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Effects of Plasma Surface treatment on Ohmic Contact to n-GaN

Published online by Cambridge University Press:  21 March 2011

E.F. Chor
Affiliation:
Center for Optoelectronics, Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, Singapore117576
X. J. Kang
Affiliation:
Center for Optoelectronics, Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, Singapore117576
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Abstract

We have investigated the effects of plasma surface treatment on ohmic contacts to n-type GaN. Prior to metal evaporation, n-GaN surface was etched either chemically using aqua-regia (control sample) or by means of inductively coupled Cl2/BCl3, N2 or Ar plasmas. The metal system adopted in our investigation was Ti/Al/Pd/Au. The as-deposited Ti/Al/Pd/Au contact on aqua-regia treated n-GaN exhibits an ohmic behavior with a specific contact resistance (ρc) of 2×10−4ωcm2. After annealing at 500°C for 5min, ρc is reduced by approximately 2 orders of magnitude to 5×10−6ωcm2. For Cl2/BCl3 and N2 plasma treated n-GaN surface, the as-deposited Ti/Al/Pd/Au contacts also yield ohmic behavior and ρc's are about 2×10−4 and 5×10−4 ωcm2 respectively. After annealing at 500°C for 5min, ρc's are reduced by about 3 orders of magnitude to around 5×10−7 and 8×10−7 ωcm2 respectively. On the other hand, the as-deposited Ti/Al/Pd/Au contact on Ar plasma treated n-GaN exhibits a non-ohmic behavior. After annealing at 500°C for 5min, ρc is about 5×10−7 ωcm2 and the lowest ρc of 7×10−8 ωcm2 is obtained after annealing at 700°C for 5min. The contacts on other surface treated n-GaN are found to degrade at 700°C annealing. By comparing the values of ρc for various surface treatments, particularly those after annealing, it is observed that plasma etching can be used beneficially in the formation of ohmic contacts – plasma surface treatment using Cl2/BCl3, N2 or Ar has resulted in an order of magnitude reduction in ρc compared to chemical surface treatment by aqua-regia.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

[1] Mohammad, S. N., , Arnel Salvador, A., and Morkoc, Hadis, Fellow, IEEE “Emerging Gallium Nitride Based Devices”, Proceedings of the IEEE, Vol. 83, NO. 10, 1036, (1995)Google Scholar
[2] Shul, R. J., McClellan, G. B., Casalnuovo, S. A., and Rieger, D.J., Perton, S. J., Conjstantine, C., Barratt, C., Karlicek, R. F. Jr, Tran, C., and Schurman, M., “Inductively coupled plasma etching of GaN”, Appl. Phys. Lett. 69 (8), 11191121, (1996)Google Scholar
[3] Sheu, J. K. and Su, Y. K., “Investigation of mechanism for Ti/Al ohmic contact on etched nGaN surface”, J. Vac. Sci. Technol. B 18(2), pp729932, Mar/Apr (2000).Google Scholar
[4] Rong, B., Cheung, R., Gao, W., Alkaisi, M. M., Reeves, R. J., “effects of reactive ion etching on the electrical characteristics of GaN”, J. Vac. Sci. Technol. B 18(6), pp34673470, Nov/Dec (2000).Google Scholar
[5] Ping, A. T., Chen, Q., Yang, J. W., a, and Adesida, I., “The Effects of Reactive Ion Etching-Induced Damage on the Characteristics of Ohmic Contact to n-Type GaN”, Journal of Electronic Materials, Vol. 27, NO. 4, 261265 (1998)Google Scholar