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The multiscale effects of graphene oxide on the corrosion resistance properties of waterborne alkyd resin coatings

Published online by Cambridge University Press:  06 February 2019

Juanjuan Li ,
Huan Zhang ,
Furong Sun ,
Hong Zhou ,
Lijuan Zhao  and
Yongjiao Song
Juanjuan Li*
Affiliation:
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
Huan Zhang
Affiliation:
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
Furong Sun
Affiliation:
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
Hong Zhou
Affiliation:
Aerochemical Materials Department, The Second Research Institute of Civil Aviation Administration of China, Chengdu 610041, China
Lijuan Zhao*
Affiliation:
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
Yongjiao Song*
Affiliation:
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
*
a)Address all correspondence to these authors. e-mail: lijuan_zhao@sicnu.edu.cn
b)e-mail: 13408030100@163.com
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Abstract

Graphene oxide (GO) is a promising material in improving the corrosion resistance properties of metals. This improvement significantly relies on the microstructure and electrical properties of GO, which nevertheless is rarely studied. Here, multiscale GOs with different flake sizes and oxidation degrees were fabricated and incorporated into waterborne alkyd resin (AR). The physical and chemical structures of GO and AR/GO composites were characterized in detail. Multiscale GOs are successfully prepared, and the corrosion resistance of AR/GO coatings is measured by electrochemical workstation. Electrochemical experiments indicate that GOs with larger flake sizes have excellent barrier properties due to the shielding effect; GOs with appropriate oxidation degrees could effectively improve the dispersion of GO and avoid the conductive path of GO in the matrix, because oxidation degree of GO could influence the dispersion and electrical properties. The corrosion protection efficiency of AR/GO(GO: 120 μm, 1.5 wt%, sp2/sp3 = 2.61) is 98.14%, which is 2.26 times higher than AR. The multiscale effects of GO on the corrosion resistance property of AR coatings are quite general, thus providing guidelines for developing highly efficient corrosion resistant coatings for practical usage.

Keywords

corrosioncoatingbarrier layer
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 6 , 28 March 2019 , pp. 950 - 958
Copyright
Copyright © Materials Research Society 2019 

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