Hostname: page-component-848d4c4894-xfwgj Total loading time: 0 Render date: 2024-06-15T16:04:29.221Z Has data issue: false hasContentIssue false

Modelling of Copper Precipitation in Fe-Cu Alloys Under Irradiation

Published online by Cambridge University Press:  21 March 2011

Alexander V. Barashev
Affiliation:
Materials Science and Engineering, Department of Engineering, The University of Liverpool, Brownlow Hill, Liverpool, L69 3GH, UK
Stanislav I. Golubov
Affiliation:
Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong
David J. Bacon
Affiliation:
Materials Science and Engineering, Department of Engineering, The University of Liverpool, Brownlow Hill, Liverpool, L69 3GH, UK
Get access

Abstract

Precipitation of copper-rich clusters is a major cause of in-service hardening of reactor pressure vessel steels and has attracted much attention. Experimental studies of microstructural changes in alloys under various conditions have revealed similarities and differences. It has been established that under ageing the precipitate ensemble experiences normal nucleation, growth and Ostwald ripening, a distinguishing feature of which is the bcc-9R-3R-fcc transformations the precipitates undergo during growth. The main effect of electron irradiation is believed to be enhancement of the diffusion of copper and hence acceleration of the kinetics. In the case of neutron irradiation, however, there are many aspects that are not clear. One is that at temperatures less than about 300°C the precipitate size is observed to be very small (∼1-3 nm), i.e. the coarsening rate is very low. In this paper we study this phenomenon by computer simulations based on the “mean-field” approach for describing microstructural evolution.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Odette, G.R., Scripta Metallurgica, 17, 1183 (1983).Google Scholar
2. Mathon, M.H., Barbu, A., Dunstetter, F., Maury, F., Lorenzelli, N. and Novion, C.H. de, J. Nucl. Mater., 245, 224 (1997).Google Scholar
3. Golubov, S.I., Osetsky, Yu.N., Serra, A. and Barashev, A.V., J. Nucl. Mater., 226, 252 (1995).Google Scholar
4. Golubov, S.I., Serra, A., Osetsky, Yu.N. and Barashev, A.V., J. Nucl. Mater., 277, 113 (2000).Google Scholar
5. Buswell, J.T., English, C.A., Hetherington, M.G., Phythian, W.J., Smith, G.D.W. and Worral, G.M., in Effects of Radiation on Materials, ASTM STP 1046, 11, 127 (1990).Google Scholar
6. Othen, P.J., Jenkins, M.L., Smith, G.D.W. and Phythian, W.J., Phil. Mag. Lett., 64, 383 (1991).Google Scholar
7. Monzen, R., Jenkins, M.L. and Sutton, A.P., Phil. Mag. A, 80, 711 (2000).Google Scholar
8. Nicol, A.C., Jenkins, M.L. and Kirk, M.A., in Microstructural Processes in Irradiated Materials, edited by Zinkle, S.J., Lucas, G.E., Ewing, R.C. and Williams, J.S., (Mat. Res. Soc. Symp. Proc. 540, Warrendale, Pennsylvania, 1999) pp.409414.Google Scholar
9. Nicol, A.C., Jenkins, M.L., Wanderka, N. and Abromeit, C., in Microstructural Processes in Irradiated Materials, edited by Zinkle, S.J., Lucas, G.E., Ewing, R.C. and Williams, J.S., (Mat. Res. Soc. Symp. Proc. 540, Warrendale, Pennsylvania, 1999) pp.457462.Google Scholar
10. Osetsky, Yu.N. and Serra, A., Phil. Mag. A, 75, 1097 (1997).Google Scholar
11. Stoop, P.M., Merwe, J.H. van der, Sciflet, C.J. and Johnson, R.A., Surface Review and Letters, 4, 1279 (1997).Google Scholar
12. Blackstock, J.J. and Ackland, G.J., Phil. Mag. A (in press).Google Scholar
13. Buswell, J.T., Bischler, P.J.E., Fenton, S.T., Ward, A.E. and Phythian, W.J., J. Nucl. Mater., 205, 198 (1993).Google Scholar
14. Anand, M.S. and Agarwala, R.P., J. Appl. Phys., 37, 4248 (1966).Google Scholar
15. Singh, B.N., Golubov, S.I., Trinkaus, H., Serra, A., Osetsky, Yu.N. and Barashev, A.V., J. Nucl. Mater., 251, 107 (1997).Google Scholar
16. Golubov, S.I., Ovcharenko, A.M., Barashev, A.V. and Singh, B.N., Phil. Mag. A (in press).Google Scholar
17. Schultz, H., Landolt-Börnstein Series Group III, 25, ed. Ullmaier, H. (Berlin: Springer, 1991).Google Scholar
18. Bacon, D.J., Gao, F. and Yu.N. Osetsky, J. Nucl. Mater., 276, 1 (2000).Google Scholar
19. Auger, P., Pareige, P., Welzel, S. and Van Duysen, J.-C., J. Nucl. Mater., 280, 331 (2000).Google Scholar
20. Golubov, S.I., Barashev, A.V. and Ovcharenko, A.M., IPPE Report-9592, Obninsk, (1997).Google Scholar
21. Trinkaus, H., Singh, B.N. and Foreman, A.J.E., J. Nucl. Mater., 199, 1 (1992).Google Scholar