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The Electronic Transfer and the Formation of Cationic Intercalation Compounds

Published online by Cambridge University Press:  21 February 2011

J. Rouxel
J. Rouxel*
Affiliation:
Laboratoire de Chimie des Solides, Institut de Physique et Chimie des Matériaux - 2, rue de la Houssinière, 44072 Nantes Cédex 03, France
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Abstract

Low-dimensional solids are known to be among the best host structures to practice intercalation chemistry. Besides geometrical aspects which play an important role but are now quite well understood, this paper emphasizes the relationship between chemical reactivity and the electronic structure of the host. A special attention is paid to the nature of redox centers involved in the intercalation process and to the connection between the phase diagram and the band structure of the host material.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 431
Copyright
Copyright © Materials Research Society 1989

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