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Geochemistry and related studies of Clyde Estuary sediments

Published online by Cambridge University Press:  13 November 2018

David G. Jones ,
Christopher H. Vane ,
Solveigh Lass-Evans ,
Simon Chenery ,
Bob Lister ,
Mark Cave ,
Joana Gafeira ,
Gareth Jenkins ,
Alick Leslie  and
Neil Breward
...Show all authors
David G. Jones
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Christopher H. Vane*
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Solveigh Lass-Evans
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK.
Simon Chenery
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Bob Lister
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Mark Cave
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Joana Gafeira
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK.
Gareth Jenkins
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Alick Leslie
Affiliation:
British Geological Survey, The Lyell Centre, Research Avenue South, Edinburgh EH14 4AP, UK.
Neil Breward
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Katy Freeborough
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Ian Harrison
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Alexander W. Kim
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Alicja Lacinska
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Tony Milodowski
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
John Ridgway
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Jim Riding
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Mick Strutt
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Doris Wagner
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
Ian Wilkinson
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK. Email: chv@bgs.ac.uk
*
*Corresponding author
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Abstract

Geochemical and related studies have been made of near-surface sediments from the River Clyde estuary and adjoining areas, extending from Glasgow to the N, and W as far as the Holy Loch on the W coast of Scotland, UK. Multibeam echosounder, sidescan sonar and shallow seismic data, taken with core information, indicate that a shallow layer of modern sediment, often less than a metre thick, rests on earlier glacial and post-glacial sediments. The offshore Quaternary history can be aligned with onshore sequences, with the recognition of buried drumlins, settlement of muds from quieter water, probably behind an ice dam, and later tidal delta deposits. The geochemistry of contaminants within the cores also indicates shallow contaminated sediments, often resting on pristine pre-industrial deposits at depths less than 1m. The distribution of different contaminants with depth in the sediment, such as Pb (and Pb isotopes), organics and radionuclides, allow chronologies of contamination from different sources to be suggested. Dating was also attempted using microfossils, radiocarbon and 210Pb, but with limited success. Some of the spatial distribution of contaminants in the surface sediments can be related to grain-size variations. Contaminants are highest, both in absolute terms and in enrichment relative to the natural background, in the urban and inner estuary and in the Holy Loch, reflecting the concentration of industrial activity.

Keywords

contaminantsmetalsorganicsPb isotopesQuaternary historyradionuclidesScotlandUK
Type
Articles
Information
Earth and Environmental Science Transactions of The Royal Society of Edinburgh , Volume 108 , Issue 2-3: The Geosciences in Europe’s Urban Sustainability: Lessons from Glasgow and Beyond (CUSP) , June 2017 , pp. 269 - 288
Copyright
Copyright © British Geological Survey UKRI 2018 

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References

5. References

Alexander, D. 2015. The Iron Age. Glasgow: Culture and Sport Glasgow (Glasgow Museums).Google Scholar
Assinder, D. J., Yamamoto, M., Kim, C. K., Seki, R., Takaku, Y., Yamauchi, Y., Igarashi, S., Komura, K. & Ueno, K. 1993. Radioisotopes of 13 elements in intertidal coastal and estuarine sediments in the Irish Sea. Journal of Radioanalytical and Nuclear Chemistry-Articles 170, 333–346.Google Scholar
Berry, W. J., Boothman, W. S., Serbst, J. R. & Edwards, P. A. 2004. Predicting the toxicity of chromium in sediments. Environmental Toxicology and Chemistry 23, 2981–2992.Google Scholar
Birch, G. F. & Davies, K. 2003. A scheme for assessing human impact and sediment quality in coastal waterways. Coastal GIS 2003: an integrated approach to Australian issues. Wollongong Papers on Marine Policy 23, 371–380.Google Scholar
Birch, G. F. & Olmos, M. A. 2008. Sediment-bound heavy metals as indicators of human influence and biological risk in coastal water bodies. ICES Journal of Marine Science 65, 1407–1413.Google Scholar
Brown, J. E., McDonald, P., Parker, A. & Rae, J. E. 1999. The vertical distribution of radionuclides in a Ribble Estuary saltmarsh: transport and deposition of radionuclides. Journal of Environmental Radioactivity 43, 259–275.Google Scholar
Browne, M. & McMillan, A. 1989. Quaternary geology of the Clyde valley. British Geological Survey Research Report, SA/89/1.Google Scholar
Cave, M. R., Milodowski, A. E. & Friel, E. N. 2004. Evaluation of a method for identification of host physico-chemical phases for trace metals and measurement of their solid-phase partitioning in soil samples by nitric acid extraction and chemometric mixture resolution. Geochemistry: Exploration, Environment, Analysis 4, 71–86.Google Scholar
Colina, M., Gardiner, P. H. E., Rivas, Z. & Troncone, F. 2005. Determination of vanadium species in sediment, mussel and fish muscle tissue samples by liquid chromatography–inductively coupled plasma-mass spectrometry. Analytica Chimica Acta 538, 107–115.Google Scholar
Cook, G. T., MacKenzie, A. B., McDonald, P. & Jones, S. R. 1997. Remobilization of Sellafield-derived radionuclides and transport from the north-east Irish Sea. Journal of Environmental Radioactivity 35, 227–241.Google Scholar
Deegan, C., Kirby, R., Rae, I. & Floyd, R. 1973. The superficial deposits of the Firth of Clyde and its sea lochs. Report of the Institute of Geological Sciences, 73/9.Google Scholar
Dyer, K. R. 1997. Estuaries: a physical introduction. Chichester: John Wiley & Sons.Google Scholar
Edgar, P. J., Davies, I. M., Hursthouse, A. S. & Matthews, J. E. 1999. The biogeochemistry of polychlorinated biphenyls (PCBs) in the Clyde: distribution and source evaluation. Marine Pollution Bulletin 38, 486–496.Google Scholar
European Community. 2000. Directive 2000/60/EC of October 23 2000 of the European Parliament and of the Council establishing a framework for community action in the field of water policy. Official Journal of the European Community L327, 1–72.Google Scholar
Farr, K. M. 1989. Palynomorph and palynodebris distributions in modern British and Irish estuarine sediments. In Batten, D. J. & Keen, M. C. (eds) Northwest European micropalaeontology and palynology, 265–285. Chichester: Ellis Horwood Limited.Google Scholar
Fordyce, F. M., O' Dochartaigh, B., Lister, T. R., Cooper, R., Kim, A., Harrison, I., Vane, C. & Brown, S. 2004. Clyde tributaries: report of urban stream sediment and surface water geochemistry for Glasgow. British Geological Survey Commissioned Report, CR/04/037. Keyworth, Nottingham: British Geological Survey.Google Scholar
Fyfe, J., Long, D. & Evans, D. 1993. The geology of the Malin-Hebrides area. UK Offshore Regional Report. London: HMSO.Google Scholar
Hayslip, G., Edmond, L., Partridge, V., Nelson, W., Lee, H., Cole, F., Lamberson, J. & Caton, L. 2006. Ecological Condition of the Estuaries of Oregon and Washington. U.S. Environmental Protection Agency, Office of Environmental Assessment, Region 10 Report, EPA 910-R-06-001.Google Scholar
Ingham, M. N. & Vrebos, B. A. R. 1994. High productivity geochemical XRF analysis. Advances in X-ray Analysis 37, 717–724.Google Scholar
Jardine, W. G. 1980. Glasgow region: field guide. Glasgow: Quaternary Research Association.Google Scholar
Jardine, W. G. 1986. The geological and geomorphological setting of the Estuary and Firth of Clyde. Proceedings of the Royal Society of Edinburgh 90B, 25–41.Google Scholar
Jones, D. G., Lister, T. R., Strutt, M. H., Entwisle, D. C., Harrison, I., Kim, A. W., Ridgway, J. & Vane, C. H. 2004. Estuarine Geochemistry: Report for Glasgow City Council. British Geological Survey Commissioned Report, CR/04/057.Google Scholar
Jones, D. G., Kershaw, P. J., McMahon, C. A., Milodowski, A. E., Murray, M. & Hunt, G. J. 2007. Changing patterns of radionuclide distribution in Irish Sea subtidal sediments. Journal of Environmental Radioactivity 96, 63–74.Google Scholar
Kershaw, P. J., Woodhead, D. S., Malcolm, S. J., Allington, D. J. & Lovett, M. B. 1990. A sediment history of Sellafield discharges. Journal of Environmental Radioactivity 12, 201–241.Google Scholar
Klamer, H. J. C., Leonards, P. E. G., Lamoree, M. H., Villerius, L. A., Åkerman, J. E. & Bakker, J. F. 2005. A chemical and toxicological profile of Dutch North Sea surface sediments. Chemosphere 58, 1579–1587.Google Scholar
Leslie, A. B., Gafeira, J., Jenkins, G. O. & Freeborough, K. A. 2011. Clyde Estuary boomer and multibeam survey interpretation, 2002–2009. British Geological Survey Open Report, OR/11/012.Google Scholar
Long, E. R., MacDonald, D. D., Smith, S. L. & Calder, F. 1995. Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments. Environmental Management 19, 81–97.Google Scholar
MacDonald, D. D., Carr, R. S., Calder, F. D., Long, E. R. & Ingersoll, C. G. 1996. Development and evaluation of sediment quality guidelines for Florida coastal waters. Ecotoxicology 5, 253–278.Google Scholar
MacDonald, D. D., Dipinto, L. M., Field, J., Ingersoll, C. G., Lvong, E. R. & Swartz, R. C. 2000a. Development and evaluation of consensus-based sediment effect concentrations for polychlorinated biphenyls. Environmental Toxicology and Chemistry 19, 1403–1413.Google Scholar
MacDonald, D. D., Ingersoll, C. G. & Berger, T. A. 2000b. Development and evaluation of consensus-based sediment quality guidelines for freshwater ecosystems. Archives of Environmental Contamination and Toxicology 39, 20–31.10.1007/s002440010075Google Scholar
MacKenzie, A. B., Scott, R. D., Allan, R. L., Benshaban, Y. A., Cook, G. T. & Pulford, I. D. 1994. Sediment radionuclide profiles – implications for mechanisms of Sellafield waste dispersal in the Irish Sea. Journal of Environmental Radioactivity 23, 39–69.Google Scholar
MacKenzie, A. B., Cook, G. T., McDonald, P. & Jones, S. R. 1998. The influence of mixing timescales and re-dissolution processes on the distribution of radionuclides in northeast Irish Sea sediments. Journal of Environmental Radioactivity 39, 35–53.Google Scholar
Macklin, M. G. 1992. Metal contaminated soils and sediment: a geographical perspective. In Newson, M. D. (ed.) Managing the human impact on the natural environment: patterns and processes, 172–195. London: Belhaven Press.Google Scholar
Mai, B., Chen, S., Luo, X., Chen, L., Yang, Q., Sheng, G., Peng, P., Fu, J. & Zeng, E. Y. 2005. Distribution of polybrominated diphenyl ethers in sediments of the pearl river delta and adjacent South China Sea. Environmental Science & Technology 39, 3521–3527.Google Scholar
Matschullat, J., Ottenstein, R. & Reimann, C. 2000. Geochemical background – can we calculate it? Environmental Geology 39, 990–1000.Google Scholar
Miller, B. S., Pirie, D. J. & Redshaw, C. J. 2000. An assessment of the contamination and toxicity of marine sediments in the Holy Loch, Scotland. Marine Pollution Bulletin 40, 22–35.Google Scholar
O'Connor, T. P. 2004. The sediment quality guideline, ERL, is not a chemical concentration at the threshold of sediment toxicity. Marine Pollution Bulletin 49, 383–385.Google Scholar
