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Design Approaches, Functionalization, and Environmental and Analytical Applications of Magnetic Halloysite Nanotubes: A Review

Published online by Cambridge University Press:  01 January 2024

Meriem Fizir Open the ORCID record for Meriem Fizir [Opens in a new window] ,
Wei Liu ,
Xue Tang ,
Fangqi Wang  and
Yassmine Benmokadem
Meriem Fizir*
Affiliation:
Laboratoire de Valorisation Des Substances Naturelles, Université Djilali Bounaâma, Khemis Miliana, Algérie Department of Chemistry, China Pharmaceutical University, Nanjing 211198, China
Wei Liu
Affiliation:
Nanjing Institute for Comprehensive Utilization of Wild Plants, Nanjing, China
Xue Tang
Affiliation:
Department of Chemistry, China Pharmaceutical University, Nanjing 211198, China
Fangqi Wang
Affiliation:
Department of Chemistry, China Pharmaceutical University, Nanjing 211198, China
Yassmine Benmokadem
Affiliation:
Laboratoire de Valorisation Des Substances Naturelles, Université Djilali Bounaâma, Khemis Miliana, Algérie
*
e-mail: meriem.fizir@univ-dbkm.dz; meriem_fizir@163.com
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Abstract

Researchers have long been committed to developing alternative, low-cost nanomaterials that have comparable capacity to carbon nanotubes. Halloysite nanotubes (HNTs) are naturally hollow, multi-walled, tubular structures that have high porosity, enlarged volumes and surface areas, and hydroxyl groups ready for modification. In addition, HNTs are non-toxic, biocompatible, inexpensive, abundant in nature, and easy to obtain. Magnetic nanocomposites have aroused widespread attention for their diverse potential applications in analytical fields and so magnetic halloysite nanotubes (MHNTs) have emerged as outstanding magnetic nano-adsorbent materials. Owing to their superparamagnetism, selective adsorption ability, and easy separation and surface modification, these captivating nanomaterials excel at extracting and enriching various analytes from environmental, biological, and food samples. The current review article gives an insight into recent advances in the design, functionalization, characterization, and application of MHNTs as magnetic, solid-phase extraction sorbents for separation of antibiotics, pesticides, proteins, carcinogens such as polycyclic aromatic hydrocarbons (PAHs), dyes, radioactive ions, and heavy-metal ions in complex matrices.

Keywords

Environmental applicationsFunctionalizationHalloysite nanotubesMagnetic nanocompositesMagnetic solid-phase extractionSynthesis
Type
Review
Information
Clays and Clay Minerals , Volume 70 , Issue 5 , October 2022 , pp. 660 - 694
Copyright
Copyright © The Author(s), under exclusive licence to The Clay Minerals Society 2022

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Footnotes

Associate Editor: Lynda B. Williams

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