Skip to main content Accessibility help
×
Home
Hostname: page-component-55597f9d44-ms7nj Total loading time: 0.28 Render date: 2022-08-18T05:31:14.147Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "useRatesEcommerce": false, "useNewApi": true } hasContentIssue true

Ordered Mesoporous Silica Films Synthesized from Vapor Phase

Published online by Cambridge University Press:  10 February 2011

Shunsuke Tanaka
Affiliation:
Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
Norikazu Nishiyama
Affiliation:
Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
Yasuyuki Egashira
Affiliation:
Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
Yoshiaki Oku
Affiliation:
Mirai project, Association of Super-Advanced Electronics Technology, AIST Tsukuba West 7, 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan
Korekazu Ueyama
Affiliation:
Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
Get access

Abstract

A novel synthesis route for mesostructured silica films is reported. Nano-phase transition from lamellar phase of surfactant to hexagonal phase of silica-surfactant nanocomposite was found under vapor infiltration. Vapor infiltration was performed using HCl as catalyst source and tetraethoxysilane (TEOS) as framework source. Highly ordered mesostructured silica films are obtained using alkyltrimethylammonium bromide CnTAB (the carbon number in the alkyl chain; n = 8, 10, 12, 14, 16, 18) as templating agent. The d values of the mesostructured silica films increase with increasing the length of the alkyl chain and are controllable by the synthetic temperature. The vapor infiltration synthesis is a simpler process compared to conventional sol-gel techniques and attractive for mass production of a variety of organic-inorganic composite materials and inorganic porous materials. This novel synthetic method provides opportunities for the creation of new materials technologies.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Yang, H., Coombs, N., Sokolov, I., and Ozin, G.A., Nature, 381, 589 (1996)CrossRefGoogle Scholar
[2] Yang, H., Coombs, N., Dag, O., Sokolov, I., and Ozin, G.A., J. Mater. Chem., 7, 1755 (1997)CrossRefGoogle Scholar
[3] Yang, H., Kuperman, A., Coombs, N., Mamich-Afara, S., and Ozin, G.A., Nature, 379, 703 (1996)CrossRefGoogle Scholar
[4] Yang, H., Coombs, N., Sokolov, I., and Ozin, G.A., J. Mater. Chem., 7, 1285 (1997)CrossRefGoogle Scholar
[5] Nishiyama, N., Koide, A., Egashira, Y., and Ueyama, K., Chem. Commun., 2499 (1998).Google Scholar
[6] Nishiyama, N., Park, D.H., Koide, A., Egashira, Y., and Ueyama, K., J. Membr. Sci., 182, 2499 (1998)Google Scholar
[7] Lu, Y., Ganguli, R., Drewien, C.A., Anderson, M.T., Brinker, C.J., Gong, W., Guo, Y., Soyez, H., Dunn, B., Huang, M.H., and Zink, J.I., Nature, 389, 364 (1997)CrossRefGoogle Scholar
[8] Sellinger, A., Weiss, P.R., Nguyen, A., Lu, Y., Assink, R.A., Gong, W., and Brinker, C.J., Nature, 394, 256 (1998)CrossRefGoogle Scholar
[9] Ogawa, M., J. Am. Chem. Soc., 116, 7941 (1994)CrossRefGoogle Scholar
[10] Ogawa, M., Chem. Commun., 1149 (1996).Google Scholar
[11] Ogawa, M., Ishikawa, H., and Kikuchi, T., J. Mater. Chem., 8, 1783 (1998)CrossRefGoogle Scholar
[12] Ogawa, M., and Masukawa, N., Micropor. Mesopor. Mater., 38, 35 (2000)CrossRefGoogle Scholar
[13] Nishiyama, N., Tanaka, S., Egashira, Y., Oku, Y., and Ueyama, K., Chem. Mater., 15, 1006 (2003)CrossRefGoogle Scholar
[14] Marler, B., Oberhagemann, U., Vortmann, S., and Gies, H., Micropor. Mater., 6, 375 (1996)CrossRefGoogle Scholar

Save article to Kindle

To save this article to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Ordered Mesoporous Silica Films Synthesized from Vapor Phase
Available formats
×

Save article to Dropbox

To save this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Dropbox account. Find out more about saving content to Dropbox.

Ordered Mesoporous Silica Films Synthesized from Vapor Phase
Available formats
×

Save article to Google Drive

To save this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Google Drive account. Find out more about saving content to Google Drive.

Ordered Mesoporous Silica Films Synthesized from Vapor Phase
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *