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Chemistry at high pressure: Tuning functional materials properties

Published online by Cambridge University Press:  10 October 2017

Paolo Postorino  and
Lorenzo Malavasi
Paolo Postorino
Affiliation:
Department of Physics, Sapienza Università di Roma, Italy; paolo.postorino@roma1.infn.it
Lorenzo Malavasi
Affiliation:
Department of Chemistry, University of Pavia, Italy; lorenzo.malavasi@unipv.it
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Abstract

High pressure is a fascinating tool to promote and enhance the properties of materials as well as to induce new and exotic phenomena. This is especially of interest for functional materials, which are very sensitive to external pressure (P) and whose features can be tuned and controlled in a rigorous fashion. Through specific examples of the role of applied P on two families of functional compounds based on the perovskite lattice, manganites, and organic–inorganic hybrid perovskites, it is shown that the particular properties of interest can be manipulated by means of pressure. Examples highlight the effects at both the microscopic and macroscopic level, and show how the understanding of P-induced phenomena is essential for the development of materials chemistry design.

Keywords

magnetoresistancephotovoltaicx-ray diffraction (XRD)Raman spectroscopysemiconducting
Type
Research Article
Information
MRS Bulletin , Volume 42 , Issue 10: Materials Under Pressure , October 2017 , pp. 718 - 723
Copyright
Copyright © Materials Research Society 2017 

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