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Examining Structural and Related Spectral Change in Mars-relevant Phyllosilicates After Experimental Impacts Between 10–40 GPa

Published online by Cambridge University Press:  01 January 2024

Lonia R. Friedlander ,
Timothy D. Glotch ,
Brian L. Phillips ,
John S. Vaughn  and
Joseph R. Michalski
Lonia R. Friedlander*
Affiliation:
Geosciences Department, 255 Earth and Space Sciences (ESS) Building, Stony Brook University, Stony Brook, NY, 11794-2100 USA
Timothy D. Glotch
Affiliation:
Geosciences Department, 255 Earth and Space Sciences (ESS) Building, Stony Brook University, Stony Brook, NY, 11794-2100 USA
Brian L. Phillips
Affiliation:
Geosciences Department, 255 Earth and Space Sciences (ESS) Building, Stony Brook University, Stony Brook, NY, 11794-2100 USA
John S. Vaughn
Affiliation:
Geosciences Department, 255 Earth and Space Sciences (ESS) Building, Stony Brook University, Stony Brook, NY, 11794-2100 USA
Joseph R. Michalski
Affiliation:
Planetary Science Institute, 1700 E. Fort Lowell, Tucson, AZ, 85719 USA
*
*E-mail address of corresponding author: loniarf@gmail.com
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Abstract

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Accurate clay mineral identification is key to understanding past aqueous activity on Mars, but martian phyllosilicates are old (>3.5 Ga) and have been heavily bombarded by meteoroid impacts. Meteoroid impacts can alter clay mineral structures and spectral signatures, making accurate remote sensing identifications challenging. This paper uses nuclear magnetic resonance (NMR) spectroscopy to examine the short-range structural deformation induced in clay mineral samples of known composition by artificial impacts and calcination. Structural changes are then related to changes in the visible-near infrared (VNIR) and mid-infrared (MIR) spectra of these clay mineral samples. The susceptibility of phyllosilicates to structural deformation after experimental impacts varies by structure. Experimental results showed that trioctahedral, Mg(II)-rich saponite was structurally resilient up to peak pressures of 39.8 GPa and its unchanged post-impact spectra reflected this. Experimental data on kaolinite showed that this Al(III)-rich, dioctahedral phyllosilicate was susceptible to structural alteration at peak pressures ⩾ 25.1 GPa. This result is similar to previously reported experimental results on the Fe(III)-rich dioctahedral smectite nontronite, suggesting that dioctahedral phyllosilicates may be more susceptible to shock-induced structural deformation than trioctahedral phyllosilicates. The octahedral vacancies present in dioctahedral phyllosilicates may drive this increased susceptibility to deformation relative to trioctahedral phyllosilicates with fully occupied octahedral sheets. Thermal alteration accompanies shock in meteoroid impacts, but shock differs from thermal alteration. NMR spectroscopy showed that structural deformation in thermally altered phyllosilicates differs from that found in shocked phyllosilicates. Similar to shock, dioctahedral phyllosilicates are also more susceptible to thermal alteration. This differential susceptibility to impact-alteration may help explain generic smectite identifications from heavily bombarded terrains on Mars.

Keywords

Dioctahedral PhyllosilicatesMartian Remote SensingMeteoroid ImpactsStructural DeformationTrioctahedral Phyllosilicates
Type
Article
Information
Clays and Clay Minerals , Volume 64 , Issue 3 , June 2016 , pp. 189 - 209
Copyright
Copyright © Clay Minerals Society 2016

References

Abramov, O. and Kring, D.A., 2005 Impact-induced hydrothermal activity on early Mars Journal of Geophysical Research 110 E12S09.CrossRefGoogle Scholar
Adams, J.B. Hörz, F. and Gibbons, R.V., 1979.Effects of shock-loading on the reflectance spectra of plagioclase, pyroxene, and glass Tenth Lunar and Planetary Science Conference, Lunar and Planetary Institute Contribution 1576, Abstract #1001Google Scholar
Ames, L.L. and Sand, L.B., 1958 Factors effecting maximum hydrothermal stability in montmorillonites American Mineralogist 43 641–648.Google Scholar
Archer, P.D.J. Franz, H.B. Sutter, B. Arevalo, R.D.J. Coll, P. Eigenbrode, J.L. Glavin, D.P. Jones, J.J. Leshin, L.A. Mahaffy, P.R. McAdam, A.C. McKay, C.P. Ming, D.W. Morris, R.V. Navarro-González, R. Niles, P.B. Pavlov, A. Squyres, S.W. Stern, J.C. Steele, A. and Wray, J.J., 2014 Abundances and implications of volatile-bearing species from evolved gas analysis of the Rocknest aeolian deposit, Gale Crater, Mars Journal of Geophysical Research: Planets 119 237–254.CrossRefGoogle Scholar
Arvidson, R. E. Squyres, S. W. Bell, J. F. Catalano, J. G. Clark, B. C. Crumpler, L. S. de Souza, P. A. Fairen, A. G. Farrand, W. H. Fox, V. K. Gellert, R. Ghosh, A. Golombek, M. P. Grotzinger, J. P. Guinness, E. A. Herkenhoff, K. E. Jolliff, B. L. Knoll, A. H. Li, R. McLennan, S. M. Ming, D. W. Mittlefehldt, D. W. Moore, J. M. Morris, R. V. Murchie, S. L. Parker, T. J. Paulsen, G. Rice, J. W. Ruff, S. W. Smith, M. D. and Wolff, M. J., 2014 Ancient Aqueous Environments at Endeavour Crater, Mars Science 343 6169 1248097–1248097.CrossRefGoogle ScholarPubMed
Bibring, J. Langevin, Y. Gendrin, A. Gondet, B. Poulet, F. Berthé, M. Soufflot, A. Arvidson, R. Mangold, N. Mustard, J. Drossart, P. OMEGA Team, 2005 Mars surface diversity as revealed by the OMEGA/Mars Express observations Science 307 1576–1581.CrossRefGoogle ScholarPubMed
Bibring, J. Langevin, Y. Mustard, J. Poulet, F. Arvidson, R. Gendrin, A. Gondet, B. Mangold, N. Pinet, P. Forget, F. OMEGA Team, 2006 Global mineralogical and aqueous Mars history derived from OMEGA/Mars Express data Science 312 400–404.CrossRefGoogle ScholarPubMed
