This paper presents an updated radiocarbon chronology of the earliest pottery sites in the Old World. Ceramic production originated in the Late Glacial period in several regions of East Asia—the Japanese Islands, the Russian Far East, and southern China—at approximately the same time, about 13,700–13,300 BP (about 17,200–14,900 cal BP).

A chronological framework for the prehistoric cultural complexes of Sakhalin Island is presented based on 160 radiocarbon dates from 74 sites. The earliest 14C-dated site, Ogonki 5, corresponds to the Upper Paleolithic, about 19,500–17,800 BP. According to the 14C data, since about 8800 BP, there is a continuous sequence of Neolithic, Early Iron Age, and Medieval complexes. The Neolithic existed during approximately 8800–2800 BP. Transitional Neolithic-Early Iron Age complexes are dated to about 2800–2300 BP. The Early Iron Age may be dated to about 2500–1300 BP. The Middle Ages period is dated to approximately 1300–300 BP (VII–XVII centuries AD).

Eleven woolly mammoth bone samples from Lugovskoe (central West Siberian Plain, Russia) were radiocarbon dated in 3 laboratories: Institute of Geology, Novosibirsk; Oxford University, Oxford; and Christian Albrechts University, Kiel. Each laboratory used its own protocol for collagen extraction. Parallel dating was carried out on 3 samples in Novosibirsk and Oxford. Two results are in good agreement. However, there is a major discrepancy between 2 dates obtained for the third sample. The dates obtained so far on the Lugovskoe mammoths range from about 18,250 BP to about 10,210 BP. The Lugovskoe results thus far confirm the possibility of woolly mammoth survival south of Arctic Siberia in the Late Glacial after about 12,000 BP, which has important implications for interpreting the process of mammoth extinction. The site has also produced the first reliable traces of human occupation from central Western Siberia at the Late Glacial, including unique direct evidence of mammoth hunting.

A kohitsugire is a paper fragment from an old manuscript written mainly in the Heian and Kamakura periods. Although they contain significant information for historical, literary, and paleographical study, because of their antique handwriting and description of historical incidents, there are many copies and counterfeits written several centuries later. In this study, radiocarbon ages of kohitsugire were measured by accelerator mass spectrometry (AMS). On the kohitsugire attributed to the famous calligraphists in the Kamakura period (Fujiwara no Sadaie and Prince Munetaka), 14C dating indicated that they were not genuine and should be excluded from the materials for study of the calligraphists. Calibrated 14C ages of the kohitsugire attributed to Fujiwara no Yukinari indicated the middle Heian period. This calligraphy was written on Tobikumogami paper, which has a billowing cloud pattern decorated with indigo-blue-dyed fiber. Although it was commonly accepted that the Tobikumogami is peculiar to the middle 11th to early 12th century, the results from 14C dating also suggested that the origin of the Tobikumogami would date back to the last of the 10th or the early 11th century, when Fujiwara no Yukinari flourished as a calligraphist. Calibrated 14C ages of the kohitsugire attributed to Nijo Tameuji and Reizei Tamesuke showed that they are fragments of old manuscripts describing lost tales and were written in the 13th–14th century. Consequently, 14C dating clarified the existence of ancient tales which had been unknown and indicated their worth as a material for the study of classical Japanese literature.

The Neolithic site of Schletz in Lower Austria comprises a fortified settlement from the end of the Linearbandkeramik (LBK) culture. Large numbers of human bones were found at the base of the fortification ditches, and many of the excavated bones and skulls showed evidence of trauma which most likely originates from violence. This remarkable deposit of human remains has been considered evidence for an abrupt end to the Early Neolithic settlement at Schletz. In order to investigate this interpretation, radiocarbon accelerator mass spectrometry (AMS) measurements of human bone samples from this site were performed at VERA. The χ2 test of the results from specimens with clearly identified lesions suggests that these may be contemporaneous. Further, it may be concluded that all individuals with evidence of trauma from Schletz were probably the victims of a single event: a massacre at the end of the LBK.

