Hostname: page-component-848d4c4894-p2v8j Total loading time: 0.001 Render date: 2024-05-21T18:30:49.035Z Has data issue: false hasContentIssue false
  • English
  • Français

Design and Optical Properties of Rare Earth-Based Mixed-Anions (O, S, F) Compounds

Published online by Cambridge University Press:  11 February 2011

Damien Pauwels ,
Alain Demourgues  and
Alain Tressaud
Damien Pauwels
Affiliation:
Institut de Chimie de la Matiere Condensee de Bordeaux (ICMCB-CNRS), 87, avenue du Dr. Albert Schweitzer, Pessac cedex, 33608, FRANCE.
Alain Demourgues
Affiliation:
Institut de Chimie de la Matiere Condensee de Bordeaux (ICMCB-CNRS), 87, avenue du Dr. Albert Schweitzer, Pessac cedex, 33608, FRANCE.
Alain Tressaud
Affiliation:
Institut de Chimie de la Matiere Condensee de Bordeaux (ICMCB-CNRS), 87, avenue du Dr. Albert Schweitzer, Pessac cedex, 33608, FRANCE.
Get access

Abstract

Rare earth-based mixed-anions (O, S, F) compounds have been prepared by solid state route. The structures have been determined on the basis of powder diffraction (X-ray/neutrons) refinement and/or single crystal analysis. They have been described as a stacking of [Sx] 2x- layers and fluorite type blocks. The evaluation of the rare earth environment (bondlength, number of neighbors) can be directly related to the bandgap and to the UV-visible absorption in the La-based compounds.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD7.8
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Ozawa, L., Forest, H., Anal. Chem. 45, 978 (1973).Google Scholar
[2] Blasse, G., Grabmaier, B. C., “Luminescent Materials“, ed. Springer-Verlag, Berlin Heidelberg (1994) p. 161.Google Scholar
[3] Demourgues, A., Tressaud, A., Laronze, H., Macaudière, P., J. Alloys Comp. 323–324, 223 (2001).Google Scholar
[4] Demourgues, A., Tressaud, A., Laronze, H., Gravereau, P., Macaudière, P., J. Fluor. Chem. 107, 215 (2001).Google Scholar
[5] Morosin, B. B., , Newman, D. J., Acta Cryst. B29, 2647 (1973).Google Scholar
[6] Pauwels, D., Demourgues, A., Laronze, H., Gravereau, P., Guillen, F., Isnard, O., Tressaud, A., Solid State Science, in press.Google Scholar
[7] Pauwels, D., Demourgues, A., Weill, F., Tressaud, A., to be published.Google Scholar
[8] Ackerman, J. F., J. Solid State Chem 62, 92 (1986).Google Scholar
[9] Dugue, J., Carre, D., Guittard, M., Acta Cryst B34, 3564 (1978).Google Scholar