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Structures of New Nitrides Prepared using Solid Oxide Precursors

Published online by Cambridge University Press:  10 February 2011

Joel D. Houmes ,
David S. Bem  and
Hans-Conrad Zur Loye
Joel D. Houmes
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
David S. Bem
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
Hans-Conrad Zur Loye
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
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Abstract

Several novel transition metal nitrides and oxynitrides were synthesized via ammonolysis of solid state oxide precursors at temperatures ranging from 700°C-900°C and reaction times ranging from 12 hours to 4 days. The products were characterized by powder X-ray diffraction and their structures were determined by powder X-ray Rietveld refinement. The relationships between the structures of these nitrides and oxynitrides, and their similarity to the structures of the transition metal dichalcogenides, is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 410: Symposium S – Covalent Ceramics III-Science and Technology of Non-Oxides , 1995 , 113
Copyright
Copyright © Materials Research Society 1996

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