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Second Harmonic Generation from Multilayers of Oriented Metal Bisphosphonates

Published online by Cambridge University Press:  15 February 2011

Grace Ann Neff ,
Timothy M. Mahon ,
Travis A. Abshere  and
Catherine J. Page
Grace Ann Neff
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
Timothy M. Mahon
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
Travis A. Abshere
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
Catherine J. Page
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
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Abstract

Second order nonlinear optical properties (NLO) require the presence of a polarizable moiety situated in an anharmonic potential. Our approach to incorporating such properties into self-assembled multilayers involves use of asymmetric α,ω bisphosphonates which meet this requirement by virtue of their chemical structure and binding properties. We have developed and optimized protection and deprotection schemes to allow for oriented layering of these molecules. Characterization by optical ellipsometry and grazing angle X-ray diffraction provides insight on average layer thicknesses and bulk film densities. Second harmonic generation (SHG) intensity from the bulk film is measured to verify NLO activity.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 661
Copyright
Copyright © Materials Research Society 1996

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References

1. Netzer, L., Sagiv, J., J. Am. Chem. Soc., 105, 674 (1983).Google Scholar
2. Maoz, R., Netzer, L., Gun, J., Sagiv, J., J. Chem. Phys., 85, 1059 (1988).Google Scholar
3. Tillman, N., Ulman, A., Penner, T.L., Langmuir, 5, 101 (1989).Google Scholar
4. Li, D., Ratner, M.A., Marks, T.J., Zhang, C., Yang, J., Wong, G. J., J. Am. Chem. Soc., 112, 7389 (1990).Google Scholar
5. Lee, H., Kepley, L.J., Hong, H.-G., Mallouk, T.E., J. Am. Chem. Soc., 110, 618 (1988).Google Scholar
6. Lee, H., Kepley, L.J., Hong, H.-G., Akhter, S., Mallouk, T.E., J. Phys. Chem., 92, 2597 (1988).Google Scholar
7. Katz, H.E., Scheller, G., Putvinski, T.M., Schilling, M.L., Wilson, W.L., C.E.D. Chidsey, Science, 254, 1485 (1991).Google Scholar
8. Yang, H.C., Aoki, K., Hong, H., Sackett, D.D., Rendt, M.F., Yau, S., Bell, C.M., and Mallouk, T.E., J. Am. Chem. Soc., 115, 11855 (1993).Google Scholar
9. Vermuelen, L.A., Snover, J.L., Sapochak, L.S., Thompson, M.E., J. Am. Chem. Soc., 115, 11767 (1993).Google Scholar
10. Katz, H.E., Chem. Mater., 6, 2227, (1994).Google Scholar
11. Zeppenfeld, A.C., Fiddler, S.L., Ham, W.K., Klopfenstein, B.J., Page, C.J., J. Am. Chem. Soc., 116, 9158 (1994).Google Scholar
12. Zeppenfeld, A.C., Page, C. J., Mater. Res. Soc. Symp. Proc. 351, 77 (1994), Molecularly Designed Ultrafine/Nanostructured Materials, Gonsalves, K.E., Chow, G.-M., Xiao, T.D., Cammarata, R.C., Editors, Materials Research Society, Pittsburgh, PA. Google Scholar
13. Neff, G.A., Zeppenfeld, A.C., Klopfenstein, B.J., Page, C. J., Mater. Res. Soc. Symp. Proc., 351, 269 (1994), Molecularly Designed Ultrafine/Nanostructured Materials, Gonsalves, K.E., Chow, G.-M., Xiao, T.D., Cammarata, R.C., Editors, Materials Research Society, Pittsburgh, PA.Google Scholar
14. O'Brien, J.T., Zeppenfeld, A.C., Richmond, G.L., Page, C.J., Langmuir, 10, 4657 (1994).Google Scholar
15. Neff, G.A., Page, C.J., Meintjes, E., Tsuda, T., Pilgrim, W.-C., Roberts, N., Warren, W.W. Jr., Langmuir, 12, 238 (1996).Google Scholar
16. Ansell, M.A., Cogan, E.B., Neff, G.A., Page, C.J., submitted to Supramolecular Science.Google Scholar
17. Ansell, M.A., Zeppenfeld, A.C., Ham, W.K., Page, C.J., Mater. Res. Soc. Symp. Proc., 351, 171 (1994), Materials Research Society, Pittsburgh, PA.Google Scholar
18. Ansell, M.A., Zeppenfeld, A.C., Yoshimoto, K., Cogan, E.B., Page, C.J., Chem. Mater., 8, 591 (1996).Google Scholar
19. Dines, M.B., DiGiacomo, P.M., Inorg. Chem., 20, 92 (1981).Google Scholar
20. Cao, G., Hong, H.-G., Mallouk, T.E., Acc. Chem. Res., 25, 420 (1992).Google Scholar
21. Engel, R.E., Synthesis of Carbon-Phosphorus Bonds, CRC Press, Boca Raton, FL, p.21 (1988).Google Scholar
22. Unpublished results.Google Scholar