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Modeling of grain refinement: Part I. Effect of the solute titanium for aluminum

Published online by Cambridge University Press:  31 January 2011

X. Yao*
Affiliation:
School of Engineering, University of Queensland, Brisbane, 4072 QLD, Australia
S.D. McDonald
Affiliation:
CRC Centre for Metals Manufacturing (CAST) Cooperative Research Centre, University of Queensland, Brisbane, 4072 QLD, Australia
A.K. Dahle
Affiliation:
CRC Centre for Metals Manufacturing (CAST) Cooperative Research Centre, University of Queensland, Brisbane, 4072 QLD, Australia
C.J. Davidson
Affiliation:
Commonwealth Scientific and Industrial Research Organization (CSIRO)—Manufacturing & Infrastructure Technology, Kenmore, 4069 QLD, Australia
D.H. StJohn
Affiliation:
CRC Centre for Metals Manufacturing (CAST) Cooperative Research Centre, University of Queensland, Brisbane, 4072 QLD, Australia
*
a)Address all correspondence to this author. e-mail: x.yao@uq.edu.au
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Abstract

Over the past few decades, the grain refinement of Al alloys has been extensively investigated theoretically and experimentally. However, the relative importance of the parameters that contribute to grain refinement still remains unclear and is likely to be dependent on specific solidification conditions. This paper aims to investigate the mechanisms by which Ti, a common grain-refining addition in commercial-purity aluminum (CP), contributes to grain refinement using a cellular automaton—finite control volume method (CAFVM). CAFVM is used to model the grain formation and microstructure morphology under different conditions, e.g., with and without refiners, for Al alloys. In this Part I, the effect of adding solute of Ti on grain formation through its effect on growth restriction, constitutional undercooling, and the formation of extra-potential particles are taken into account in the calculations. It is shown that the calculated results are in reasonable agreement with the experimental data.

