. Turan, M. and Celik, M.S., 2004 Equilibrium studies on the adsorption of reactive azo dyes into zeolite Desalination 170 33–39.CrossRefGoogle Scholar
Benkli, Y.E. Can, M.F. Turan, M. and Celik, M.S., 2005 Modification of organo-zeolite surface for the removal of reactive azo dyes in fixed-bed reactors Water Research 39 487–493.CrossRefGoogle ScholarPubMed
Bilir, M.H. Sakalar, N. Acemioğlu, B. Baran, E. and Alma, M.H., 2013 Sorption of remazol brilliant blue R onto polyurethane-type foam prepared from peanut shell Journal of Applied Polymer Science 6 4340–4351.CrossRefGoogle Scholar
Chen, C.Y. Chang, J.C. and Chen, A.H., 2011 Competitive biosorption of azo dyes from aqueous solution on the templated crosslinked-chitosan nanoparticles Journal of Hazardous Materials 185 430–441.CrossRefGoogle ScholarPubMed
Chowdhury, S. Mishra, R. Saha, P. and Kushwaha, P., 2011 Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk Desalination 265 159–168.CrossRefGoogle Scholar
Dawood, S. and Sen, T.K., 2012 Removal of anionic dye Congo red from aqueous solution by raw pine and acidtreated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design Water Research 46 1933–1946.CrossRefGoogle ScholarPubMed
Dogan, M. and Alkan, M., 2003 Adsorption kinetics of methyl violet onto perlite Chemosphere 50 517–528.CrossRefGoogle ScholarPubMed
Eftekhari, S. Habibi-Yangjeh, A. and Sohrabnezhad, S.h., 2010 Application of AlMCM-41 for competitive adsorption of methylene blue and rhodamine B: Thermodynamic and kinetic studies Journal of Hazardous Materials 178 349–355.CrossRefGoogle ScholarPubMed
Ertaş, M. Acemioğlu, B. Alma, M.H. and Usta, S., 2010 Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust Journal of Hazardous Materials 183 421–427.CrossRefGoogle ScholarPubMed
Farhadi, K. Matin, A.A. and Hashemi, P., 2010 Removal of malachite green from aqueous solutions using molecularly imprinted polymer Desalination and Water Treatment 24 20–27.CrossRefGoogle Scholar
Farmer, V.C.e., 1974 The Infrared Spectra of Minerals London Mineralogical Society.CrossRefGoogle Scholar
Freundlich, H.M.F., 1906 Über die adsorption in lösungen Zeitschrift für Physikalische Chemie 57A 385–470.Google Scholar
Gao, J.F. Zhang, Q. Su, K. and Wang, J.H., 2010 Competitive biosorption of yellow 2G and reactive brilliant red K-2G onto inactive aerobic granules: Simultaneous determination of two dyes by first-order derivative spectrophotometry and isotherm studies Bioresource Technology 101 5793–5801.CrossRefGoogle ScholarPubMed
George, J.M., 1982 Microscopic Aspects of Adhesion and Lubrication Amsterdam Elsevier Scientific Publishing Company.Google Scholar
Guo, Y. Zhao, J. Zhang, H. Yang, S. Qi, J. Wang, Z. and Xu, H., 2005 Use of rice husk-based porous carbon for adsorption of rhodamine B from aqueous solutions Dyes and Pigments 66 123–128.CrossRefGoogle Scholar
Hameed, B.H. and El-Khaiary, M.I., 2008 Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: Equilibrium isotherms and kinetic studies Journal of Hazardous Materials 154 237–244.CrossRefGoogle ScholarPubMed
Hameed, B.H. and El-Khaiary, M.I., 2008 Kinetics and equilibrium studies of malachite green adsorption on rice straw-derived char Journal of Hazardous Materials 153 701–708.CrossRefGoogle ScholarPubMed
Han, R. Wang, Y. Sun, Q. Wang, L. Song, J. He, X. and Dou, C., 2010 Malachite green adsorption onto natural zeolite and reuse by microwave irridation Journal of Hazardous Materials 175 1056–1061.CrossRefGoogle Scholar
Hernandez-Montoya, V. Perez-Cruz, M.A. Mendoza-Castillo, D.I. Moreno-Virgen, M.R. and Bonilla-Petriciolet, A., 2013 Competitive adsorption of dyes and heavy metals on zeoli tic structures Journal of Environmental Management 116 213–221.CrossRefGoogle Scholar
