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Pd/Ge Contacts to n-TYPE InP

Published online by Cambridge University Press:  22 February 2011

Ping Jian
Affiliation:
Department of Mining, Metallurgical and Petroleum Engineering, University of Alberta, Edmonton, Alberta, Canada, T6G 2G6
Douglas G. Ivey
Affiliation:
Department of Mining, Metallurgical and Petroleum Engineering, University of Alberta, Edmonton, Alberta, Canada, T6G 2G6
Robert Bruce
Affiliation:
Bell Northern Research, Ltd., P.O. Box 3511, Station C, Ottawa, Ontario, Canada, K1Y 4H7
Gordon Knight
Affiliation:
Bell Northern Research, Ltd., P.O. Box 3511, Station C, Ottawa, Ontario, Canada, K1Y 4H7
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Abstract

Multilayer metallizations of Pd/Ge/Pd, with different thickness ratios of Ge and Pd, were deposited onto n-type InP by means of electron beam evaporation. The specimens were then annealed in flowing N2 gas at temperatures ranging from 250 to 425°C for various times. Transmission electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDX) and electron diffraction were used to identify the phase changes during reaction. The four point probe method was used for electrical resistance measurements. A Pd-In-P amorphous phase and a Pd2Ge compound formed during deposition. Subsequent annealing resulted in crystallization of the amorphous phase followed by epitaxial growth of Pd2InP(II) on InP at 350°C. At 425°C, Pd2InP(II) with Ge in solution, decomposed producing a contact with a lower specific contact resistance. The lowest contact resistances achieved were ∼10−5 Ωcm2. Further annealing led to more decomposition of InP, including presumably the Ge doped InP surface region, which corresponded to an increase in contact resistance.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

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