Bischoff, A. and Stöffler, D., 1992 Shock metamorphism as a fundamental process in the evolution of planetary bodies: Information from meteorites European Journal of Mineralogy 4 707–755.CrossRefGoogle Scholar
Bishop, J.L. Pieters, C.M. and Edwards, J.O., 1994 Infrared spectroscopic analyses on the nature of water in montmorillonite Clays and Clay Minerals 42 702–716.CrossRefGoogle Scholar
Bishop, J. Murad, E. and Dyar, M.D., 2002 The influence of octahedral and tetrahedral cation substitution on the structure of smectites and serpentines as observed through infrared spectroscopy Clay Minerals 37 617–628.CrossRefGoogle Scholar
Bishop, J. Madejová, J. Komadel, P. and Fröschl, H., 2002 The influence of structural Fe, Al and Mg on the infrared OH bands in spectra of dioctahedral smectites Clay Minerals 37 607–616.CrossRefGoogle Scholar
Bishop, J.L. Noe Dobrea, E.Z. McKeown, N.K. Parente, M. Ehlmann, B.L. Michalski, J.R. Milliken, R.E. Poulet, F. Swayze, G.A. Mustard, J.F. Murchie, S.L. and Bibring, J.-P., 2008 Phyllosilicate diversity and past aqueous activity revealed at Mawrth Vallis, Mars Science 321 830–833.CrossRefGoogle ScholarPubMed
Bishop, J. Lane, M. Dyar, M. and Brown, A., 2008 Reflectance and emission spectroscopy study of four groups of phyllosilicates: smectites, kaolinite-serpentines, chlorites and micas Clay Minerals 43 35–54.CrossRefGoogle Scholar
Bogard, D.D. and Hirsch, W.C., 1980 40Ar/39Ar dating, Ar diffusion properties, and cooling rate determinations of severely shocked chondrites Geochimica et Cosmochimica Acta 44 1667–1682.CrossRefGoogle Scholar
Boslough, M.B. Weldon, R.J. Ahrens, T.J., Merrill, R.B., 1980 Impactinduced water loss from serpentine, nontronite and kernite Proceedings of the Eleventh Lunar and Planetary Science Conference, Houston, Texas, USA, March 17–21, 1980 New York, New York Pergamon Press, Inc. 2145–2158.Google Scholar
Boslough, M. Venturini, E. Morosin, B. Graham, R. and Williamson, D., 1986 Physical properties of shocked and thermally altered nontronite: Implications for the Martian surface Journal of Geophysical Research 91 E207–E214.CrossRefGoogle Scholar
Boslough, M.B. Cygan, R.T. and Izett, G.A., 1995.NMR spectroscopy of quartz from the K/T Boundary: Shockinduced peak broadening, dense glass, and coesite Twenty-sixth Lunar and Planetary Science Conference, Lunar and Planetary Institute Contribution 1592, Abstract #1075Google Scholar
Brearley, A.J., 2000.Hydrous phases in ALH84001: Further evidence for preterrestrial alteration and a shock-induced thermal overprint Thirty-first Lunar and Planetary Science Conference, Lunar and Planetary Institute Contribution 1000, Abstract #1203Google Scholar
Carroll, D.L. Kemp, T.F. Bastow, T.J. and Smith, M.E., 2005 Solid-state NMR characterisation of the thermal transformation of a Hungarian white illite Solid State Nuclear Magnetic Resonance 28 31–43.CrossRefGoogle ScholarPubMed
Carter, J. Poulet, F. Bibring, J.-P. Mangold, N. and Murchie, S., 2013 Hydrous minerals on Mars as seen by the CRISM and OMEGA imaging spectrometers: Updated global view Journal of Geophysical Research: Planets 118 831–858.CrossRefGoogle Scholar
Chao, E.C.T. Fahey, J.J. and Littler, J., 1962 Stishovite, SiO2, a very high pressure new mineral from Meteor Crater, Arizona (Late Letter to the Editor) Journal of Geophysical Research 67 1 419–421.CrossRefGoogle Scholar
Che, C. and Glotch, T.D., 2012 The effect of high temperatures on the mid-to-far-infrared emission and nearinfrared reflectance spectra of phyllosilicates and natural zeolites: Implications for martian exploration Icarus 218 585–601.CrossRefGoogle Scholar
Che, C. and Glotch, T.D., 2014 Thermal alteration: A possible reason for the inconsistency between OMEGA/CRISM and TES detections of phyllosilicates on Mars? Geophysical Research Letters 41 321–327.CrossRefGoogle Scholar
Che, C., Glotch, T., Bish, D., Michalski, J.R., and Xu, W. (2011) Spectroscopic study of the dehydration and/or dehydroxylation of phyllosilicate and zeolite minerals. Journal of Geophysical Research, 116, E05007,.CrossRefGoogle Scholar
Cheetham, A.K. Clayden, N.J. Dobson, C.M. and Jakeman, R.J.B., 1986 Correlations between 31P n.m.r Journal of the Chemical Society, Chemical Communications 3 195–197.CrossRefGoogle Scholar
Clark, B.C. Arvidson, R.E. Gellert, R. Morris, R.V. Ming, D.W. Richter, L. Ruff, S.W. Michalski, J.R. Farrand, W.H. Yen, A. Herkenhoff, K.E. Li, R. Squyres, S.W. Schröder, C. Klingelhöfer, G. and Bell, J.F., 2007 Evidence for montmorillonite or its compositional equivalent in Columbia Hills, Mars Journal of Geophysical Research 112 E06S01.CrossRefGoogle Scholar
Clark, R.N., Rencz, A.N., 1999 Chapter 1: Spectroscopy of rocks and minerals, and principles of spectroscopy Manual of Remote Sensing, Volume 3, Remote Sensing for the Earth Sciences New York, USA John Wiley and Sons 3–58.Google Scholar
Cygan, R.T. Boslough, M.B. Kirkpatrick, R.J., Ryder, G. and Sharpton, V.L., 1992 NMR spectroscopy of experimentally shocked quartz and plagioclase feldspar powders Proceedings of the Twenty-second Lunar and Planetary Science Conference, Houston, Texas, USA, March 18–22, 1991 Houston, Texas, USA Lunar and Planetary Institute 127–136.Google Scholar
de d’Espinose, L. J.-B, F.C. and Massiot, D., 2008 MAS NMR spectra of quadrupolar nuclei in disordered solids: The Czjzek model Journal of Magnetic Resonance 192 244–251.CrossRefGoogle Scholar
Daly, T. Gavin, P. and Chevrier, V., 2011.Effects of thermal alteration on the near-infrared and mid-Infrared spectra of martian phyllosilicates Forty-second Lunar and Planetary Science Conference, Lunar and Planetary Institute Contribution 1608, Abstract #1164Google Scholar
