Hostname: page-component-848d4c4894-4hhp2 Total loading time: 0 Render date: 2024-05-21T05:16:05.048Z Has data issue: false hasContentIssue false
  • English
  • Français

Deep Disposal of Eurobitum Bituminised Waste: Scoping Calculations of Nitrate Release

Published online by Cambridge University Press:  21 March 2011

Eef Weetjens ,
Xavier Sillen  and
Elie Valcke
Eef Weetjens
Affiliation:
Waste and Disposal Department, SCK•CEN, Belgian Nuclear Research Centre Boeretang 200 - B-2400 Mol, Belgium, eweetjen@sckcen.be
Xavier Sillen
Affiliation:
Waste and Disposal Department, SCK•CEN, Belgian Nuclear Research Centre Boeretang 200 - B-2400 Mol, Belgium
Elie Valcke
Affiliation:
Waste and Disposal Department, SCK•CEN, Belgian Nuclear Research Centre Boeretang 200 - B-2400 Mol, Belgium
Get access

Abstract

The Eurobitum bituminised waste produced by the former EUROCHEMIC reprocessing plant in Mol-Dessel (Belgium) contains a lot of salts, mainly NaNO3. This NaNO3 may possibly affect significantly the evolution of a radwaste repository through redox and ion exchange reactions with Boom Clay, which in Belgium is studied as a reference host formation. Yet, the leaching behaviour of NaNO3 from the Eurobitum and its migration in the Boom Clay is rather unclear. Therefore, some scoping numerical calculations have been performed. In a first phase, we calculated the water flux towards the disposal gallery to assess the timescale of the saturation process of the disposal galleries. In a second phase, the leaching rate of NaNO3 out of the drums is compared with its diffusive removal through the Boom Clay.

The water flux to the gallery was calculated at approximately 100 ml/day per metre gallery, based on the natural pressure gradient observed around the HADES Underground Research Laboratory. Different approaches were elaborated to find a NaNO3 source term for the diffusion calculations. For various ways of characterising the nitrate release, the numerical calculations generally show that the NaNO3 concentrations in the first decimetres of Boom Clay will not be much higher than 1 M. Moreover, a sensitivity analysis showed that if the nitrate is released from the bituminised waste product within 10 000 years, the Boom Clay controls the concentration profiles; if the release is slower, the source term has a more pronounced effect on the near field concentrations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 932: Symposium – Scientific Basis for Nuclear Waste Management XXIX , 2006 , 41.1
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Runchal, A.K.. PORFLOW, a software tool for multiphase fluid flow, heat and mass transport in fractured porous media. User's manual, Version 3.07 (ACRi, Bel Air, California, USA, 1997).Google Scholar
2. Šimůnek, J., Šejna, M. and Genuchten, M.Th. van. The HYDRUS-2D software package for simulating the two-dimensional movement of water, heat, and multiple solutes in variably-saturated media. Version 2.0 (USSL-ARS-USDA, Riverside, California, 1999).Google Scholar
3. Cannière, P. De, Fonteyne, A., Moors, H., Put, M. and Gompel, M. Van, Geological Disposal of Conditioned High-Level and Long Lived Radioactive waste. Tasks 1.2 to 5.2 & Operation and Maintenance of the URF. Progress report to NIRAS/ONDRAF for the second semester of 1993. R-2992 SCK·CEN (1994).Google Scholar
4. Valcke, E., Sneyers, A. and Iseghem, P. van, Characterisation and compatibility with the disposal medium of Eurochemic reprocessing waste forms. R-3633 SCK·EN (2002).Google Scholar
5. Broderson, K., Brunel, G., Gens, R., Lambert, F., Nominé, J.C., Sneyers, A. and Iseghem, P. Van, Characteristics of bituminised radioactive waste. EUR report 18228 (1998).Google Scholar
6. Weetjens, E., Characterisation and compatibility with the disposal medium of Eurochemic reprocessing waste forms. Nitrate release from EUROBITUM bituminised waste: scoping calculations. R-3767 SCK·CEN (2003).Google Scholar