Hisarli, G. Tezcan, C. and Atun, G., 2012 Adsorption kinetics and equilibria of basic dyes onto zeolite in single and binary systems Chemical Engineering Communication 199 1412–1436.CrossRefGoogle Scholar
Ho, Y.S. and McKay, G., 1998 Sorption of dye from aqueous solution by peat Chemical Engineering Journal 70 115–124.CrossRefGoogle Scholar
Lagergren, S., 1898 About the theory of so-called adsorption of soluble substance Kungliga Svenska Vetenskapsakademiens. Handlingar. Band 24 1–39.Google Scholar
Langmuir, I., 1918 The adsorption of gases on plane surfaces of glass, mica and platinum Journal of American Chemical Society 40 1361–1403.CrossRefGoogle Scholar
Li, L. Liu, F. Jing, X. Ling, P. and Li, A., 2011 Displacement mechanism of binary competitive adsorption for aqueous divalent metal ions onto a novel IDA-chelating resin: Isotherm and kinetic modeling Water Research 45 1177–1188.CrossRefGoogle ScholarPubMed
Mahmoodi, N.M. Salehi, R. and Arami, M., 2011 Binary system dye removal from colored textile wastewater using activated carbon: Kinetic and isotherm studies Desalination 272 187–195.CrossRefGoogle Scholar
Maleki, R. Farhadi, K. and Nikkhahi, Y., 2012 Trace determination of malachite green in water samples using dispersive liquidliquid microextraction coupled with highperformance liquid chromatography-diode array detection International Journal of Environmental Analytical Chemistry 92 1026–1035.CrossRefGoogle Scholar
Margeta, K. Zabukovec Logar, N. Šiljeg, M. Farkaš, A., Elshorbagy, W., 2013 Natural zeolites in water treatment — how effective is their use? Water Treatment 81–112.CrossRefGoogle Scholar
Milanova, D. Chambers, R.D. Bahga, S.S. and Santiago, J.G., 2012 Effect of PVP on the electroosmotic mobility of wetetched glass microchannels Electrophoresis 33 3259–3262.CrossRefGoogle ScholarPubMed
Ming, D.W. and Dixon, J.B., 1987 Quantitative determinatıon of clinoptilolite in soils by a cation-exchange capacity method Clays and Clay Minerals 35 463–468.CrossRefGoogle Scholar
Nandi, B.K. Goswami, A. and Purkait, M.K., 2009 Adsorption characteristics of brilliant green dye on kaolin Journal of Hazardous Materials 161 387–395.CrossRefGoogle ScholarPubMed
Ofomaja, A.E. and Ho, Y.S., 2008 Effect of temperatures and pH on methyl violet biosorption by mansonia wood sawdust Bioresource Technology 99 5411–5417.CrossRefGoogle ScholarPubMed
Önal, Y. Akmil-Başar, C. Eren, D. Sarıcı-Özdemir, C. and Depci, T., 2006 Adsorption kinetics of malachite green onto activated carbon prepared from Tuncbilek lignite Journal of Hazardous Materials B128 150–157.CrossRefGoogle ScholarPubMed
Öncel, M. Güvenç, and Acemioğlu, B., 2012 Use of pirina pretreated with hydrochloric acid for the adsorption of methyl violet from aqueous solution Asian Journal of Chemistry 24 1698–1704.Google Scholar
Özdemir, A. and Kekin, C.S., 2009 Removal of a binary dye mixture of Congo red and malachite green from aqueous solutions usıng a bentonite adsorbent Clays and Clay Minerals 57 695–705.CrossRefGoogle Scholar
Özdemir, M. Bolgaz, T. Saka, C. Şahin, , 2011 Preparation and characterization of activated carbon from cotton stalks in a two-stage process Journal of Analytical and Applied Pyrolysis 92 171–175.CrossRefGoogle Scholar
Redlich, O. and Peterson, D.L., 1959 A useful adsorption isotherm Journal of Physical Chemistry 63 1024–1026.CrossRefGoogle Scholar
Samil, A. Acemioğlu, B. Gültekin, G. and Alma, M.H., 2011 Removal of remazol orange RGB from aqueous solution by peanut shell Asian Journal of Chemistry 23 3224–3230.Google Scholar