De Carli, P.S and Jamieson, J.C., 1959 Formation of an amorphous form of quartz under shock conditions The Journal of Chemical Physics 31 1675–1676.CrossRefGoogle Scholar
Delineau, T. Allard, T. Muller, J.P. Barres, O. Yvon, J. and Cases, J.M., 1994 FTIR reflectance vs EPR studies of structural iron in kaolinites. Clays and Clay Minerals 42 308–320.CrossRefGoogle Scholar
Eberl, D. Whitney, G. and Khoury, H., 1978 Hydrothermal reactivity of smectite American Mineralogist 63 401–409.Google Scholar
Ehlmann, B.L. Mustard, J.F. Swayze, G.A. Clark, R.N. Bishop, J.L. Poulet, F. Des Marais, D.J. Roach, L.H. Milliken, R.E. Wray, J.J. Barnouin-Jha, O. and Murchie, S.L., 2009 Identification of hydrated silicate minerals on Mars using MRO-CRISM: Geologic context near Nili Fossae and implications for aqueous alteration Journal of Geophysical Research 114 E00D08.CrossRefGoogle Scholar
Ehlmann, B.L. Mustard, J.F. Murchie, S.L. Bibring, J.-P. Meunier, A. Fraeman, A.A. and Langevin, Y., 2011 Subsurface water and clay mineral formation during the early history of Mars Nature 4797371 53–60.CrossRefGoogle Scholar
Ehlmann, B.L. Bish, D.L. Ruff, S.W. and Mustard, J.F., 2012 Mineralogy and chemistry of altered Icelandic basalts: Application to clay mineral detection and understanding aqueous environments on Mars Journal of Geophysical Research 117 E00J16.CrossRefGoogle Scholar
Ehlmann, B.L. Berger, G. Mangold, N. Michalski, J.R. Catling, D.C. Ruff, S.W. Chassefière, E. Niles, P.B. Chevrier, V. and Poulet, F., 2013 Geochemical consequences of widespread clay mineral formation in Mars’ ancient crust Space Science Reviews 174 329–364.CrossRefGoogle Scholar
Engelhardt, G. and Michel, D., 1987 High-resolution Solid-State NMR of Silicates and Zeolites New York John Wiley and Sons.Google Scholar
Fahrenfort, J., 1961 Attenuated total reflection: A new principle for the production of useful infrared reflection spectra of organic compounds Spectrochimica Acta 17 698–709.CrossRefGoogle Scholar
Fairén, A.G. Chevrier, V. Abramov, O. Marzo, G.A. Gavin, P. Davila, A.F. Tornabene, L.L. Bishop, J.L. Roush, T.L. Gross, C. Kneissl, T. Uceda, E.R. Dohm, J.M. Schulze-Makuch, D. Rodríguez, J.A.P. Amils, R. and McKay, C.P., 2010 Noachian and more recent phyllosilicates in impact craters on Mars Proceedings of the National Academy of Sciences of the United States of America 107 12095–12100.CrossRefGoogle ScholarPubMed
Farmer, V.C., 1968 Infrared spectroscopy in clay mineral studies Clay Minerals 7 373–387.CrossRefGoogle Scholar
Fiske, P.S. Nellis, W.J. Xu, Z. and Stebbins, J.F., 1998 Shocked quartz: A 29Si magic-angle-spinning nuclear magnetic resonance study American Mineralogist 83 1285–1292.CrossRefGoogle Scholar
Fitzgerald, J.J. Hamza, A.I. Dec, S.F. and Bronnimann, C.E., 1996 Solid-atate 27Al and 29Si NMR and 1H CRAMPS studies of the thermal transformations of the 2:1 phyllosilicate pyrophyllite Journal of Physical Chemistry 3654 17351–17360.CrossRefGoogle Scholar
French, B.M., French, B.M. and Short, N.M., 1968 Shock metamorphism as a geologic process Shock Metamorphism of Natural Materials: Proceedings of the First Conference Held at NASA, Goddard Space Flight Center, Greenbelt, Maryland, April 14–16, 1966 Maryland, USA Mono Book Corp., Baltimore 1–17.Google Scholar
French, B.M., 1998 Traces of Catastrophe: A Handbook of Shock-Metamorphic Effects in Terrestrial Meteorite Impact Structures Houston, Texas, USA LPI Contribution 954, Lunar and Planetary Institute.Google Scholar
Friedlander, L.R. Glotch, T.D. Bish, D.L. Dyar, M.D. Sharp, T.G. Sklute, E.C. and Michalski, J.R., 2015 Structural and spectroscopic changes to natural nontronite induced by experimental impacts between 10 and 40 GPa Journal of Geophysical Research: Planets 120 888–912.CrossRefGoogle Scholar
Furukawa, Y. Sekine, T. Kakegawa, T. and Nakazawa, H., 2011 Impact-induced phyllosilicate formation from olivine and water Geochimica et Cosmochimica Acta 75 6461–6472.CrossRefGoogle Scholar
Gault, D.E. and Heitowit, E.D., 1963 The partition of energy for hypervelocity impact craters formed in rock Proceedings of the 6th Hypervelocity Impact Symposium Ohio/Moffett Field, California National Aeronautics and Space Administration, Cleveland 1–38.Google Scholar
Gavin, P. and Chevrier, V., 2010 Thermal alteration of nontronite and montmorillonite: Implications for the martian surface Icarus 208 721–734.CrossRefGoogle Scholar
Gavin, P. Chevrier, V. Ninagawa, K. Gucsik, A. and Hasagawa, S., 2013 Experimental investigation into the effects of meteoritic impacts on the spectral properties of phyllosilicates on Mars Journal of Geophysical Research: Planets 118 1–16.Google Scholar
Gibbons, R.V. and Ahrens, T.J., 1971 Shock metamorphism of silicate glasses Journal of Geophysical Research 76 5489–5498.CrossRefGoogle Scholar
Glotch, T.D. Rossman, G.R. and Aharonson, O., 2007 Midinfrared (5-100 mm) reflectance spectra and optical constants of ten phyllosilicate minerals Icarus 192 605–622.CrossRefGoogle Scholar
Gooding, J.L. Aggrey, K.E. and Muenow, D.W., 1990 Volatile compounds in shergottite and nakhlite meteorites Meteoritics and Planetary Science 25 281–289.CrossRefGoogle Scholar
Gooding, J.L. Wentworth, S.J. and Zolensky, M.E., 1991 Aqueous alteration of the Nakhla meteorite Meteoritics and Planetary Science 26 135–143.CrossRefGoogle Scholar
Grieve, R.A.F. Langenhorst, F. and Stöffler, D., 1996 Invited Review: Shock metamorphism of quartz in nature and experiment: II Significance in geoscience. Meteoritics and Planetary Science 31 6–35.CrossRefGoogle Scholar
