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Morphology of Ti37Al63 Thin-Films Deposited by Magnetron Sputtering

Published online by Cambridge University Press:  17 March 2011

N. David Theodore
Affiliation:
DigitalDNA™ Labs., Motorola Inc., 2100 E. Elliot Rd., MD-EL622, Tempe, AZ 85284, U.S.A
Hyunchul C. Kim
Affiliation:
Department of Chemical and Materials Engineering, Arizona State University, Tempe, AZ 85287, U.S.A
Kaustubh S. Gadre
Affiliation:
Intel Corp., RA3-402, 2501 NW 229th St., Hillsboro, OR 97124, U.S.A
James W. Mayer
Affiliation:
Department of Chemical and Materials Engineering, Arizona State University, Tempe, AZ 85287, U.S.A
Terry L. Alford
Affiliation:
Department of Chemical and Materials Engineering, Arizona State University, Tempe, AZ 85287, U.S.A
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Abstract

TiAl based thin-films possess high oxidation-resistance and high melting points, making them possible candidates for application in electronics. The behavior of the films upon exposure to various temperatures is of interest for such application. In the present study, Ti37Al63 thin films were deposited onto SiO2 substrates using RF magnetron sputtering from a compound target. Anneals were performed in vacuum at temperatures ranging from 400 °C to 700 °C. The phases and microstructural behavior of the films were evaluated as a function of annealing. Microstructural behavior was correlated with resistivity changes in the films. The behavior of Ti-Al films as potential under-layers for silver metallization was also evaluated. The Ti-Al was observed to enhance the thermal stability of pure Al thin-films. The results are relevant for potential application of the films to electronics.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

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