Similar evidence is found at Early Neolithic sites at Talheim and Herxheim in the western part of Germany. Analysis of the 14C ages of bones from both sites suggests that the Talheim event may have been coeval with the massacre of Schletz, whereas an event at Herxheim might have happened some time earlier. For Herxheim, the massacre theory is still under discussion, and a change in the burial rite is also considered as an alternative interpretation.

The dating of the settlement of Iceland has been debated for many years. According to written sources (sagas) from the early 12th century, the first Norwegian settlers arrived in Iceland in AD 874. However, some 14C dates from the earliest archaeological sites in Iceland, invariably from samples of birch and other indigenous wood species, have yielded surprisingly old ages, older by 100–150 yr than the historical date, suggesting that the settlement took place in the 7th or 8th century. In this paper, we report 16 new 14C dates of pairs of barley grain and wood samples from an excavation in Reykjavík in 2001. The new results show that the wood samples tend to be older than the grain samples by up to about 100 yr. We argue that the barley grains give the true date (AD 890), whereas the wood dates are too old. The grain dates are in close agreement with the settlement year quoted in the written sources. In particular, our new data eliminate the need of any of the ad hoc theories introduced up to now to explain the suspiciously high 14C ages of wood samples from the settlement of Iceland, namely, 1) the island effect, 2) the volcanic or geothermal effect, or 3) that settlement actually took place significantly before the time recorded in the sagas.

The largest volcanic crater on Easter Island in the South Pacific contains a lake 1 km in diameter with large floating mats of vegetation, mainly Scirpus californicus. A core taken through a mat near the center produced anomalous dates, with older dates above younger ones. The possibility that the mat had become inverted was considered, but palynological evidence refutes this idea because it shows a progressive upward decline of forest pollen, which is well known from other swamp cores on the island. A new series of radiocarbon dates made directly on pollen concentrates was obtained. These dates also produced inconsistencies, particularly when pollen concentrate ages were compared with 14C ages on plant fragments from the same depth. This series of 14C ages seems to indicate that both old and young organic components in the sediment are deposited contiguously and that the depositional history of these cores is more complex than previously known. Previous age determinations on bulk sediments from Easter Island, which also show anomalous dates, may be too simplistic. This paper provides a warning to other researchers dating sediments from Easter Island. We suggest that sample selection and dating procedures be carefully considered for these sediments.

A technique of accelerator mass spectrometry (AMS) has made it possible to directly measure radiocarbon ages of pottery by isolating organic materials sealed in the pottery when the pottery was formed. We analyzed the carbon contents and 14C ages for “black pottery” from the Philippines and “fiber pottery” from Japan using the relevant carbonaceous materials extracted from the pottery samples, i.e., adhered chaff or grass fibers that were incorporated in the pottery matrix, respectively. The carbon yield of the pottery sample varied largely depending on the pottery types, the preservation conditions, as well as the chemical pretreatment methods to purify carbonaceous materials for 14C dating. We will discuss criteria for sample selection of well-preserved pottery, and a modified method, instead of the standard alkali treatment, to obtain sufficient material for precise 14C dating.

We investigated Csípo-halom, one of the kurgans that served as a burial place in the Hortobágy area of the Hungarian Great Plain. For pedological description and other studies of the protected mound and its surroundings, only a few monitoring drillings were permitted to get soil samples. On the basis of morphological and visual studies, the structure and layers of the mound were reconstructed. The Laboratory of Environmental Studies of the Institute of Nuclear Research at the Hungarian Academy of Sciences (INR/HAS) performed radiocarbon measurements of soil samples, applying a bulk combustion pretreatment method. The measured 14C ages of soil samples from reference points, such as the top layer of the mound, the center of mound body, the base layer of the mound, the near surroundings, and the distant surroundings, are in good agreement with the preliminary archaeological concept for this field and give substantial information about the rate of soil generation processes in this area.

This study estimates the maximum and minimum degrees of autocompaction for radiocarbon-dated Holocene mangrove sediments in Singapore, in order to correct apparent sediment accretion rates for the effects of sediment compression due to autocompaction. Relationships developed for a suite of modern (surface) sediment samples between bulk density, particle-size distribution, and organic matter content were used to estimate the initial (uncompacted) bulk density of buried and variably compressed Holocene sediments, based on the grain-size distribution and organic matter content of the sediment. The difference between measured (compacted) and initial (uncompacted) bulk density of each buried sediment interval can be interpreted as the amount of length shortening experienced by each interval since burial. This allows the elevation of samples selected for 14C dating to be corrected for the effects of autocompaction of the underlying sediment sequence, so that accurate estimates of vertical sediment accretion rates can be calculated.

