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Simultaneous Immobilization of Zn(II) and Cr(III) in Spinel Crystals from Beneficial Utilization of Waste Brownfield-Site Soils

Published online by Cambridge University Press:  01 January 2024

Fei Wu ,
Yuanyuan Tang ,
Xingwen Lu ,
Chengshuai Liu ,
Yahui Lv ,
Hui Tong ,
Zengping Ning ,
Changzhong Liao  and
Fangbai Li
Fei Wu
Affiliation:
State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China University of Chinese Academy of Sciences, Beijing 100049, China
Yuanyuan Tang
Affiliation:
School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China
Xingwen Lu
Affiliation:
Research Centre for Environmental Health and Pollution Control, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
Chengshuai Liu*
Affiliation:
State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China
Yahui Lv
Affiliation:
Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China
Hui Tong
Affiliation:
Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China
Zengping Ning
Affiliation:
Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China
Changzhong Liao
Affiliation:
Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China
Fangbai Li
Affiliation:
Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and Management, Guangdong Institute of Eco-Environmental Sciences & Technology, Guangzhou 510650, China
*
*E-mail address of corresponding author: liuchengshuai@vip.gyig.ac.cn
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Abstract

Waste brownfield-site soils contaminated with heavy metals such as Zn and Cr are of critical environmental concern because of the rapid urbanization and industrialization that is occurring in China. Thermal treatment can fix heavy metals in specific mineral structures, which might be a promising technology for remediation and reutilization of the metal-contaminated soils. The objective of the present study was to elucidate the stabilization mechanisms of Zn and Cr through thermal treatment of mixtures of ZnO + Cr2O3 to form ZnCr2O4 and to confirm that Zn and Cr were incorporated simultaneously into the spinel structure. The incorporation efficiency for Zn was quantified, with the value ranging from 70.6 to 100% over the temperature range 700–1300°C. Leaching results further confirmed that ZnCr2O4 spinel was a superior product for Zn and Cr immobilization. Then, by artificially sintering Zn- and Cr-enriched soils, both Zn and Cr were immobilized effectively (with three orders of magnitude reduction in Zn leachability) in the ZnCr2O4 spinel as the predominant product phase. In addition, multiple heavy metals such as Zn, Cu, and Cr in the actual brownfield-site soils were well immobilized after sintering, which confirmed the potential for practical application of the thermal treatment technology utilized in this study.

Keywords

Brownfield site soilsChromiumSimultaneous immobilizationSpinelThermal treatmentZinc
Type
Article
Information
Clays and Clay Minerals , Volume 67 , Issue 4 , August 2019 , pp. 315 - 324
Copyright
Copyright © Clay Minerals Society 2020

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Footnotes

Fei Wu and Yuanyuan Tang contributed equally to this work.

This paper was originally presented during the World Forum on Industrial Minerals, held in Qing Yang, China, October 2018

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