Grotzinger, J. P. Sumner, D. Y. Kah, L. C. Stack, K. Gupta, S. Edgar, L. Rubin, D. Lewis, K. Schieber, J. Mangold, N. Milliken, R. Conrad, P. G. DesMarais, D. Farmer, J. Siebach, K. Calef, F. Hurowitz, J. McLennan, S. M. Ming, D. Vaniman, D. Crisp, J. Vasavada, A. Edgett, K. S. Malin, M. Blake, D. Gellert, R. Mahaffy, P. Wiens, R. C. Maurice, S. Grant, J. A. Wilson, S. Anderson, R. C. Beegle, L. Arvidson, R. Hallet, B. Sletten, R. S. Rice, M. Bell, J. Griffes, J. Ehlmann, B. Anderson, R. B. Bristow, T. F. Dietrich, W. E. Dromart, G. Eigenbrode, J. Fraeman, A. Hardgrove, C. Herkenhoff, K. Jandura, L. Kocurek, G. Lee, S. Leshin, L. A. Leveille, R. Limonadi, D. Maki, J. McCloskey, S. Meyer, M. Minitti, M. Newsom, H. Oehler, D. Okon, A. Palucis, M. Parker, T. Rowland, S. Schmidt, M. Squyres, S. Steele, A. Stolper, E. Summons, R. Treiman, A. Williams, R. Yingst, A. Team, M. S. Kemppinen, O. Bridges, N. Johnson, J. R. Cremers, D. Godber, A. Wadhwa, M. Wellington, D. McEwan, I. Newman, C. Richardson, M. Charpentier, A. Peret, L. King, P. Blank, J. Weigle, G. Li, S. Robertson, K. Sun, V. Baker, M. Edwards, C. Farley, K. Miller, H. Newcombe, M. Pilorget, C. Brunet, C. Hipkin, V. Leveille, R. Marchand, G. Sanchez, P. S. Favot, L. Cody, G. Fluckiger, L. Lees, D. Nefian, A. Martin, M. Gailhanou, M. Westall, F. Israel, G. Agard, C. Baroukh, J. Donny, C. Gaboriaud, A. Guillemot, P. Lafaille, V. Lorigny, E. Paillet, A. Perez, R. Saccoccio, M. Yana, C. Armiens-Aparicio, C. Rodriguez, J. C. Blazquez, I. C. Gomez, F. G. Gomez-Elvira, J. Hettrich, S. Malvitte, A. L. Jimenez, M. M. Martinez-Frias, J. Martin-Soler, J. Martin-Torres, F. J. Jurado, A. M. Mora-Sotomayor, L. Caro, G. M. Lopez, S. N. Peinado-Gonzalez, V. Pla-Garcia, J. Manfredi, J. A. R. Romeral-Planello, J. J. Fuentes, S. A. S. Martinez, E. S. Redondo, J. T. Urqui-O'Callaghan, R. Mier, M.-P. Z. Chipera, S. Lacour, J.-L. Mauchien, P. Sirven, J.-B. Manning, H. Fairen, A. Hayes, A. Joseph, J. Sullivan, R. Thomas, P. Dupont, A. Lundberg, A. Melikechi, N. Mezzacappa, A. DeMarines, J. Grinspoon, D. Reitz, G. Prats, B. Atlaskin, E. Genzer, M. Harri, A.-M. Haukka, H. Kahanpaa, H. Kauhanen, J. Paton, M. Polkko, J. Schmidt, W. Siili, T. Fabre, C. Wray, J. Wilhelm, M. B. Poitrasson, F. Patel, K. Gorevan, S. Indyk, S. Paulsen, G. Bish, D. Gondet, B. Langevin, Y. Geffroy, C. Baratoux, D. Berger, G. Cros, A. d'Uston, C. Forni, O. Gasnault, O. Lasue, J. Lee, Q.-M. Meslin, P.-Y. Pallier, E. Parot, Y. Pinet, P. Schroder, S. Toplis, M. Lewin, E. Brunner, W. Heydari, E. Achilles, C. Sutter, B. Cabane, M. Coscia, D. Szopa, C. Robert, F. Sautter, V. Le Mouelic, S. Nachon, M. Buch, A. Stalport, F. Coll, P. Francois, P. Raulin, F. Teinturier, S. Cameron, J. Clegg, S. Cousin, A. DeLapp, D. Dingler, R. Jackson, R. S. Johnstone, S. Lanza, N. Little, C. Nelson, T. Williams, R. B. Jones, A. Kirkland, L. Baker, B. Cantor, B. Caplinger, M. Davis, S. Duston, B. Fay, D. Harker, D. Herrera, P. Jensen, E. Kennedy, M. R. Krezoski, G. Krysak, D. Lipkaman, L. McCartney, E. McNair, S. Nixon, B. Posiolova, L. Ravine, M. Salamon, A. Saper, L. Stoiber, K. Supulver, K. Van Beek, J. Van Beek, T. Zimdar, R. French, K. L. Iagnemma, K. Miller, K. Goesmann, F. Goetz, W. Hviid, S. Johnson, M. Lefavor, M. Lyness, E. Breves, E. Dyar, M. D. Fassett, C. Edwards, L. Haberle, R. Hoehler, T. Hollingsworth, J. Kahre, M. Keely, L. McKay, C. Bleacher, L. Brinckerhoff, W. Choi, D. Dworkin, J. P. Floyd, M. Freissinet, C. Garvin, J. Glavin, D. Harpold, D. Martin, D. K. McAdam, A. Pavlov, A. Raaen, E. Smith, M. D. Stern, J. Tan, F. Trainer, M. Posner, A. Voytek, M. Aubrey, A. Behar, A. Blaney, D. Brinza, D. Christensen, L. DeFlores, L. Feldman, J. Feldman, S. Flesch, G. Jun, I. Keymeulen, D. Mischna, M. Morookian, J. M. Pavri, B. Schoppers, M. Sengstacken, A. Simmonds, J. J. Spanovich, N. Juarez, M. d. l. T. Webster, C. R. Yen, A. Archer, P. D. Cucinotta, F. Jones, J. H. Morris, R. V. Niles, P. Rampe, E. Nolan, T. Fisk, M. Radziemski, L. Barraclough, B. Bender, S. Berman, D. Dobrea, E. N. Tokar, R. Cleghorn, T. Huntress, W. Manhes, G. Hudgins, J. Olson, T. Stewart, N. Sarrazin, P. Vicenzi, E. Bullock, M. Ehresmann, B. Hamilton, V. Hassler, D. Peterson, J. Rafkin, S. Zeitlin, C. Fedosov, F. Golovin, D. Karpushkina, N. Kozyrev, A. Litvak, M. Malakhov, A. Mitrofanov, I. Mokrousov, M. Nikiforov, S. Prokhorov, V. Sanin, A. Tretyakov, V. Varenikov, A. Vostrukhin, A. Kuzmin, R. Clark, B. Wolff, M. Botta, O. Drake, D. Bean, K. Lemmon, M. Schwenzer, S. P. Lee, E. M. Sucharski, R. Hernandez, M. A. d. P. Avalos, J. J. B. Ramos, M. Kim, M.-H. Malespin, C. Plante, I. Muller, J.-P. Navarro-Gonzalez, R. Ewing, R. Boynton, W. Downs, R. Fitzgibbon, M. Harshman, K. Morrison, S. Kortmann, O. Williams, A. Lugmair, G. Wilson, M. A. Jakosky, B. Balic-Zunic, T. Frydenvang, J. Jensen, J. K. Kinch, K. Koefoed, A. Madsen, M. B. Stipp, S. L. S. Boyd, N. Campbell, J. L. Perrett, G. Pradler, I. VanBommel, S. Jacob, S. Owen, T. Savijarvi, H. Boehm, E. Bottcher, S. Burmeister, S. Guo, J. Kohler, J. Garcia, C. M. Mueller-Mellin, R. Wimmer-Schweingruber, R. Bridges, J. C. McConnochie, T. Benna, M. Franz, H. Bower, H. Brunner, A. Blau, H. Boucher, T. Carmosino, M. Atreya, S. Elliott, H. Halleaux, D. Renno, N. Wong, M. Pepin, R. Elliott, B. Spray, J. Thompson, L. Gordon, S. Ollila, A. Williams, J. Vasconcelos, P. Bentz, J. Nealson, K. Popa, R. Moersch, J. Tate, C. Day, M. Francis, R. McCullough, E. Cloutis, E. ten Kate, I. L. Scholes, D. Slavney, S. Stein, T. Ward, J. Berger, J. and Moores, J. E., 2013 A Habitable Fluvio-Lacustrine Environment at Yellowknife Bay, Gale Crater, Mars Science 343 6169 1242777–1242777.CrossRefGoogle ScholarPubMed
