New results of radiocarbon concentration in tree rings from the Kraków region covering a growth period of 20 yr have been analyzed, and the relationship between them and 14C concentrations in the atmospheric CO2 are described. This enabled assessment of the uptake period for pine trees at the regional climatic conditions. Both sets of data show lower 14C concentrations than reported for “clean air” at the reference station, indicating a remarkable input of “dead” CO2 of fossil fuel origin. Using data of carbon dioxide and 14C concentrations from Schauinsland, summer values of the fossil component (Cf) in carbon dioxide were calculated for the Kraków area. Fitting exponential and linear functions to experimental data, the exchange time was calculated, and expected future 14C concentration in the atmosphere was estimated.

Given the non-monotonic form of the radiocarbon calibration curve, the precision of single 14C dates on the calendar timescale will always be limited. One way around this limitation is through comparison of time-series, which should exhibit the same irregular patterning as the calibration curve. This approach can be employed most directly in the case of wood samples with many years growth present (but not able to be dated by dendrochronology), where the tree-ring series of unknown date can be compared against the similarly constructed 14C calibration curve built from known-age wood. This process of curve-fitting has come to be called “wiggle-matching.”

In this paper, we look at the requirements for getting good precision by this method: sequence length, sampling frequency, and measurement precision. We also look at 3 case studies: one a piece of wood which has been independently dendrochronologically dated, and two others of unknown age relating to archaeological activity at Silchester, UK (Roman) and Miletos, Anatolia (relating to the volcanic eruption at Thera).

Annual tree rings from Thailand were analyzed by radiocarbon AMS for AD 1938–1954. The results showed no significant depletion in atmospheric 14C over Thailand during the pre-bomb period, even though the air mass to Thailand during the growing season of tree rings is transported over a potentially significant source of oceanic 14C-depleted CO2, out-gassing in the northern Indian Ocean. When compared with Washington and Chile for different periods from the 17th century to AD 1954, Thailand appears to have the characteristics of Southern Hemisphere 14C. This supports our previous finding that Thailand was strongly influenced by the entrainment of Southern Hemisphere air parcels in the southwest Asian monsoon (Hua et al. 2004). For Thailand, this effect is much stronger than the reduction of atmospheric 14C in association with CO2 out-gassing in the northern Indian Ocean.

The abrupt millennial-scale changes associated with the Younger Dryas (YD) event (“chronozone”) near the dawn of the Holocene are at least hemispheric, if not global, in extent. Evidence for the YD cold excursion is abundant in Europe but fairly meager in central North America. We are engaged in an investigation of high-resolution environmental changes in mid-North America over several millennia (about 10,000 to 14,000 BP) during the Late Glacial–Early Holocene transition, including the YD interval. Several sites containing logs or stumps have been identified and we are in the process of initial sampling or re-sampling them for this project. Here, we report on a site in central Illinois containing a deposit of logs initially thought to be of YD age preserved in alluvial sands. The assemblage of wood represents hardwood (angiosperm) trees, and the ring-width characteristics are favorable to developing formal tree-ring chronologies. However, 4 new radiocarbon dates indicate deposition of wood may have taken place over at least 8000 14C yr (6000–14,000 BP). This complicates the effort to develop a single floating chronology of several hundred years at this site, but it may provide wood from a restricted region over a long period of time from which to develop a sequence of floating chronologies, the timing of deposition and preservation of which could be related to paleoclimatic events and conditions.

Two independent 14C data sets of 10 tree-ring samples from the longest master chronology of the Pazyryk cultural complex were obtained and wiggle-matched to the absolute timescale. The results show very good agreement, within 10–15 calendar yr. The Ulandryk-4 burial ground (mound 1) was dated to about 320–310 cal BC, and this is consistent with wiggle-matching of the Pazyryk burial ground date series.