Sismanoglu, T. Kismir, Y. and Karakus, S., 2010 Single and binary adsorption of reactive dyes from aqueous solutions onto clinoptilolite Journal of Hazardous Materials 184 164–169.CrossRefGoogle ScholarPubMed
Sprynskyy, M. Buszewski, B. Terzyk, A.P. and Namiesnik, J., 2006 Study of the selection mechanism of heavy metal (Pb2+, Cu2+, Ni2+, and Cd2+) adsorption on clinoptilolite Journal of Colloid and Interface Science 304 21–28.CrossRefGoogle ScholarPubMed
Tarlan-Yel, E. and Önen, V., 2010 Performance of natural zeolite and sepiolite in the removal of free cyanide and copper-complexed cyanide ([Cu(CN)3]2-) Clays and Clay Minerals 58 110–119.CrossRefGoogle Scholar
Temkin, M.J. and Pyzhev, V., 1940 Kinetics of ammonia synthesis on promoted iron catalysts Acta Physiochim URSS 12 327–356.Google Scholar
Tomić, S. Rajić, N. Hrenović, J. and Povrenović, D., 2012 Removal of Mg from spring water using natural clinoptilolite Clay Minerals 47 81–92.CrossRefGoogle Scholar
Uğurlu, M., 2009 Adsorption of a textile dye onto activated sepiolite Microporous and Mesoporous Materials 119 276–283.CrossRefGoogle Scholar
Uğurlu, M. Gürses, A. and Açıkyıldız, M., 2008 Comparison of textile dyeing effluent adsorption on commercial activated carbon and activated carbon prepared from olive stone by ZnCl2 activation Microporous and Mesoporous Materials 111 228–235.CrossRefGoogle Scholar
Vala, R.M.K. and Tichagwa, L., 2013 Enhancement of the adsorption of phenol red from wastewater onto clinoptilolite by modificatıon wıth n-terminated siloxanes Clays and Clay Minerals 61 532–540.CrossRefGoogle Scholar
Wang, S. and Ariyanto, E., 2007 Competitive adsorption of malachite green and Pb2+ ions on natural zeolite Journal of Colloid and Interface Science 314 25–31.CrossRefGoogle ScholarPubMed
Wang, S. and Peng, Y., 2010 Natural zeolites as effective adsorbents in water and wastewater treatment Chemical Engineering Journal 156 11–24.CrossRefGoogle Scholar
Wang, S. Ng, C.W. Wang, W. Li, Q. and Hao, Z., 2012 Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes Chemical Engineering Journal 197 34–40.CrossRefGoogle Scholar
Wang, S.B. and Zhu, Z.H., 2006 Characterisation and environmental application of an Australian natural zeolite for basic dye removal from aqueous solution Journal of Hazardous Materials B136 946–952.CrossRefGoogle ScholarPubMed
Weber, W.J. and Morris, J.C., 1963 Kinetics of adsorption on carbon from solution Journal of Sanitary Engineering Division ASCE 89(SA2), 31–39.CrossRefGoogle Scholar
Won, S.W. Han, M.H. and Yun, Y.S., 2008 Different binding mechanism in biosorption of reactive dyes according to their reactivity Water Research 42 4847–4855.CrossRefGoogle ScholarPubMed
Yang, Y. Jin, D. Wang, G. Wang, S. Xiaoming Jia, J. and Zhao, Y., 2011 Competitive biosorption of acid blue 25 and acid red 337 onto unmodified and CDAB-modified biomass of Aspergillus oryzae Bioresource Technology 102 7429–7436.CrossRefGoogle ScholarPubMed
Yazici, M. Acemioğlu, B. Akbas, M. and Kuvet, M., 2016 Determination of the ground and excited-state dipole moments of 4’-(Hexyloxy)-4-biphenylcarbonitrile and 4- Isothiocyanatophenyl 4-Pentylbicyclo [2,2,2]octane-1-carboxylate nematic liquid crystals and their mixtures Liquid Crystal 45 678–890.Google Scholar
Zhang, R. Hummelgård, M. Lv, G. and Olin, H., 2011 Real time monitoring of the drug release of rhodamine B on graphene oxide Carbon 49 1126–1132.CrossRefGoogle Scholar
Zou, Y. Zhang, Z. Shao, X. Chen, Y. Wu, X. Yang, L. Zhu, J. and Zhang, D., 2014 Application of three-phase hollow fiber LPME using an ionic liquid as supported phase for preconcentration of malachite green from water samples with HPLC detection Bulletin of the Korean Chemical Society 35 371–376.CrossRefGoogle Scholar