Hamilton, V.E. Christensen, P.R. McSween, H.Y. Jr. and Bandfield, J.L., 2003 Searching for the source regions of martian meteorites using MGS TES: Integrating martian meteorites into the global distribution of igneous materials on Mars Meteoritics and Planetary Science 38 871–885.CrossRefGoogle Scholar
Hanss, R.E. Montague, M.K. Davis, C. Galindo, C., Merrill, R.B., 1978 X-ray diffractometer studies of shocked materials Proceedings of the Ninth Lunar and Planetary Science Conference, Houston, Texas, USA, March 13–17, 1978, Volume 2 New York, New York, USA Pergamon Press, Inc. 2773–2787.Google Scholar
Harris, W.G. Hollien, K.A. Bates, S.R. and Acree, W.A., 1992 Dehydration of hydroxy-interlayered vermiculite as a function of time and temperature Clays and Clay Minerals 40 335–340.CrossRefGoogle Scholar
Hartmann, W.K., 1966 Martian cratering Icarus 5 565–576.CrossRefGoogle Scholar
Hartmann, W.K. and Neukum, G., 2001 Cratering chronology and the evolution of Mars Space Science Reviews 96 165–194.CrossRefGoogle Scholar
Hayashi, S. and Hayamizu, K., 1990 Accurate determination of NMR chemical shifts in alkali halides and their correlation with structural factors Bulletin of the Chemical Society of Japan 63 913–919.CrossRefGoogle Scholar
Hayashi, S. Ueda, T. Hayamizu, K. and Akiba, E., 1992 NMR study of kaolinite. 1. 29Si, 27Al and 1H spectra Journal of Physical Chemistry 96 10922–10928.CrossRefGoogle Scholar
Hörz, F. and Ahrens, T.J., 1969 Deformation of experimental shocked biotite American Journal of Science 267 1213–1229.CrossRefGoogle Scholar
Hugoniot, H., 1889 Sur la propagation du movement dans les corps et spécialement dans les gaz parfaits Journal de l-École Polytechnique 58 1–125.Google Scholar
Johnson, J. Hörz, F. Lucey, P.G. and Christensen, P.R., 2002 Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars Journal of Geophysical Research 107 5073.CrossRefGoogle Scholar
Johnson, J.R. and Hörz, F., 2003 Visible/near-infrared spectra of experimentally shocked plagioclase feldspars Journal of Geophysical Research 108 5120.CrossRefGoogle Scholar
Johnson, J.R. Staid, M.I. and Kraft, M.D., 2007 Thermal infrared spectroscopy and modeling of experimentally shocked basalts American Mineralogist 92 1148–1157.CrossRefGoogle Scholar
Kieffer, S.W., 1971 Shock metamorphism of the Coconino Sandstone at Meteor Crater, Arizona Journal of Geophysical Research 76 5449–5473.CrossRefGoogle Scholar
Kieffer, S.W. Schaal, R.B. Gibbons, R. Hörz, F. Milton, D.J. Dube, A., Merrill, R.B., 1976 Shocked basalt from Lonar Impact Crater, India and experimental analogues Proceedings of the Seventh Lunar and Planetary Science Conference, Houston, Texas, USA, March 15–19, 1976, Volume 2 New York, New York Pergamon Press, Inc. 1391–1412.Google Scholar
Kloprogge, J. and Frost, R., 2001 Infrared emission spectroscopic study of the dehydroxylation of some natural and synthetic saponites Neues Jahrbuch für Mineralogie Abhandlungen 2001 446–463.Google Scholar
Kraus, R.G. Stewart, S.T. Newman, M.G. Milliken, R.E. and Tosca, N.J., 2013 Uncertainties in the shock devolatilization of hydrated minerals: A nontronite case study Journal of Geophysical Research: Planets 118 2137–2145.CrossRefGoogle Scholar
Kulbicki, G. (1959) High temperature phases in sepiolite, attapulgite and saponite. American Mineralogist, 44, 752–764.Google Scholar
Lange, MATJ, 1982 Impact induced dehydration of serpentine and the evolution of planetary atmospheres Journal of Geophysical Research 87 A451–A456.CrossRefGoogle Scholar
Langenhorst, F., 2002 Shock metamorphism of some minerals: Basic introduction and microstructural observations Bulletin of the Czech Geological Survey 77 265–282.Google Scholar
Laperche, V. Lambert, J.F. Prost, R. and Fripiat, J.J., 1990 High-resolution solid-state NMR of exchangeable cations in the interlayer surface of a swelling mica: 23Na, 111Cd, and 133Cs vermiculites Journal of Physical Chemistry 94 8821–8831.CrossRefGoogle Scholar
Lipsicas, M. Raythatha, R.H. Pinnavaia, T.J. Johnson, I.D. Giese, R.F. Costanzo, P.M. and Robert, J.L., 1984 Silicon and aluminum site distributions in 2:1 layered silicate clays Nature 309 604–607.CrossRefGoogle Scholar
Loizeau, D. Mangold, N. Poulet, F. Bibring, J. Gendrin, A. Ansan, V. Gomez, C. Gondet, B. Langevin, Y. Masson, P. and Neukum, G., 2007 Phyllosilicates in the Mawrth Vallis region of Mars Journal of Geophysical Research 112 E08S08.CrossRefGoogle Scholar
Madejová, J. and Komadel, P., 2001 Baseline studies of the Clay Minerals Society Source Clays: Infrared methods Clays and Clay Minerals 49 410–432.CrossRefGoogle Scholar
Magi, M. Lippmaa, E. Samoson, A. Engelhardt, G. and Grimmer, A.R., 1984 Solid-state high-resolution silicon-29 chemical shifts in silicates Journal of Physical Chemistry 88 1518–1522.CrossRefGoogle Scholar
Mangold, N. Poulet, F. Mustard, J. Bibring, J. Gondet, B. Langevin, Y. Ansan, V. Masson, P. Fassett, C. Head, J. Hoffmann, H. and Neukum, G., 2007 Mineralogy of the Nili Fossae region with OMEGA/Mars Express data: 2 Aqueous alteration of the crust. Journal of Geophysical Research 112 E08S04.Google Scholar
Marzo, G.A. Davila, A.F. Tornabene, L.L. Dohm, J.M. Fairén, A.G. Gross, C. Kneissl, T. Bishop, J.L. Roush, T.L. and McKay, C.P., 2010 Evidence for Hesperian impact-induced hydrothermalism on Mars Icarus 208 667–683.CrossRefGoogle Scholar
Massiot, D. Dion, P. Alcover, J.F. and Bergaya, F., 1995 27Al and 29Si MAS NMR study of kaolinite thermal decomposition by controlled rate thermal analysis Journal of the American Ceramic Society 78 2940–2944.CrossRefGoogle Scholar
McKeown, N. Bishop, J. Noe Dobrea, E. Ehlmann, B. Parente, M. Mustard, J. Murchie, S. Swayze, G. Bibring, J. and Silver, E., 2009 Characterization of phyllosilicates observed in the central Mawrth Vallis region, Mars, their potential formational processes, and implications for past climate Journal of Geophysical Research 114 E00D10.CrossRefGoogle Scholar