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Articles
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1McCartney, D.G.: Grain refining of aluminum and its alloys using inoculants. Int. Mater. Rev. 34, 247 1989CrossRefGoogle Scholar
2Zhou, Y., Hu, Z.Q.Jie, W.: Solidification Technology Mechanical Industrial Press Beijing, China 1998 125Google Scholar
3Spittle, J.A.Cushway, A.A.: Influences of superheat and grain structure on hot tearing susceptibilities of Al–Cu alloy castings. Met. Technol. 10, 6 1983CrossRefGoogle Scholar
4Maxwell, I.Hellawell, A.: Simple model for grain refinement during solidification. Acta Metall. 23, 229 1975CrossRefGoogle Scholar
5Desnain, P., Fautrelle, Y., Meyer, J-L., Requet, J-P.Durand, F.: Prediction of equiaxed grain density in multicomponent alloys, stirred electromagnetically. Acta Metall. Mater. 38, 1513 1990CrossRefGoogle Scholar
6Hodaj, F.Durand, F.: Equiaxed grains in multicomponent alloys: Effect of growth rate. Acta Mater. 45, 2121 1997CrossRefGoogle Scholar
7Greer, A.L., Bunn, A.M., Tronche, A., Evans, P.V.Bristow, D.J.: Modelling of inoculation of metallic melts: Application to grain refinement of aluminium by Al–Ti–B. Acta Mater. 48, 2823 2000CrossRefGoogle Scholar
8Rappaz, M.Gandin, Ch-A.: Probabilistic modeling of microstructure formation in solidification processes. Acta Metall. Mater. 41, 345 1993CrossRefGoogle Scholar
9Gandin, Ch-A.Rappaz, M.: A coupled finite-element cellular-automaton model for the prediction of dendritic grain structures in solidification processes. Acta Metall. Mater. 42, 2233 1994CrossRefGoogle Scholar
10Nastac, L.: Numerical modeling of solidification morphologies and segregation patterns in cast dendritic alloys. Acta Mater. 47, 4253 1999CrossRefGoogle Scholar
11Zhu, M.F.Hong, C.P.: A modified cellular automaton model for the simulation of dendritic growth in solidification of alloys. ISIJ Int. 41, 436 2001CrossRefGoogle Scholar
12Yao, X., Davidson, C.J., Dahle, A.K.StJohn, D.H.: Modelling of microstructure formation and evolution during solidification. Int. J. Cast Metals Res. 15, 219 2002CrossRefGoogle Scholar
13Easton, M.StJohn, D.H.: Grain refinement of aluminum alloys: Part I. The nucleant and salute paradigms—A review of the literature. Metall. Mater. Trans. A 30, 1613 1999CrossRefGoogle Scholar
14Lee, S.Y., Lee, S.M.Hong, C.P.: Numerical modeling of deflected columnar dendritic grains solidified in a flowing melt and its experimental verification. ISIJ Int. 40, 48 2000CrossRefGoogle Scholar
15Yao, X., Wang, H., He, B.Zhou, X.: Modeling of columnar-to-equiaxed transition in solidified Al–Si alloys. Mater. Sci. Forum 457–479, 3141 2005CrossRefGoogle Scholar
16Easton, M.StJohn, D.H.: Grain refinement of aluminum alloys: Part II. Confirmation of, and a mechanism for, the solute paradigm. Metall. Mater. Trans. A 30, 1625 1999CrossRefGoogle Scholar
17StJohn, D.H.: The peritectic reaction. Acta Metall. Mater. 38, 631 1990CrossRefGoogle Scholar
18Kurz, W., Giovanola, B.Trivedi, R.: Theory of microstructural development during rapid solidification. Acta Metall. 34, 823 1986CrossRefGoogle Scholar
19Cho, S-H., Okane, T.Umeda, T.: CA-DFD analysis of nucleation parameter effects on the grain structures of castings. Int. J. Cast Metals Res. 13, 327 2001Google Scholar
20Yoo, X., Dargusch, M.S., Dahle, A.K., Davidson, C.J.StJohn, D.H.: Investigation into the effect of nucleation parameters on grain formation during solidification using a cellular automaton-finite control volume method (CAFVM). J. Mater. Res. (in press)Google Scholar
21Easton, M. Grain refinement mechanisms in aluminum and its alloys and the effect of grain refinement on castability.Ph.D. Thesis, The University of Queensland, 1999,Google Scholar
22Kurz, W., Fisher, D.J.: Fundamentals of Solidification J. Mater. Res. (in press)Google Scholar
23Yao, X.: Effect of the solute redistribution on the growth kinetics in solidification. Trans Tech Publications Ltd. Zurich, Switzerland 1986 54Google Scholar
24Johnsson, M.: Grain-refinement of aluminium studied by use of a thermal analytical technique. Thermochim. Acta 256, 107 1995CrossRefGoogle Scholar
25Johnsson, M.Backerud, L.: The influence of composition on equiaxed crystal growth mechanisms and grain size in Al alloys. Z. Metallkd. 87, 216 1996Google Scholar
26Spittle, J.A.Sadli, S.: Effect of alloy variables on grain-refinement of binary aluminum-alloys with Al–Ti–B. Mater. Sci. Technol. 11, 533 1995CrossRefGoogle Scholar
27Yao, X., Davidson, C.J., Dahle, A.K.StJohn, D.H.: Effect of solute on the growth rate and the constitutional undercooling ahead of the advancing interface during solidification of an alloy and the implications for nucleation. J. Mater. Res. 21, 2470 2006CrossRefGoogle Scholar
28Tronche, A.Greer, A.L.: Design of grain refiners for aluminium alloys in Light Metals 2000, edited by R.D. Peterson (TMS, Warrendale, PA, 2000), p. 827Google Scholar
29Mondolfo, L.F., Farooq, S.Tse, C.: Solidification Processing 1987 The Institute of Metals London, UK 1988 133Google Scholar
30Cornish, A.J.: The influences of boron on the mechanism of grain refinement in dilute aluminum–titanium alloys. Met. Sci. 9, 477 1975CrossRefGoogle Scholar
31Marcantonio, J.A.Mondolfo, L.F.: Grain refinement in aluminum alloyed with titanium and boron. Metall. Trans 2, 465 1971Google Scholar
32Jones, G.P.Pearso, J.: Factors affecting grain refinement of aluminum using titanium and boron additives. Metall. Trans. 7, 223 1976CrossRefGoogle Scholar
33Sigworth, G.K.: The grain refining of aluminum and phase-relationships in the Al–Ti–B system. Metall. Trans. A 15, 277 1984CrossRefGoogle Scholar
34Sigwort, G.K.: The grain refining of aluminum and phase-relationships in the Al–Ti–B system-reply. Metall. Trans. A 22, 349 1986Google Scholar
35Johnsson, M.: A critical survey on grain refinement of aluminum.Ph.D. Thesis, Stockholm University, Stockholm, 1993,Google Scholar
36Wanqi, J.Reif, W.: Effect of Cu content on grain-refinement of an Al–Cu alloy with AlTi6 and AlTi5B1 refiners. Z. Metallkd. 84, 445 1993Google Scholar
37Backerud, L.Shao, Y.D.: Grain refining mechanism as a result of addition of titanium and boron. Aluminium 67, 780 1991Google Scholar
38Mohanty, P.S.Gruzleski, J.E.: Mechanism of grain-refinement in aluminum. Acta Metall. Mater. 43, 2001 1995CrossRefGoogle Scholar
39Johnsson, M.: On the mechanism of grain refining aluminum after additions of Ti and B in Light Metals 1993, edited by S.K. Das TMS Warrendale, PA 1993 769Google Scholar
40Cibula, A.: The grain refinement of aluminum alloy castings by additions of titanium and boron. J. Inst. Met. 80, 1 1952Google Scholar
41Banjeri, A.Reif, W.: Development of Al–Ti–C grain refiners containing TiC. Metall. Trans. A 17, 2127 1986Google Scholar
42Vandyoussefi, M.Greer, A.L.: Application of cellular automatonfinite element model to the grain refinement of directionally solidified Al–4.15 wt% Mg alloys. Acta Mater. 50, 1693 2002CrossRefGoogle Scholar
43Yao, X., McDonald, S.D., Dahle, A.K., Davidson, C.J.StJohn, D.H.: Modeling of grain refinement: Part II. Effect of nucleant particles—TiB2 additions for aluminum. J. Mater. Res. 23(5), 1292 2008CrossRefGoogle Scholar