OSPAR. 2008. CEMP assessment manual: co-ordinated environmental monitoring programme assessment manual for contaminants in sediment and biota. OSPAR Monitoring and Assessment Series, 379/2008.Google Scholar
OSPAR. 2009. Agreement on CEMP assessment criteria for the QSR 2010. Agreement number 2009–2 OSPAR 2010. The Quality Status Report 2010. London: OSPAR Commission.Google Scholar
Peacock, J. D. 1975. Scottish late- and post-glacial marine deposits. In Gemmell, A. M. D. (ed.) Quaternary studies in North East Scotland, 45–48. Aberdeen: Quaternary Research Association.Google Scholar
Peacock, J. D., Graham, D. K. & Wilkinson, I. P. 1978. Late-glacial and post-glacial marine environments at Ardyne, Scotland, and their significance in the interpretation of the history of the Clyde sea area. Institute of Geological Sciences, Report 78/17.Google Scholar
Pearce, J. 1997. Marine pollution. Marine Pollution Bulletin 34, 592–594.Google Scholar
Ridgway, J., Bee, E., Breward, N., Cave, M. R., Chenery, S., Gowing, C., Harrison, I., Hodgkinson, E., Humphreys, B., Ingham, M., Jarrow, A., Jenkins, G., Kim, A., Lister, T. R., Milodowski, A. E., Pearson, S., Rowlands, K., Spiro, B., Strutt, M. H., Turner, P. & Vane, C. H. 2012. The Mersey Estuary: sediment geochemistry. Keyworth, Nottingham: British Geological Survey.Google Scholar
Riding, J. B. & Kyffin-Hughes, J. E. 2004. A review of the laboratory preparation of palynomorphs with a description of an effective non-acid technique. Revista Brasileira de Paleontologia 7, 13–44.Google Scholar
Rogers, H. R. 2002. Assessment of PAH contamination in estuarine sediments using the equilibrium partitioning-toxic unit approach. The Science of the Total Environment 290, 139–155.Google Scholar
Santamaria-Fernández, R., Cave, M. R. & Hill, S. J. 2006. Trace metal distribution in the Arosa estuary (N.W. Spain): the application of a recently developed sequential extraction procedure for metal partitioning. Analytica Chimica Acta 557, 344–352.Google Scholar
Schoonen, M. 2004. Mechanisms of sedimentary pyrite formation. In Amend, J. & Edwards, K. & Lyons, T. (eds) Sulfur biogeochemistry: past and present. Geological Society of America Special Paper 379, 117–134. Boulder, CO: The Geological Society of America Inc.Google Scholar
Vane, C. H., Harrison, I. & Kim, A. W. 2007a. Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in sediments from the Mersey Estuary, UK. Science of the Total Environment 374, 112–126.Google Scholar
Vane, C. H., Harrison, I. & Kim, A. W. 2007b. Assessment of polyaromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in surface sediments of the Inner Clyde Estuary, UK. Marine Pollution Bulletin 54, 1301–1306.Google Scholar
Vane, C. H., Jones, D. G. & Lister, T. R. 2009. Mercury contamination in surface sediments and sediment cores of the Mersey Estuary, UK. Marine Pollution Bulletin 58, 940–946.Google Scholar
Vane, C. H., Ma, Y.-J., Chen, S.-J. & Mai, B.-X. 2010. Increasing polybrominated diphenyl ether (PBDE) contamination in sediment cores from the inner Clyde Estuary, UK. Environmental Geochemistry and Health 32, 13–21.Google Scholar
Vane, C. H., Chenery, S. R., Harrison, I., Kim, A. W., Moss-Hayes, V. & Jones, D. G. 2011. Chemical signatures of the Anthropocene in the Clyde estuary, UK: sediment-hosted Pb, 207/206Pb, total petroleum hydrocarbon, polyaromatic hydrocarbon and polychlorinated biphenyl pollution records. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 369, 1085–1111.Google Scholar
Woodhead, R. J., Law, R. J. & Matthiessen, P. 1999. Polycyclic aromatic hydrocarbons in surface sediments around England and Wales, and their possible biological significance. Marine Pollution Bulletin 38, 773–790.Google Scholar
Zhang, W., Feng, H., Chang, J., Qu, J., Xie, H. & Yu, L. 2009. Heavy metal contamination in surface sediments of Yangtze River intertidal zone: an assessment from different indexes. Environmental Pollution 157, 1533–1543.Google Scholar