Meinhold, R.H. Atakul, H. Davies, T.W. and Slade, R.C.T., 1992 Flash calcines of kaolinite: Kinetics of isothermal dehydroxylation of partially dehydroxylated flash calcines and of flash calcination itself Journal of Materials Chemistry 2 913–921.CrossRefGoogle Scholar
Meinhold, R.H. Slade, R.C.T. and Davies, T.W., 1993 Highfield 27Al MAS NMR studies of the formation of metakaolinite by flash calcination of kaolinite Applied Magnetic Resonance 4 141–155.CrossRefGoogle Scholar
Mermut, A.R. and Cano, A.F., 2001 Baseline studies of the Clay Minerals Society Source Clays: Chemical analyses of major elements Clays and Clay Minerals 49 381–386.CrossRefGoogle Scholar
Michalski, J.R. and Noe Dobrea, E.Z., 2007 Evidence for a sedimentary origin of clay minerals in the Mawrth Vallis region, Mars Geology 35 951–954.CrossRefGoogle Scholar
Michalski, J.R. Kraft, M.D. Sharp, T.G. Williams, L.B. and Christensen, P.R., 2005 Mineralogical constraints on the high-silica martian surface component observed by TES Icarus 174 161–177.CrossRefGoogle Scholar
Michalski, J.R. Kraft, M.D. Sharp, T.G. Williams, L.B. and Christensen, P.R., 2006 Emission spectroscopy of clay minerals and evidence for poorly crystalline aluminosilicates on Mars from Thermal Emission Spectrometer data Journal of Geophysical Research 111 E03004.CrossRefGoogle Scholar
Michalski, J. Poulet, F. Bibring, J.-P. and Mangold, N., 2010 Analysis of phyllosilicate deposits in the Nili Fossae region of Mars: Comparison of TES and OMEGA data Icarus 206 269–289.CrossRefGoogle Scholar
Moll, W.F. Jr., 2001 Baseline studies of the Clay Minerals Society Source Clays: Geological origin Clays and Clay Minerals 49 374–380.CrossRefGoogle Scholar
Moore, D.M. and Reynolds, R.C.J., 1989 X-Ray Diffraction and the Identification and Analysis of Clay Minerals Oxford UK Oxford University Press.Google Scholar
Moskowitz, B.M. and Hargraves, R.B., 1984 Magnetic cristobalite (?): A possible new magnetic phase produced by the thermal decomposition of nontronite Science 255 1152–1154.CrossRefGoogle Scholar
Murchie, S.L. Mustard, J.F. Ehlmann, B.L. Milliken, R.E. Bishop, J.L. McKeown, N.K. Noe Dobrea, E.Z. Seelos, F.P. Buczkowski, D.L. Wiseman, S.M. Arvidson, R.E. Wray, J.J. Swayze, G. Clark, R.N. Des Marais, D.J. McEwen, A.S. and Bibring, J.-P., 2009 A synthesis of Martian aqueous mineralogy after 1 Mars year of observations from the Mars Reconnaissance Orbiter Journal of Geophysical Research 114 E00D06.CrossRefGoogle Scholar
Mustard, J.F. Murchie, S.L. Pelkey, S.M. Ehlmann, B.L. Milliken, R.E. Grant, J.A. Bibring, J.-P. Poulet, F. Bishop, J. Noe Dobrea, E. Roach, L. Seelos, F. Arvidson, R.E. Wiseman, S. Green, R. Hash, C. Humm, D. Malaret, E. McGovern, J.A. Seelos, K. Clancy, T. Clark, R. Des Marais, D. Izenberg, N. Knudson, A. Langevin, Y. Martin, T. McGuire, P. Morris, R. Robinson, M. Roush, T. Smith, M. Swayze, G. Taylor, H. Titus, T. and Wolff, M., 2008 Hydrated silicate minerals on Mars observed by the Mars Reconnaissance Orbiter CRISM instrument Nature 454 305–309.CrossRefGoogle ScholarPubMed
Mustard, J.F. Ehlmann, B.L. Murchie, S.L. Poulet, F. Mangold, N. Head, J.W. Bibring, J.-P. and Roach, L.H., 2009 Composition, morphology, and stratigraphy of Noachian crust around the Isidis basin Journal of Geophysical Research 114 E00D12.CrossRefGoogle Scholar
Newman, R.H. Childs, C.W. and Churchman, G.J., 1994 Aluminum coordination and structural disorder in halloysite and kaolinite by 27Al NMR spectroscopy Clay Minerals 29 305–312.CrossRefGoogle Scholar
Petit, S. Madejová, J. Decarreau, A. and Martin, F., 1999 Characterization of octahedral substitutions in kaolinites using near infrared spectroscopy Clays and Clay Minerals 47 103–108.CrossRefGoogle Scholar
Petit, S. Decarreau, A. Martin, F. and Buchet, R., 2004 Refined relationship between the position of the fundamental OH stretching and the first overtones for clays Physics and Chemistry of Minerals 31 585–592.CrossRefGoogle Scholar
Post, J.L., 1984 Saponite from near Ballarat, California Clays and Clay Minerals 32 147–153.CrossRefGoogle Scholar
Poulet, F. Bibring, J. Mustard, J. Gendrin, A. Mangold, N. Langevin, Y. Arvidson, R. Gondet, B. Gomez, C. Berthé, M. Erard, S. Forni, O. Manaud, N. Poulleau, G. Soufflot, A. Combes, M. Drossart, P. Encrenaz, T. Fouchet, T. Melchiorri, R. Bellucci, G. Altieri, F. Formisano, V. Fonti, S. Capaccioni, F. Cerroni, P. Coradini, A. Korablev, O. Kottsov, V. Ignatiev, N. Titov, D. Zasova, L. Pinet, P. Schmitt, B. Sotin, C. Hauber, E. Hoffmann, H. Jaumann, R. Keller, U. and Forget, F., 2005 Phyllosilicates on Mars and implications for early martian climate Nature 438 623–627.CrossRefGoogle ScholarPubMed
Poulet, F. Mangold, N. Loizeau, D. Bibring, J. Langevin, Y. Michalski, J. and Gondet, B., 2008 Abundance of minerals in the phyllosilicate-rich units on Mars Astronomy and Astrophysics 487 L41–L44.CrossRefGoogle Scholar
Poulet, F. Beaty, D. Bibring, J. Bish, D. Bishop, J. Noe Dobrea, E. Mustard, J. Petit, S. and Roach, L., 2009 Key scientific questions and key investigations from the First International Conference on Martian Phyllosilicates Astrobiology 9 257–267.CrossRefGoogle ScholarPubMed
Pruett, R.J. and Webb, H.L., 1993 Sampling and analysis of KGa-1B well-crystallized kaolin Source Clay Clays and Clay Minerals 41 514–519.CrossRefGoogle Scholar
Rankine, W.J.M., 1870 On the thermodynamic theory of waves of finite longitudinal disturbance Proceedings of the Royal Society of London 18 80–83.Google Scholar
Roch, G.E. Smith, M.E. and Drachman, S.R., 1998 Solid state NMR characterization of the thermal transformation of an illite-rich clay Clays and Clay Minerals 46 694–704.CrossRefGoogle Scholar
