Hostname: page-component-848d4c4894-x5gtn Total loading time: 0 Render date: 2024-05-16T08:29:08.429Z Has data issue: false hasContentIssue false

X-ray Fluorescence Analysis of Zeolites for the Determination of Silica: Alumina Ratio and Soda: Alumina Ratio

Published online by Cambridge University Press:  06 March 2019

P. A. Gokhale
Affiliation:
Akzo Chemicals Inc. Catalyst Division Pasadena, Texas 77507
M. R. Wuensche
Affiliation:
Akzo Chemicals Inc. Catalyst Division Pasadena, Texas 77507
Get access

Extract

Zeolites-based fluid cracking catalysts are used in petroleum refining. Zeolites are crystalline alumina silicates with a framework based on extensive three-dimensional network of oxygen, and cations which occupy nonframework positions. The distribution of silicon and aluminum atoms within the framework determines many important properties of zeolites, most notably catalytic, absorptive capacity, acidity, stability, etc. For the zeolite scientist, information obtained from the determination of silca:alumina ratio (SAR) and soda:alumina ratio (NAR) during crystallization, dealumination and cationic exchange is important for the optimization of preparative techniques and development of new products.

Type
Research Article
Copyright
Copyright © International Centre for Diffraction Data 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Taro, M. E.; 1987, Development of AAS and ICP method for the analysis of Al, Na and Si in zeolites, Pittsburgh conference abstracts, 278.Google Scholar
2. Taro, M. E., Giampa, V. and Collins, R.; 1989, Dissolution of zeolites for flame AA and ICP analysis, Spectroscopy, 4(2) PP. 1822,Google Scholar
3. Engelhardt, G., Fahlke, B., Lippmma, M. E., Zeolites, 5, 49 (1985).Google Scholar
4. Flanigen E., Khattani, Szymanski, H., Adv. Chem. Series, 1971, PP. 102-201.Google Scholar
5. Breck, D. W., Zeolite Molecular Sieves, Wiley, New York, 1974.Google Scholar
6. Claisse Fluxer, Instruction Manual.Google Scholar
7. Lachance, G., Trail, R., Canadian spectroscopy, March 1966, PP 43-48. Lachance G., Trail R., Canadian spectroscopy, May 1966, PP 63-71.Google Scholar