Hostname: page-component-848d4c4894-hfldf Total loading time: 0 Render date: 2024-05-31T02:22:00.568Z Has data issue: false hasContentIssue false

The Effect of Collimation On Sputtered Alcusi and Almg Microstructures And Electromigration Failure Characteristics

Published online by Cambridge University Press:  21 February 2011

Thomas J. Licata
Affiliation:
IBM Technology Products: Hopewell Junction, NY 12533
Timothy D. Sullivan
Affiliation:
Essex Junction, VT 05452
Roy S. Bass
Affiliation:
Rensselaer Polytechnic Institute, Department of Materials Science, Troy, NY 12180
James G. Ryan
Affiliation:
IBM Technology Products: Hopewell Junction, NY 12533
David B. Knorr
Affiliation:
IBM Technology Products: Hopewell Junction, NY 12533
Get access

Abstract

Increasing circuit densities produce higher metal wiring aspect ratios, and more difficult feature fill for damascene processing. One method of extending the use of sputter deposition to challenging aspect ratios is to collimate the sputtered flux using a collimator plate, and to avoid randomizing the collimated flux by using low process pressures corresponding to long sputtered atom mean free paths. In this paper, we discuss our fabrication of damascene AI-0.5Cu-2Si and AI-2Mg wiring using both collimated and uncollimated sputtering, and our observations of collimation-induced changes in Al alloy electromigration and microstructure. Our experiments show that collimation has only a small effect on AlCuSi, but a large effect on AIMg. Specifically, the median time to electromigration failure for collimated AIMg was ∼10X the value for uncollimated AlMg and ∼6X the values for collimated and uncollimated AlCuSi. Transmission electron microscope and x-ray diffraction analyses of these films show that the collimation-induced improvement in AIMg t50 is associated with the formation of smaller, lower strain grains which are clustered in very well-oriented (111) domains. We propose that the advantageous AlMg microstructure results from enhanced texture produced by aspects of the collimated deposition active in the absence of incoherent precipitates.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Thornton, J. A., J. Vac. Sci. Technol. 11, 666 (1974).Google Scholar
2. Thornton, J. A., J. Vac. Sci. Technol. 12, 830 (1975).Google Scholar
3. Greene, J. E. and Eltoukhy, A. H., Surface and Interface Analysis 3, 34 (1981).Google Scholar
4. Greene, J. E. and Barnett, S. A., J. Vac. Sci. Technol. 21, 285 (1982).Google Scholar
5. Thornton, J. A., J. Vac. Sci. Technol. A4, 3059 (1986).Google Scholar
6. Roehl, S., Camiletti, L., Cote, W., Cote, D., Eckstein, E., Froehner, K. H., Lee, P. I., Restaino, D., Roeska, G., Vynorius, V., Wolff, S. and Vollmer, B., 1992 VMIC Proceedings, p. 22.Google Scholar
7. Vollmer, B., Licata, T. J., Restaino, D. D. and Ryan, J. G., to be published in Thin Solid Films (ICMCTF, San Diego, CA 1993).Google Scholar
8. Mikalsen, D. J. and Rossnagel, S. M., US Patent No. 4,824,544, April 25, 1989.Google Scholar
9. Rossnagel, S. M., Mikalsen, D., Kinoshita, H. and Cuomo, J. J., J. Vac. Sci. Technol. A9, 261 (1991).Google Scholar
10. Hoffman, Vance, Varian Associates (private communication).Google Scholar
11. Dennison, D. R. and Hartsough, L. D., J. Vac. Sci. Technol. 17, 1326 (1980).Google Scholar
12. Sanchez, J. E. Jr., McKnelly, L. T. and Morris, J. W. Jr., J. Elec. Mater. 19, 1213 (1990).Google Scholar
13. Shimamura, H., Yajima, A., Yoneoka, Y. and Kobayashi, S., J. Vac. Sci. Technol. A9, 595 (1991).CrossRefGoogle Scholar
14. d'Heurle, F. M., Gangulee, A., Aliotta, C. F. and Ranieri, V. A., J. Elec. Mater. 4, 497 (1975).Google Scholar
15. Attardo, M. J. and Rosenberg, R., J. Appl. Phys. 41,2381 (1970).Google Scholar
16. Knorr, D. B., in Materials Reliability Issues in Microelectronics III, edited by Rodbell, K. P., Filter, W. F., Frost, H. and Ho, P. S. (Mater. Res. Soc. Proc. 309, Pittsburgh, PA, 1993) these proceedings.Google Scholar
17. Schultz, L. G., J. Appl. Phys. 20, 1030 (1949).Google Scholar
18. Knorr, D. B. and Rodbell, K. P., to be published in Submicron Metallization: The Challenges. Opportunities and Limitations, (SPIE, Redmond, WA 1993).Google Scholar
19. Hansen, M., Constitution of Binary Alloys, 2nd ed. (McGraw-Hill Book Company, New York, 1958), pp. 105, 132.Google Scholar
20. McCaldin, J. O. and Sankur, H., Appl. Phys. Lett. 19, 524 (1971).CrossRefGoogle Scholar