Rocha, J., 1999 Single- and triple-quantum 27Al MAS NMR study of the thermal transformation of kaolinite Journal of Physical Chemistry B 103 9801–9804.CrossRefGoogle Scholar
Rocha, J. and Klinowski, J., 1990 29Si and 27Al magic-anglespinning NMR studies of the thermal transformation of kaolinite Physics and Chemistry of Minerals 17 179–186.CrossRefGoogle Scholar
Rocha, J. and Klinowski, J., 1990b Solid-state NMR studies of the structure and reactivity of metakaolinite Angewandte Chemie International Edition in English 29 553–554.CrossRefGoogle Scholar
Ruff, S.W. Christensen, P.R. Barbera, P.W. and Anderson, D.L., 1997 Quantitative thermal emission spectroscopy of minerals: A laboratory technique for measurement and calibration Journal of Geophysical Research 102 14,899–14,913.CrossRefGoogle Scholar
Sand, L.B. and Ames, L.L., 1957 Stability and decomposition products of hectorite Clays and Clay Minerals 6 392–398.CrossRefGoogle Scholar
Sanz, J. Sobrados, I. and Robert, J.L., 2015 Influence of hydration on 23Na, 27Al, and 29Si MAS-NMR spectra of sodium saponites and sodium micas American Mineralogist 100 1076–1083.CrossRefGoogle Scholar
See, T.H. Cardenas, F. and Montes, R., 2012.The Johnson Space Center Experimental Impact Lab: Contributions toward understanding the evolution of the solar system Forty-third Lunar and Planetary Science Conference, Lunar and Planetary Institute Contribution 1659, Abstract #2488Google Scholar
Slade, R.C.T. and Davies, T.W., 1991 Evolution of structural changes during flash calcination of kaolinite: A 29Si and 27Al nuclear magnetic resonance spectroscopy study Journal of Materials Chemistry 1 361–364.CrossRefGoogle Scholar
Slade, R.C.T. Davies, T.W. and Atakul, H., 1991 Flash calcination of kaolinite: Mechanistic information from thermogravimetry Journal of Materials Chemistry 1 751–756.CrossRefGoogle Scholar
Smith, M.E., 1993 Application of 27Al NMR techniques to structure determination in solids Applied Magnetic Resonance 4 1–64.CrossRefGoogle Scholar
Stöffler, D., 1972 Deformation and transformation of rockforming minerals by natural and experimental shock processes: I Behavior of minerals under shock compression. Fortschritte der Mineralogie 49 50–113.Google Scholar
Stöffler, D., 1974 Deformation and transformation of rockforming minerals by natural and experimental shock processes: II Physical properties of shocked minerals. Fortschritte der Mineralogie 51 256–289.Google Scholar
Stöffler, D., 1984 Glasses formed by hypervelocity impact Journal of Non-Crystalline Solids 67 465–502.CrossRefGoogle Scholar
Stöffler, D. and Langenhorst, F., 1994 Shock metamorphism of quartz in nature and experiment: I Basic observation and theory. Meteoritics 29 155–181.Google Scholar
Tanaka, K.L., 1987 The stratigraphy of Mars. Proceedings of the Seventeenth Lunar and Planetary Science Conference, Houston, Texas, USA, March 17–21, 1986 Journal of Geophysical Research 91 E139–E158.Google Scholar
Tanaka, K.L., 2005 Geology and insolation-driven climatic history of Amazonian north polar materials on Mars Nature 437 991–994.CrossRefGoogle ScholarPubMed
Tarte, P. Rulmont, A. Liégeois-Duyckaerts, M. Cahay, R. and Winand, J.M., 1990 Vibrational spectroscopy and solid state chemistry Solid State Ionics 42 177–196.CrossRefGoogle Scholar
Thomas-Keprta, K.L. Wentworth, S.J. Mckay, D.S. and Gibson, E.K., 2000.Field emission gun scanning electron (FEGSEM) and transmission electron (TEM) microscopy of phyllosilicates in martian meteorites ALH84001, Nakhla, and Shergotty Thirty-first Lunar and Planetary Science Conference, Lunar and Planetary Institute Contribution No. 1000, Abstract #1690Google Scholar
Tornabene, L.L. Osinski, G.R. McEwen, A.S. Wray, J.J. Craig, M.A. Sapers, H.M. and Christensen, P.R., 2013 An impact origin for hydrated silicates on Mars: A synthesis Journal of Geophysical Research: Planets 118 994–1012.CrossRefGoogle Scholar
Treiman, A.H. Barrett, R.A. and Gooding, J.L., 1993 Preterrestrial aqueous alteration of the Lafayette (SNC) meteorite Meteoritics and Planetary Science 28 86–97.CrossRefGoogle Scholar
Tyburczy, J.A. Ahrens, T.J., Ryder, G., 1987 Dehydration kinetics of shocked serpentine Proceedings of the Eighteenth Lunar and Planetary Science Conference, Houston, Texas, USA, March 16–20, 1987 Cambridge and New York/Houston, Texas, USA Cambridge University Press/Lunar and Planetary Institute 435–441.Google Scholar
Vaniman, D. T. Bish, D. L. Ming, D. W. Bristow, T. F. Morris, R. V. Blake, D. F. Chipera, S. J. Morrison, S. M. Treiman, A. H. Rampe, E. B. Rice, M. Achilles, C. N. Grotzinger, J. P. McLennan, S. M. Williams, J. Bell, J. F. Newsom, H. E. Downs, R. T. Maurice, S. Sarrazin, P. Yen, A. S. Morookian, J. M. Farmer, J. D. Stack, K. Milliken, R. E. Ehlmann, B. L. Sumner, D. Y. Berger, G. Crisp, J. A. Hurowitz, J. A. Anderson, R. Des Marais, D. J. Stolper, E. M. Edgett, K. S. Gupta, S. Spanovich, N. Agard, C. Alves Verdasca, J. A. Anderson, R. Archer, D. Armiens-Aparicio, C. Arvidson, R. Atlaskin, E. Atreya, S. Aubrey, A. Baker, B. Baker, M. Balic-Zunic, T. Baratoux, D. Baroukh, J. Barraclough, B. Bean, K. Beegle, L. Behar, A. Bender, S. Benna, M. Bentz, J. Berger, J. Berman, D. Blanco Avalos, J. J. Blaney, D. Blank, J. Blau, H. Bleacher, L. Boehm, E. Botta, O. Bottcher, S. Boucher, T. Bower, H. Boyd, N. Boynton, B. Breves, E. Bridges, J. Bridges, N. Brinckerhoff, W. Brinza, D. Brunet, C. Brunner, A. Brunner, W. Buch, A. Bullock, M. Burmeister, S. Cabane, M. Calef, F. Cameron, J. Campbell, J. I. Cantor, B. Caplinger, M. Caride Rodriguez, J. Carmosino, M. Carrasco