The 3 Holocene mangrove sequences analyzed and dated for this study ranged in age from 2000 to 8500 cal BP. The effects of autocompaction are significant, even in comparatively thin sequences, with subsidence of up to 56 cm calculated for carbon-dated samples presently 2 m above incompressible basement. The vertical sediment accretion rates for these mangrove sequences ranged from 0.99 to 6.84 mm/yr and carbon sequestration rates ranged from 0.9 to 1.7 t/ha/yr, all within the range observed for comparable Holocene and modern mangrove sediments elsewhere.

Radiocarbon age determinations and stratigraphy suggest that the deposits in Black Creek Swamp on Kangaroo Island record 3 phases of deposition and associated soil development which spanned at least the last 20,000 yr. Four new 14C age determinations on bulk soil organic matter and their stratigraphic context are presented in this paper. Three of these age determinations (FP6: 15,687 ± 110 BP [WK11487]; FP7: 16,326 ± 385 BP [WK11488]; and FP8: 17,618 ± 447 BP [WK11489]), are from the organic-rich fossil layer located 45–75 cm below the current floodplain surface. The fourth, a much younger date, FP5: 5589 ± 259 BP (WK11486), was obtained from the base of the overlying modern soil. The dates for the fossil layer increase systematically with depth and correlate well with 5 previous 14C dates (Hope et al., unpublished), ranging between 15,040 ± 120 BP and 19,000 ± 310 BP. This suggests that the data set represents a possible minimum age of the bulk organic matter, and considering the high organic matter contents of approximately 8%, has implications for the age of the megafauna buried in this layer. The overlying modern soil, with its much younger date, contains lower levels of organic matter (3–7%) and gastropods not seen in the fossil layer. This suggests a substantial change in environmental conditions probably due to an alteration in the floodplain drainage conditions. This chronological and sedimentalogical discontinuity indicates that 2 distinct depositional regimes existed and were separated by up to 10,000 14C yr. A calcareous, sandy silt deposit underlying the fossil layer is a calcarenite deposit with low total organic content and is considered the base of the section; it suggests a third separate depositional episode. As such, the Black Creek Swamp in the southwest corner of Kangaroo Island formed intermittently over at least the last 20,000 yr during 3 distinct depositional phases, one of which was the formation of the fossil-laden, organic-rich floodplain surface, which has a possible minimum age of approximately 15,000 to 19,000 BP.

Concentrations of organic carbon, carbon isotopes (13C and 14C), atmospheric 10Be in soil, and in situ 10Be in bedrock and weathering rock were determined in a study of a profile of a grassland slope at the Heshan Hilly Land Interdisciplinary Experimental Station, Chinese Academy of Sciences, in Guangdong Province, China. A good linear relationship between depth and the 14C apparent age of the organic carbon demonstrates that the rock weathering process and the accumulation process of organic matter in the slope are relatively stable. Both 14C and 10Be results show that about 34% of soil in the grassland slope has been eroded during the past 3800 yr. The 10Be results for interstitial soil from weathered rocks show that the 90-cm-thick weathering rock layer above the bedrock has evolved over a period of 1.36 Myr. The concentrations of in situ 10Be in the weathered rock and bedrock are 10.7 × 104 atoms/g and 8.31 × 104 atoms/g, respectively. The weathering rate of the bedrock, equivalent to the soil production rate, was estimated at 8.8 × 10-4 cm/yr, and the exposure ages of the weathered rock and the bedrock were 72 kyr and 230 kyr, respectively.

Sub-fossil sections from a Florida wetland were accelerator mass spectrometry (AMS) dated and the sedimentological conditions were determined. 14C data were calibrated using a combined wiggle-match and 14C bomb-pulse approach. Repeatable results were obtained providing accurate peat chronologies for the last 130 calendar yr. Assessment of the different errors involved led to age models with 3–5 yr precision. This allows direct calibration of paleoenvironmental proxies with meteorological data. The time frame in which 14C dating is commonly applied can possibly be extended to include the 20th century.