We have measured the radiocarbon concentrations in single-yr tree rings of old wood by accelerated mass spectrometry (AMS) using a multicathode. The 14C concentrations of 10 single-yr tree rings were measured in 100 tree rings at intervals of 10. For each single-yr tree-ring sample, typically 80 measurements of the 14C concentrations were carried out using multicathodes. The sample standard deviations indicated that there are other fluctuations of typically 1.5%, in addition to the fluctuation of the Poisson counting statistics which is typically 3% for each measurement. The average 14C date of the tree rings was 22,130 ± 306 BP for all 624 data of single-yr tree-ring samples measured by the multicathodes. From the calibration data of Lake Suigetsu, the calendar dates of these 100 tree rings were located between 25,400 cal BP and 26,150 cal BP. The 14C dates changed between 21,979 BP and 22,272 BP, with an error of approximately 50 BP, corresponding to a precision of approximately 0.5%. There was a step with a change of approximately 144 BP for each 10 yr in the time profile.

Often it is not possible to date a sample of wood from the final growth ring of the tree from which it came. In these cases, an “old-wood offset” is apparent. A number of quantitative approaches for the assessment of this offset are available, dependent on the actual tree rings that have been dated. A range of examples are given, demonstrating how such radiocarbon measurements can be interpreted using additional information from archaeology and dendrochronology.

This paper presents the variation of radiocarbon content in annual tree rings for the period AD 1413–1553, which includes the Spoerer Minimum period (AD 1415–1534). Since the variation of the production rate of 14C is strongly related to solar activity, the variation of 14C content in annual tree rings gives us information on the characteristics of variation of solar activity. We have studied solar activity during the grand solar minima, focusing especially on the stability of the 11-yr cycle. The minima are determined to have been almost free of sunspots. Our results, however, have revealed quite remarkably the existence of the 11-yr cycle for most of the time during the Spoerer Minimum. The 11-yr variation weakened around AD 1460–1510, suggesting that solar activity might have been strongly suppressed during these 50 yr.

High-precision radiocarbon accelerator mass spectrometry (AMS) measurements of a new high-altitude stone-pine tree-ring chronology from the European Alps were performed for a 500-yr stretch in the second half of the 4th millennium BC. A 14C calibration curve with a typical 1-σ uncertainty of about 20 14C yr was achieved. Although the general agreement of our data set with INTCAL98 is very good (confirming once more that INTCAL98 is also proper for calibration of samples of extraordinary sites), we found small deviations of 17 ± 5 14C yr, indicating possible seasonal effects of the delayed growing season at high altitude.

A Bayesian multiple-frequency model has been developed for spectral analysis of data with unknown correlated noise. A description of the model is given and the method is applied to decadal atmospheric INTCAL98 Δ14C data. The noise of the INTCAL98 data is found to be red, and there seems to be no support for continuous harmonic frequencies in the data.

Least-squares fitted smooth curves to radiocarbon versus tree-ring calibration data for the period AD 1140 to 1950 are compared with climatic warming and cooling of the North Atlantic (Little Ice Age), and with recorded sunspot numbers over the period AD 1670 to 1950.

Calibration curves from different parts of the globe are not identical, and appear to be determined by a combination of variable solar activity and variable oceanic upwelling of 14C-depleted water, with the variable upwelling itself partly determined by solar activity.

The influence of the calibration curve on the statistical inference of time intervals was investigated. For this purpose, the calculation of the summed probability density function was used. Computer simulations were done for batches of 11 samples, each time uniformly covering 200-yr time intervals. The results show that the calibration curve causes the summed probability density function of a group to cover a wider interval than the real-time interval of the phenomenon. Moreover, the estimated time interval may be often shifted in relation to the real-time interval.

ΔR results of known-age shells from the Solomon and Coral Seas and the northwest coast of New Ireland are presented. The results are too few to be conclusive but indicate that ΔR in this region is variable. An average ΔR value of 370 ± 25 yr is recorded for a range of shell species from Kavieng Harbor, New Ireland, and is primarily attributed to weak equatorial upwelling of depleted 14C due to seasonal current reversals. In contrast, values from the Solomon and Coral Seas are lower (average ΔR = 45 ± 19 yr). Higher ΔR values for some shellfish from these 2 seas is attributed to ingestion of 14C-depleted sediment by deposit-feeding species.