Blazquez, I. Charpentier, A. Choi, D. Clark, B. Clegg, S. Cleghorn, T. Cloutis, E. Cody, G. Coll, P. Conrad, P. Coscia, D. Cousin, A. Cremers, D. Cros, A. Cucinotta, F. d'Uston, C. Davis, S. Day, M. K. de la Torre Juarez, M. DeFlores, L. DeLapp, D. DeMarines, J. Dietrich, W. Dingler, R. Donny, C. Drake, D. Dromart, G. Dupont, A. Duston, B. Dworkin, J. Dyar, M. D. Edgar, L. Edwards, C. Edwards, L. Ehresmann, B. Eigenbrode, J. Elliott, B. Elliott, H. Ewing, R. Fabre, C. Fairen, A. Farley, K. Fassett, C. Favot, L. Fay, D. Fedosov, F. Feldman, J. Feldman, S. Fisk, M. Fitzgibbon, M. Flesch, G. Floyd, M. Fluckiger, L. Forni, O. Fraeman, A. Francis, R. Francois, P. Franz, H. Freissinet, C. French, K. L. Frydenvang, J. Gaboriaud, A. Gailhanou, M. Garvin, J. Gasnault, O. Geffroy, C. Gellert, R. Genzer, M. Glavin, D. Godber, A. Goesmann, F. Goetz, W. Golovin, D. Gomez Gomez, F. Gomez-Elvira, J. Gondet, B. Gordon, S. Gorevan, S. Grant, J. Griffes, J. Grinspoon, D. Guillemot, P. Guo, J. Guzewich, S. Haberle, R. Halleaux, D. Hallet, B. Hamilton, V. Hardgrove, C. Harker, D. Harpold, D. Harri, A.-M. Harshman, K. Hassler, D. Haukka, H. Hayes, A. Herkenhoff, K. Herrera, P. Hettrich, S. Heydari, E. Hipkin, V. Hoehler, T. Hollingsworth, J. Hudgins, J. Huntress, W. Hviid, S. Iagnemma, K. Indyk, S. Israel, G. Jackson, R. Jacob, S. Jakosky, B. Jensen, E. Jensen, J. K. Johnson, J. Johnson, M. Johnstone, S. Jones, A. Jones, J. Joseph, J. Jun, I. Kah, L. Kahanpaa, H. Kahre, M. Karpushkina, N. Kasprzak, W. Kauhanen, J. Keely, L. Kemppinen, O. Keymeulen, D. Kim, M.-H. Kinch, K. King, P. Kirkland, L. Kocurek, G. Koefoed, A. Kohler, J. Kortmann, O. Kozyrev, A. Krezoski, J. Krysak, D. Kuzmin, R. Lacour, J. L. Lafaille, V. Langevin, Y. Lanza, N. Lasue, J. Le Mouelic, S. Lee, E. M. Lee, Q.-M. Lees, D. Lefavor, M. Lemmon, M. Malvitte, A. L. Leshin, L. Leveille, R. Lewin-Carpintier, E. Lewis, K. Li, S. Lipkaman, L. Little, C. Litvak, M. Lorigny, E. Lugmair, G. Lundberg, A. Lyness, E. Madsen, M. Mahaffy, P. Maki, J. Malakhov, A. Malespin, C. Malin, M. Mangold, N. Manhes, G. Manning, H. Marchand, G. Marin Jimenez, M. Martin Garcia, C. Martin, D. Martin, M. Martinez-Frias, J. Martin-Soler, J. Martin-Torres, F. J. Mauchien, P. McAdam, A. McCartney, E. McConnochie, T. McCullough, E. McEwan, I. McKay, C. McNair, S. Melikechi, N. Meslin, P.-Y. Meyer, M. Mezzacappa, A. Miller, H. Miller, K. Minitti, M. Mischna, M. Mitrofanov, I. Moersch, J. Mokrousov, M. Molina Jurado, A. Moores, J. Mora-Sotomayor, L. Mueller-Mellin, R. Muller, J.-P. Munoz Caro, G. Nachon, M. Navarro Lopez, S. Navarro-Gonzalez, R. Nealson, K. Nefian, A. Nelson, T. Newcombe, M. Newman, C. Nikiforov, S. Niles, P. Nixon, B. Noe Dobrea, E. Nolan, T. Oehler, D. Ollila, A. Olson, T. Owen, T. de Pablo Hernandez, M. A. Paillet, A. Pallier, E. Palucis, M. Parker, T. Parot, Y. Patel, K. Paton, M. Paulsen, G. Pavlov, A. Pavri, B. Peinado-Gonzalez, V. Pepin, R. Peret, L. Perez, R. Perrett, G. Peterson, J. Pilorget, C. Pinet, P. Pla-Garcia, J. Plante, I. Poitrasson, F. Polkko, J. Popa, R. Posiolova, L. Posner, A. Pradler, I. Prats, B. Prokhorov, V. Purdy, S. W. Raaen, E. Radziemski, L. Rafkin, S. Ramos, M. Raulin, F. Ravine, M. Reitz, G. Renno, N. Richardson, M. Robert, F. Robertson, K. Rodriguez Manfredi, J. A. Romeral-Planello, J. J. Rowland, S. Rubin, D. Saccoccio, M. Salamon, A. Sandoval, J. Sanin, A. Sans Fuentes, S. A. Saper, L. Sautter, V. Savijarvi, H. Schieber, J. Schmidt, M. Schmidt, W. Scholes, D. D. Schoppers, M. Schroder, S. Schwenzer, S. Sebastian Martinez, E. Sengstacken, A. Shterts, R. Siebach, K. Siili, T. Simmonds, J. Sirven, J.-B. Slavney, S. Sletten, R. Smith, M. Sobron Sanchez, P. Spray, J. Squyres, S. Stalport, F. Steele, A. Stein, T. Stern, J. Stewart, N. Stipp, S. L. S. Stoiber, K. Sucharski, B. Sullivan, R. Summons, R. Sun, V. Supulver, K. Sutter, B. Szopa, C. Tan, F. Tate, C. Teinturier, S. ten Kate, I. Thomas, P. Thompson, L. Tokar, R. Toplis, M. Torres Redondo, J. Trainer, M. Tretyakov, V. Urqui-O'Callaghan, R. Van Beek, J. Van Beek, T. VanBommel, S. Varenikov, A. Vasavada, A. Vasconcelos, P. Vicenzi, E. Vostrukhin, A. Voytek, M. Wadhwa, M. Ward, J. Webster, C. Weigle, E. Wellington, D. Westall, F. Wiens, R. C. Wilhelm, M. B. Williams, A. Williams, R. Williams, R. B. M. Wilson, M. Wimmer-Schweingruber, R. Wolff, M. Wong, M. Wray, J. Wu, M. Yana, C. Yingst, A. Zeitlin, C. Zimdar, R. and Zorzano Mier, M.-P., 2013 Mineralogy of a Mudstone at Yellowknife Bay, Gale Crater, Mars Science 343 6169 1243480–1243480.CrossRefGoogle ScholarPubMed
Weiss, C.A. Altaner, S.P. and Kirkpatrick, R.J., 1987 Highresolution 29Si NMR spectroscopy of 2:1 layer silicates: Correlations among chemical shift, structural distortions, and chemical variations American Mineralogist 72 935–942.Google Scholar
Weldon, R.J. Thomas, W.M. Boslough, M.B. and Ahrens, T.J., 1982 Shock-induced color changes in nontronite: Implications for the martian fines Journal of Geophysical Research 87 10,102–10,114.CrossRefGoogle Scholar
Wiseman, S.M. Arvidson, R.E. Morris, R.V. Poulet, F. Andrews-Hanna, J.C. Bishop, J.L. Murchie, S.L. Seelos, F.P. Des Marais, D. and Griffes, J.L., 2010 Spectral and stratigraphic mapping of hydrated sulfate and phyllosilicatebearing deposits in northern Sinus Meridiani, Mars Journal of Geophysical Research 115 E00D18.CrossRefGoogle Scholar
Woessner, D.E., 1989 Characterization of clay minerals by 27Al nuclear magnetic resonance spectroscopy American Mineralogist 74 203–215.Google Scholar
Wray, J. Noe Dobrea, E. Arvidson, R. Wiseman, S. Squyres, S. McEwen, A. Mustard, J. and Murchie, S., 2009 Phyllosilicates and sulfates at Endeavour Crater, Meridiani Planum, Mars Geophysical Research Letters 36 L21201.CrossRefGoogle Scholar