Radiocarbon measurements of different lipid fractions and individual compounds, isolated from soil samples collected on 2 different agricultural long-term study sites, located in the rural area of Rotthalmünster (Germany) and in the city of Halle/Saale (Germany), were analyzed to obtain information about sources and the stability of soil organic matter (SOM). Different lipid compound classes were isolated by automated solvent extraction and subsequent medium-pressure liquid chromatography. Generally, 14C contents of lipid compound classes from topsoil samples of maize plots at Rotthalmünster are close to the modern atmospheric 14C content. Lower 14C values of aliphatic and aromatic hydrocarbons isolated from neutral lipids suggest a contribution of old carbon to these fractions. In contrast, 14C values of bulk soil (52 pMC) as well as isolated lipid classes from Halle are highly depleted. This can be attributed to a significant contribution of fossil carbon at this site. Extremely low 14C contents of aromatic (7 pMC) and aliphatic hydrocarbons (19 pMC) reflect the admixture of fossil hydrocarbons at the Halle site. Individual phospholipid fatty acids (PLFA), which are used as a proxy for viable microbial biomass, were isolated by preparative capillary gas chromatography (PCGC) from topsoils at Rotthalmünster and Halle. PLFA 14C values are close to atmospheric 14C values and, thus, indicate a clear microbial preference for relatively young SOM. At Rotthalmünster, the 14C concentration of short-chain unsaturated PLFAs is not significantly different from that of the atmosphere, while the saturated PLFAs show a contribution of sub-recent SOM extending over the last decades. At Halle, up to 14% fossil carbon is incorporated in PLFAs n-C17:0 and cy-C18:0, which suggests the use of fossil carbon by soil microorganisms. Moreover, it can be concluded that the 14C age of soil carbon is not indicative of its stability.

Radiocarbon enables a distinction between contemporary and fossil carbon, which can be used for the apportionment of biogenic and anthropogenic sources in environmental studies. In order to apply this approach to carbonaceous atmospheric aerosols, it is necessary to adapt pretreatment procedures to the requirements of 14C measurements. In this work, we followed an approach in which total carbon (TC) is subdivided into fractions of different chemical and physical properties. 14C data of ambient aerosols from Zürich (Switzerland) are presented for the 2 sub-fractions of TC, organic carbon (OC) and elemental carbon (EC). Furthermore, OC is separated into water-insoluble OC (WINSOC) and water-soluble OC (WSOC). Results demonstrate the importance to differentiate between these fractions for 14C-deduced source apportionment, as the contributions can range between both extremes, nearly exclusively biogenic and anthropogenic.

The temporal radiocarbon variation (in terms of percent Modern Carbon: pMC) of size-fractionated airborne particulate matter (APM) collected in Tokyo between April 2002 and February 2003 was analyzed in order to get an insight into the sources of carbonaceous particles. Results indicated significant biogenic origins (approximately 40 pMC on average). In general, the seasonal and particle size variations in pMC were relatively small, with 2 exceptions: elevated pMC in coarse particles in April and October 2002, and relatively low pMC in the finest particle size fraction collected in August 2002. The former finding could be tentatively attributed to the abundance of coarse particles of biological origins, such as pollen; the latter might be due to an increased fraction of anthropogenic secondary particles.

Estimation of the magmatic contribution to soil air at Unzen Volcano, SW Japan, was carried out using carbon isotopes, both 14C and 13C, and a mixing model of isotopic mass balance in order to assess the spatial variation of magmatic influence from the volcano. The advantage of using soil air samples is that a wide range of gas sampling sites can be selected. Magmatic CO2 contributed mostly in the eastern region from Unzen Volcano. The high magmatic contribution to soil air appeared along the Akamatsudani fault zone located southeast of the volcano. Our observations across the fault also showed remarkable peaks of CO2 concentration and δ13C values, suggesting that magmatic fluid comes up along the fracture zone as for the normal fault system of the graben.