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121Sb Mössbauer Studies On No2SbF6 Intercalated Graphite

Published online by Cambridge University Press:  15 February 2011

P. Boolchand ,
W. Bresser ,
D. Mcdaniel ,
P.C. Eklund ,
D. Billaud  and
J.E. Fischer
P. Boolchand
Affiliation:
University of Cincinnati, Cincinnati, OH 45221
W. Bresser
Affiliation:
University of Cincinnati, Cincinnati, OH 45221
D. Mcdaniel
Affiliation:
University of Cincinnati, Cincinnati, OH 45221
P.C. Eklund
Affiliation:
University of Kentucky, Lexington, KY 40506
D. Billaud
Affiliation:
Université de Nancy, France
J.E. Fischer
Affiliation:
University of Pennsylvania, Philadelphia, PA 19104
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Abstract

We have examined graphite salts of the composition C23nSbF6(CH3NO2)1,7 n = 1,2 by121Sb Mössbauer spectroscopy at 4.2K. The spectra reveal a strong and narrow feature in the Sb5+ region and no evidence of any features in the Sb3+ region. This result is in general accord with the expectation of only Sb5+ in the chemical form of SbF6− anion in the intercalate layers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 20: Symposium H – Intercalated Graphite , 1982 , 389
Copyright
Copyright © Materials Research Society 1983

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References

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